Search Results - "Groux, Laurent F"

Synthesis and Reactivities of Neutral and Cationic Indenyl−Palladium Complexes by Sui-Seng, Christine, Groux, Laurent F, Zargarian, Davit

“…The complexes [(1-R-Ind)Pd(PPh3)Me] (R = H (3), Me (4)), [(1-R-Ind)Pd(PPh3)2]BF4 (R = H (5[BF4]), Me (6)), and [(1-R-Ind)Pd(PPh3)(OSO2CF3)] (R = H (7), Me (8))…”
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Indenyl-Nickel Complexes Bearing a Pendant, Hemilabile Olefin Ligand:  Preparation, Characterization, and Catalytic Activities by Gareau, Daniel, Sui-Seng, Christine, Groux, Laurent F, Brisse, François, Zargarian, Davit

“…The reaction of (PPh3)2NiCl2 with Li[Ind∧CHCH2] gave the neutral complexes (η:η0-Ind∧CHCH2)Ni(PPh3)Cl (Ind = indenyl; ∧ = (CH2)2, 1a; Si(Me)2CH2, 1b), which…”
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Insertion of Acrylonitrile into Palladium Methyl Bonds in Neutral and Anionic Pd(II) Complexes by Groux, Laurent F, Weiss, Thomas, Reddy, Dastigiri N, Chase, Preston A, Piers, Warren E, Ziegler, Tom, Parvez, Masood, Benet-Buchholz, Jordi

“…The reactions of a series of Pd(II) methyl compounds of general formula LPd(NCCH3)CH3, where L is a bulky phenoxydiazene or phenoxyaldimine ligand with the…”
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Catalytic Reactivities of Indenyl–nickel, Indenyl–palladium, and PCsp3P–nickel Complexes by Sui-Seng, Christine, Castonguay, Annie, Chen, Yaofeng, Gareau, Daniel, Groux, Laurent F., Zargarian, Davit

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Aminoalkyl-Substituted Indenyl−Nickel Compounds:  Tuning Reactivities as a Function of the Pendant, Hemilabile Moiety by Groux, Laurent F, Zargarian, Davit

“…Indenyl ligands bearing three different aminoalkyl substituents have been used to prepare the complexes (Ind∧NR2)Ni(PPh3)Cl (Ind∧NR2 =…”
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Structure and Reactivity of the Cationic Nickel Compound [(η3:η1-Ind(CH2)2NMe2)Ni(PPh3)][BPh4] by Groux, Laurent F, Zargarian, Davit

“…The solid-state structure of the first nickel compound containing a chelating amino−indenyl ligand, [(η3:η1-Ind(CH2)2NMe2)Ni(PPh3)][BPh4] (2), has been…”
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Phosphino-indenyl complexes of nickel(II) by Groux, Laurent F, Bélanger-Gariépy, Francine, Zargarian, Davit

“…The BH 3 -protected phosphinoindenyl ligand indenyl(CH 2 ) 2 PPh 2 ·BH 3 was used in the preparation of (η 5/3 :η 0 -indenyl(CH 2 ) 2 PPh 2 ·BH 3 )Ni(PPh 3…”
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Nickel-Triflate Complexes as Precursors to Reactive Cations:  Preparation and Reactivities of (1-R-indenyl)Ni(PPh3)(OSO2CF3) by Wang, Ruiping, Groux, Laurent F, Zargarian, Davit

“…The complexes (1-R-indenyl)Ni(PPh3)(OTf) (OTf = OSO2CF3; R = Et (1), i-Pr (2), and Bz (3)) have been prepared by reacting the corresponding Ni-thienyl or Ni-Cl…”
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Copolymerization of Ethylene with Polar Monomers:  Chain Propagation and Side Reactions. A DFT Theoretical Study Using Zwitterionic Ni(II) and Pd(II) Catalysts by Szabo, Miklos J, Galea, Natasha M, Michalak, Artur, Yang, Sheng-Yong, Groux, Laurent F, Piers, Warren E, Ziegler, Tom

“…Calculations utilizing anionic substituted derivates of the cationic N∧N Ni(II) and Pd(II) diimine Brookhart complex have been carried out on the barriers of…”
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Aminoalkyl-Substituted Indenylnickel(II) Complexes (η3:η0-Ind(CH2)2NMe2)Ni(PR3)X and [(η3:η1-Ind(CH2)2NMe2)Ni(PR3)][BPh4]:  Influence of the Phosphine in Ligand Exchange and Polymerization Reactions by Groux, Laurent F, Zargarian, Davit

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Aminoalkyl-Substituted Indenylnickel(II) Complexes (η 3:η 0-Ind(CH2)2NMe2)Ni(PR3)X and [(η 3:η 1-Ind(CH2)2NMe2)Ni(PR3)][BPh4]:  Influence of the Phosphine in Ligand Exchange and Polymerization Reactions by Groux, Laurent F, Zargarian, Davit

“…Reaction of LiInd(CH2)2NMe2 with (PR3)2NiCl2 gave the neutral complexes (η 3:η 0-Ind(CH2)2NMe2)Ni(PR3)Cl (R = Ph (1) or Me (2)), while the PCy3 analogue, (η…”
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Dimerization and polymerization of ethylene catalyzed by nickel complexes bearing multidentate amino-functionalized indenyl ligands by Groux, Laurent F, Zargarian, Davit, Simon, Leonardo C, Soares, João B.P

“…The combination of ( η 3: η 0-Ind(CH 2) 2NMe 2)Ni(PPh 3)Cl ( 1) and methylaluminoxane (MAO) produces catalysts for the dimerization and the polymerization of…”
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Preparation, characterization, and reactivities of thienyl nickel complexes bearing indenyl ligands by Wang, Ruiping, Groux, Laurent F, Zargarian, Davit

“…The complexes (1-R, 2-R′-indenyl)NiPPh 3(thienyl) (R′=H, R=Me ( 1); Et ( 2); i-Pr ( 3); CH 2Ph ( 4); R′=Ph, R=Me ( 5)) have been prepared and characterized by…”
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Preparation and Characterization of Nickel Complexes with η-Indenyl Ligands Bearing a Pendant Aminoalkyl Chain by Groux, Laurent F, Bélanger-Gariépy, Francine, Zargarian, Davit, Vollmerhaus, Rainer

“…The aminoindenyl complexes {Ind(CH2)3,4N(t-Bu)H}Ni(PPh3)Cl (7, 8) and {Ind(CH2)2,3NMe2}Ni(PPh3)Cl (9, 10) have been prepared and characterized by spectroscopy…”
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Aminoalkyl-Substituted Indenylnickel(II) Complexes (η 3 :η 0 -Ind(CH 2 ) 2 NMe 2 )Ni(PR 3 )X and [(η 3 :η 1 -Ind(CH 2 ) 2 NMe 2 )Ni(PR 3 )][BPh 4 ]:  Influence of the Phosphine in Ligand Exchange and Polymerization Reactions by Groux, Laurent F., Zargarian, Davit

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Aminoalkyl-Substituted Indenylnickel(II) Complexes ( η 3 : η 0 -Ind(CH 2 ) 2 NMe 2 )Ni(PR 3 )X and [( η 3 : η 1 -Ind(CH 2 ) 2 NMe 2 )Ni(PR 3 )][BPh 4 ]:  Influence of the Phosphine in Ligand Exchange and Polymerization Reactions by Groux, Laurent F., Zargarian, Davit

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Copolymerization of Ethylene with Polar Monomers by Anionic Substitution. Theoretical Study Based on Acrylonitrile and the Brookhart Diimine Catalyst by Szabo, Miklos J., Galea, Natasha M., Michalak, Artur, Yang, Sheng-Yong, Groux, Laurent F., Piers, Warren E., Ziegler, Tom

“…Calculations have been carried out on the complexation energy of acrylonitrile and ethylene using derivatives of the cationic N∧N Ni(II)−diimine Brookhart…”
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Phosphino-indenyl complexes of nickel(II)1 by Groux, Laurent F, Bélanger-Gariépy, Francine, Zargarian, Davit

“…The BH^sub 3^-protected phosphinoindenyl ligand indenyl(CH^sub 2^)^sub 2^PPh^sub 2^.BH^sub 3^ was used in the preparation of (η^sup 5/3^:η^sup…”
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[2-(1H-Inden-3-yl)­ethyl]­di­phenyl­phos­phine-borane by Groux, Laurent F., Zargarian, Davit

“…The title compound, C23H24BP, crystallizes in the centrosymmetric space group P21/c, with one mol­ecule in the asymmetric unit. The indene moiety is…”
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[2-(1 H -Inden-3-yl)ethyl]diphenylphosphine–borane by Groux, Laurent F., Zargarian, Davit

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