Search Results - "Grosche, Manja"
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A Defined N-Heterocyclic Carbene Complex for the Palladium-Catalyzed Suzuki Cross-Coupling of Aryl Chlorides at Ambient Temperatures
Published in Angewandte Chemie International Edition (15-04-2002)“…Highly active but sterically demanding: Ambient‐temperature Suzuki cross‐coupling of aryl chlorides is possible with a palladium(0) complex bearing two bulky,…”
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2
Polymer-Supported Carbene Complexes of Palladium: Well-Defined, Air-Stable, Recyclable Catalysts for the Heck Reaction
Published in Chemistry : a European journal (15-05-2000)“…N‐Heterocyclic dicarbene chelate complexes of formula [cis‐CH2{N(H)CC(H)N(R)C}2PdX2] (X=Br, I; R=(CH2)nOH; n=2, 3) have been prepared and structurally…”
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3
Synthesis, structure and catalytic application of palladium(II) complexes bearing N-heterocyclic carbenes and phosphines
Published in Journal of organometallic chemistry (01-01-2001)“…A variety of mixed palladium(II) complexes bearing N-heterocyclic carbenes (NHCs) and triaryl- and trialkylphosphines [NHC(R 2)]Pd(PR′ 3)I 2 (R=Me, t-Bu, (…”
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4
Developing Transition-Metal Catalysts for the Intramolecular Hydroamination of Alkynes
Published in Organometallics (24-01-2000)“…Group 7−12 transition-metal complexes serve as effective catalysts for the regioselective intramolecular hydroamination of aminoalkynes having the general…”
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5
Unsymmetrically Substituted Iridium(III)−Carbene Complexes by a CH-Activation Process
Published in Organometallics (01-05-2000)“…The synthesis of the metalhydride Cp*(L‘)IrH+OTf - (L‘ = 1-(2-cyclohexenyl)-3-cyclohexylimidazolin-2-ylidene, OTf = OSO2CF3) is achieved by a cyclohexane to…”
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6
Boron−Nitrogen Coordination Polymers Bearing Ferrocene in the Main Chain
Published in Organometallics (25-10-1999)“…The reaction of 1,1‘-fc(BMe2)2 (2) with pyrazine gives a novel poly(ferrocene) [2·pyz]n, which has been structurally characterized by X-ray crystallography [fc…”
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7
Palladium-Catalyzed Cyclization of 6-Aminohex-1-yne
Published in Organometallics (15-10-2001)“…Mechanistic details and limiting factors for the palladium-catalyzed addition of amines to alkynes (hydroamination) were studied, using the cyclization of…”
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8
Dibenzo-1,5-diazocine-2,6-dione, 2-iminoindolin-3-one and N-(carbamoylmethyl)-aminobenzoic acid ester from aminobenzoic acid by multicomponent reactions
Published in Tetrahedron (24-09-1998)“…Aminobenzoic acids show different types of multicomponent reactions when treated with a carbonylic component and an isocyanide in an alcoholic solution…”
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9
A Merrifield Resin Functionalized with Molybdenum Peroxo Complexes: Synthesis and Catalytic Properties
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (2003)“…Abstract CH 2 Cl functionalized polystyrene (Merrifield resin) was reacted with deprotonated 2‐(3‐pyrazolyl)pyridine to give a polymer bound chelate ligand…”
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10
Syntheses and properties of the novel co-catalysts N, N-dimethylanilinium- and trityl{tetrakis[4-(trifluoromethyl)-2,3,5,6-tetrafluorophenyl]borate}
Published in Journal of organometallic chemistry (01-03-2001)“…The syntheses and characterization of the novel co-catalysts trityl{tetrakis[4-(trifluoromethyl)-2,3,5,6-tetrafluorophenyl]borate} ( 2) and the corresponding…”
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11
Trimethylammonium[tetrakis(pentafluorophenoxy)borate], a safe way to synthesize novel co-catalysts for olefin polymerization
Published in Journal of organometallic chemistry (01-03-2001)“…The synthesis and characterization of the novel co-catalyst trimethylammonium[tetrakis(pentafluorophenoxy)borate] ( 1) is reported. Activation of TIBA…”
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dl-Arginine monohydrate at 100 K
Published in Acta crystallographica. Section C, Crystal structure communications (01-10-2000)“…In the title compound, C6H14N4O2·H2O, the α‐amino group is neutral. The molecular side chain including the guanidinium group is not fully extended, having a…”
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13
A Merrifield Resin Functionalized with Molybdenum Peroxo Complexes: Synthesis and Catalytic Properties
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (01-11-2003)“…CH2Cl functionalized polystyrene (Merrifield resin) was reacted with deprotonated 2‐(3‐pyrazolyl)pyridine to give a polymer bound chelate ligand system, which…”
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14
Ein definierter N‐heterocyclischer Carbenkomplex für die Palladium‐katalysierte Suzuki‐Kreuzkupplung von Chlorarenen bei Raumtemperatur
Published in Angewandte Chemie (15-04-2002)“…Hoch aktiv trotz sterischer Abschirmung: Die Suzuki‐Kreuzkupplung von Chlorarenen bei Raumtemperatur ist durch Einsatz eines Palladium(0)‐Komplexes möglich,…”
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15
Ein definierter N-heterocyclischer Carbenkomplex für die Palladium-katalysierte Suzuki-Kreuzkupplung von Chlorarenen bei Raumtemperatur
Published in Angewandte Chemie (15-04-2002)Get full text
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Ein definierter N-heterocyclischer Carbenkomplex für die Palladium-katalysierte Suzuki-Kreuzkupplung von Chlorarenen bei Raumtemperatur N-Heterocyclische Carbene, 32. Mitteilung. Diese Arbeit wurde von der Deutschen Forschungsgemeinschaft (DFG), dem Bayerischen Forschungsverbund Katalyse (FORKAT) und der Bayer AG unterstützt. Wir danken Dr. Öfele und Dr. Scholz für hilfreiche Diskussionen. – 31. Mitteilung: Lit. [4c] (Aufsatz in diesem Heft)
Published in Angewandte Chemie (15-04-2002)Get full text
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