Search Results - "Gros, Philippe C"

Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds by Tilly, David, Chevallier, Floris, Mongin, Florence, Gros, Philippe C

“…A study investigated bimetallic combinations for dehalogenative metalation involving organic compounds. Sulfoxide-magnesium exchange is mentioned as it relates…”
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Combinations of Alkyllithiums and Lithium Aminoalkoxides for Generation of Functional Pyridine Organometallics and Derivatives by Gros, Philippe C., Fort, Yves

“…This account covers the current status of pyridine metallation with alkyllithium/lithium aminoalkoxide reagents and follows a previous review focusing on…”
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Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties by Darari, Mohamed, Francés-Monerris, Antonio, Marekha, Bogdan, Doudouh, Abdelatif, Wenger, Emmanuel, Monari, Antonio, Haacke, Stefan, Gros, Philippe C

“…The control of ligand-field splitting in iron (II) complexes is critical to slow down the metal-to-ligand charge transfer (MLCT)-excited states deactivation…”
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Deprotonative Metalation of Substituted Benzenes and Heteroaromatics Using Amino/Alkyl Mixed Lithium-Zinc Combinations by Snégaroff, Katia, Komagawa, Shinsuke, Chevallier, Floris, Gros, Philippe C., Golhen, Stéphane, Roisnel, Thierry, Uchiyama, Masanobu, Mongin, Florence

“…Different homoleptic and heteroleptic lithium–zinc combinations were prepared, and structural elements obtained on the basis of NMR spectroscopic experiments…”
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Impact of Polypyridyl Ru Complexes on Angiogenesis-Contribution to Their Antimetastatic Activity by Gurgul, Ilona, Mazuryk, Olga, Stachyra, Kamila, Olszanecki, Rafał, Lekka, Małgorzata, Łomzik, Michał, Suzenet, Franck, Gros, Philippe C, Brindell, Małgorzata

“…The use of polypyridyl Ru complexes to inhibit metastasis is a novel approach, and recent studies have shown promising results. We have reported recently that…”
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NHC-Based Iron Sensitizers for DSSCs by Duchanois, Thibaut, Liu, Li, Pastore, Mariachiara, Monari, Antonio, Cebrián, Cristina, Trolez, Yann, Darari, Mohamed, Magra, Kevin, Francés-Monerris, Antonio, Domenichini, Edoardo, Beley, Marc, Assfeld, Xavier, Haacke, Stefan, Gros, Philippe

“…Nanostructured dye-sensitized solar cells (DSSCs) are promising photovoltaic devices because of their low cost and transparency. Ruthenium polypyridine…”
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Theoretical Study of New Ruthenium-Based Dyes for Dye-Sensitized Solar Cells by Monari, Antonio, Assfeld, Xavier, Beley, Marc, Gros, Philippe C

“…Two relevant, recently reported, ruthenium-based complexes to be used as sensitizers in Grätzel photovoltaic cells are theoretically studied. The UV/vis…”
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Structural Studies of (rac)‑BIPHEN Organomagnesiates and Intermediates in the Halogen–Metal Exchange of 2‑Bromopyridine by Francos, Javier, Gros, Philippe C, Kennedy, Alan R, O’Hara, Charles T

“…Four lithium magnesiate complexes (2–5) containing the dianionic (rac)-BIPHEN ligand have been prepared and characterized using X-ray crystallography and NMR…”
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Hydrophilic Ethylene-Glycol-Based Ruthenium Sensitizers for Aqueous Dye-Sensitized Solar Cells by Cisneros, Robin, Beley, Marc, Lapicque, François, Gros, Philippe C.

“…Three ruthenium complexes bearing glycol chains of varied length and number have been prepared and evaluated as hydrophilic sensitizers in aqueous…”
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Tuneable access to indole, indolone, and cinnoline derivatives from a common 1,4-diketone Michael acceptor by El-Marrouki, Dalel, Touchet, Sabrina, Abdelli, Abderrahmen, M'Rabet, Hédi, Lotfi Efrit, Mohamed, Gros, Philippe C

“…A convergent strategy is reported for the construction of nitrogen-containing heterocycles from common substrates: 1,4-diketones and primary amines. Indeed, by…”
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Deprotonative Metalation of Chloro- and Bromopyridines Using Amido-Based Bimetallic Species and Regioselectivity-Computed CH Acidity Relationships by Snégaroff, Katia, Nguyen, Tan Tai, Marquise, Nada, Halauko, Yury S., Harford, Philip J., Roisnel, Thierry, Matulis, Vadim E., Ivashkevich, Oleg A., Chevallier, Floris, Wheatley, Andrew E. H., Gros, Philippe C., Mongin, Florence

“…A series of chloro‐ and bromopyridines have been deprotometalated by using a range of 2,2,6,6‐tetramethylpiperidino‐based mixed lithium–metal combinations…”
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Deprotonative metalation of substituted aromatics using mixed lithium–cobalt combinations by Dayaker, Gandrath, Chevallier, Floris, Gros, Philippe C., Mongin, Florence

“…The deprotonation of anisole was attempted using different homo- and heteroleptic TMP/Bu mixed lithium–cobalt combinations. Using iodine to intercept the…”
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Enantioselective Metalation of N,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases by Dayaker, Gandrath, Tilly, David, Chevallier, Floris, Hilmersson, Göran, Gros, Philippe C., Mongin, Florence

“…Enantioselective deprotonative metalations of substituted ferrocenes using mixed lithium‐metal bases are described. Using N,N‐diisopropylferrocenecarboxamide…”
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TMSCH2Li and TMSCH2Li−LiDMAE:  Efficient Reagents for Noncryogenic Halogen−Lithium Exchange in Bromopyridines by Doudouh, Abdelatif, Woltermann, Christopher, Gros, Philippe C

“…TMSCH2Li and TMSCH2Li−LiDMAE have been used efficiently for bromine−lithium exchange in 2-bromo-, 3-bromo-, and 2,5-dibromopyridines under noncryogenic…”
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Homoleptic Zincate-Promoted Room-Temperature Halogen-Metal Exchange of Bromopyridines by Chau, Nguyet Trang Thanh, Meyer, Maxime, Komagawa, Shinsuke, Chevallier, Floris, Fort, Yves, Uchiyama, Masanobu, Mongin, Florence, Gros, Philippe C.

“…Homoleptic lithium tri‐ and tetraalkyl zincates were reacted with a set of bromopyridines. Efficient and chemoselective bromine–metal exchanges were realized…”
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Iron-Sensitized Solar Cells (FeSSCs) by Pastore, Mariachiara, Caramori, Stefano, Gros, Philippe C.

“…Conspectus The harvesting and conversion of solar energy have become a burning issue for our modern societies seeking to move away from the exploitation of…”
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Lithium Cadmate-Mediated Deprotonative Metalation of Anisole: Experimental and Computational Study by Snégaroff, Katia, Komagawa, Shinsuke, Yonehara, Mitsuhiro, Chevallier, Floris, Gros, Philippe C, Uchiyama, Masanobu, Mongin, Florence

“…Lithium cadmates bearing different ligands were compared with efficient (TMP)3CdLi (TMP = 2,2,6,6-tetramethylpiperidino) for their ability to deprotometalate…”
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Tuning of Ruthenium Complex Properties Using Pyrrole- and Pyrrolidine-Containing Polypyridine Ligands by Martineau, David, Beley, Marc, Gros, Philippe C, Cazzanti, Silvia, Caramori, Stefano, Bignozzi, Carlo A

“…The effect of pyrrole- and pyrrolidine-containing ligands (L) on the properties of heteroleptic [RuL2dcbpy]2+ complexes has been investigated. TiO2 electrodes…”
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The Mechanism of Lithium Zincate‐Mediated I/Zn Exchange Revisited: A Computational Microsolvation Approach in THF by Pierret, Alexandre, Lefebvre, Corentin, Gros, Philippe C., Denhez, Clément, Vasseur, Alexandre

“…Lithium trialkylzincate‐mediated I/Zn exchange reaction has been revisited computationally through a microsolvation approach. A never yet investigated iodoaryl…”
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Front Cover: The Mechanism of Lithium Zincate‐Mediated I/Zn Exchange Revisited: A Computational Microsolvation Approach in THF (Eur. J. Org. Chem. 43/2023) by Pierret, Alexandre, Lefebvre, Corentin, Gros, Philippe C., Denhez, Clément, Vasseur, Alexandre

“…The Front Cover shows the most favorable calculated transition state (TS) through which the I/Zn exchange reaction of 4‐iodobenzyl mesylate with Et3ZnLi…”
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