Search Results - "Grune, Eduard"
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Tapered Multiblock Copolymers Based on Isoprene and 4‑Methylstyrene: Influence of the Tapered Interface on the Self-Assembly and Thermomechanical Properties
Published in Macromolecules (26-02-2019)“…The synthesis of tapered multiblock copolymers by statistical living anionic copolymerization of a mixture of isoprene (I) and 4-methylstyrene (4MS) in…”
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Effect of the Substituent Position on the Anionic Copolymerization of Styrene Derivatives: Experimental Results and Density Functional Theory Calculations
Published in Macromolecules (25-06-2019)“…In a combined synthetic, kinetic and theoretical study, the living anionic copolymerization of styrene and its ring-methylated derivatives ortho-, meta-, and…”
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One-Step Anionic Copolymerization Enables Formation of Linear Ultrahigh-Molecular-Weight Block Copolymer Films Featuring Vivid Structural Colors in the Bulk State
Published in ACS applied materials & interfaces (30-05-2018)“…Ultrahigh-molecular-weight (UHMW) tapered block copolymers (BCPs) consisting of polyisoprene-block-poly(4-methylstyrene) featuring overall molar masses in the…”
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Controlling the Polymer Microstructure in Anionic Polymerization by Compartmentalization
Published in Angewandte Chemie International Edition (23-02-2018)“…An ideal random anionic copolymerization is forced to produce gradient structures by physical separation of two monomers in emulsion compartments. One monomer…”
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One-Step Block Copolymer Synthesis versus Sequential Monomer Addition: A Fundamental Study Reveals That One Methyl Group Makes a Difference
Published in Macromolecules (08-05-2018)“…Block copolymers of polyisoprene and polystyrene are key materials for polymer nanostructures as well as for several commercially established thermoplastic…”
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Anionic Copolymerization Enables the Scalable Synthesis of Alternating (AB) n Multiblock Copolymers with High Molecular Weight in n/2 Steps
Published in ACS macro letters (17-07-2018)“…Based on the highly disparate reactivities of isoprene (I, r I = 25.4) and 4-methylstyrene (4MS, r 4MS = 0.007) in the anionic copolymerization in nonpolar…”
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Die lebende anionische Polymerisation
Published in Chemie in unserer Zeit (01-08-2017)“…Zusammenfassung Vor sechzig Jahren entdeckte Michael Szwarc die lebende anionische Polymerisation. Trotz ihrer hohen synthetischen Anforderungen ist sie bis…”
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Kontrollierte Polymermikrostruktur in anionischer Polymerisation durch Kompartimentierung
Published in Angewandte Chemie (23-02-2018)“…Eine ideale, statistische anionische Copolymerisation wird durch physikalische Trennung der beiden Monomere in Kompartimente einer Emulsion gezwungen, um so…”
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Die lebende anionische Polymerisation: Quicklebendig seit 60 Jahren
Published in Chemie in unserer Zeit (01-08-2017)“…Zusammenfassung Vor sechzig Jahren entdeckte Michael Szwarc die lebende anionische Polymerisation. Trotz ihrer hohen synthetischen Anforderungen ist sie bis…”
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10
Die lebende anionische Polymerisation
Published in Chemie in unserer Zeit (01-08-2017)“…Zusammenfassung Vor sechzig Jahren entdeckte Michael Szwarc die lebende anionische Polymerisation. Trotz ihrer hohen synthetischen Anforderungen ist sie bis…”
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11
Kontrollierte Polymermikrostruktur in anionischer Polymerisation durch Kompartimentierung
Published in Angewandte Chemie (01-02-2018)“…Eine ideale, statistische anionische Copolymerisation wird durch physikalische Trennung der beiden Monomere in Kompartimente einer Emulsion gezwungen, um so…”
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