Search Results - "Gu, Nina X."
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Hydrazine Formation via Coupling of a Nickel(III)–NH2 Radical
Published in Angewandte Chemie International Edition (19-02-2021)“…M(NHx) intermediates involved in N−N bond formation are central to ammonia oxidation (AO) catalysis, an enabling technology to ultimately exploit ammonia (NH3)…”
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2
Catalytic carbon–carbon bond cleavage in lignin via manganese–zirconium-mediated autoxidation
Published in Nature communications (29-01-2024)“…Efforts to produce aromatic monomers through catalytic lignin depolymerization have historically focused on aryl–ether bond cleavage. A large fraction of…”
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Autoxidation Catalysis for Carbon–Carbon Bond Cleavage in Lignin
Published in ACS central science (27-12-2023)“…Selective lignin depolymerization is a key step in lignin valorization to value-added products, and there are multiple catalytic methods to cleave labile…”
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4
H 2 Evolution from a Thiolate-Bound Ni(III) Hydride
Published in Journal of the American Chemical Society (29-04-2020)“…Terminal Ni hydrides are proposed intermediates in proton reduction catalyzed by both molecular electrocatalysts and metalloenzymes, but well-defined examples…”
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5
H2 Evolution from a Thiolate-Bound Ni(III) Hydride
Published in Journal of the American Chemical Society (29-04-2020)“…Terminal NiIII hydrides are proposed intermediates in proton reduction catalyzed by both molecular electrocatalysts and metalloenzymes, but well-defined…”
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6
An S = 1 / 2 Iron Complex Featuring N 2 , Thiolate, and Hydride Ligands: Reductive Elimination of H 2 and Relevant Thermochemical Fe-H Parameters
Published in Journal of the American Chemical Society (23-05-2018)“…Believed to accumulate on the Fe sites of the FeMo-cofactor (FeMoco) of MoFe-nitrogenase under turnover, strongly donating hydrides have been proposed to…”
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7
Hydrazine Formation via Coupling of a Nickel(III)-NH 2 Radical
Published in Angewandte Chemie International Edition (19-02-2021)“…M(NH ) intermediates involved in N-N bond formation are central to ammonia oxidation (AO) catalysis, an enabling technology to ultimately exploit ammonia (NH )…”
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Journal Article -
8
Cluster dynamics of heterometallic trinuclear clusters during ligand substitution, redox chemistry, and group transfer processes
Published in Chemical science (Cambridge) (29-05-2024)“…Stepwise metalation of the hexadentate ligand tbs LH 6 ( tbs LH 6 = 1,3,5-C 6 H 9 (NHC 6 H 4 - o -NHSiMe 2 t Bu) 3 ) affords bimetallic trinuclear clusters (…”
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9
An S = 1/2 Iron Complex Featuring N2, Thiolate, and Hydride Ligands: Reductive Elimination of H2 and Relevant Thermochemical Fe–H Parameters
Published in Journal of the American Chemical Society (23-05-2018)“…Believed to accumulate on the Fe sites of the FeMo-cofactor (FeMoco) of MoFe-nitrogenase under turnover, strongly donating hydrides have been proposed to…”
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Journal Article -
10
Hydrazine Formation via Coupling of a Nickel(III)–NH2 Radical
Published in Angewandte Chemie (19-02-2021)“…M(NHx) intermediates involved in N−N bond formation are central to ammonia oxidation (AO) catalysis, an enabling technology to ultimately exploit ammonia (NH3)…”
Get full text
Journal Article -
11
Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters
Published in Journal of the American Chemical Society (25-09-2013)“…Concomitant deprotonation and metalation of hexadentate ligand platform tbsLH6 (tbsLH6 = 1,3,5-C6H9(NHC6H4-o-NHSiMe2 t Bu)3) with divalent transition metal…”
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12
Hydrazine Formation via Coupling of a NiIII-NH2 Radical
Published in Angewandte Chemie International Edition (23-12-2020)“…M(NH x ) intermediates involved in N–N bond formation are central to ammonia oxidation (AO) catalysis, an enabling technology to ultimately exploit ammonia (NH…”
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Journal Article -
13
Hydrazine Formation via Coupling of a Nickel(III)–NH 2 Radical
Published in Angewandte Chemie (19-02-2021)“…M(NH x ) intermediates involved in N−N bond formation are central to ammonia oxidation (AO) catalysis, an enabling technology to ultimately exploit ammonia (NH…”
Get full text
Journal Article