Search Results - "Greytak, Andrew B."
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Energy Transfer on Demand: Photoswitch-Directed Behavior of Metal–Porphyrin Frameworks
Published in Journal of the American Chemical Society (27-08-2014)“…In this paper, a photochromic diarylethene-based derivative that is coordinatively immobilized within an extended porphyrin framework is shown to maintain its…”
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2
Connecting Wires: Photoinduced Electronic Structure Modulation in Metal–Organic Frameworks
Published in Journal of the American Chemical Society (03-04-2019)“…Electronic structure modulation of metal–organic frameworks (MOFs) through the connection of linker “wires” as a function of an external stimulus is reported…”
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3
Purification of Quantum Dots by Gel Permeation Chromatography and the Effect of Excess Ligands on Shell Growth and Ligand Exchange
Published in Chemistry of materials (23-07-2013)“…This article describes the use of gel permeation chromatography (GPC) as a means to separate natively capped colloidal CdSe and CdSe/Cd x Zn1–x S quantum dots…”
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A Bio-inspired Approach for Chromophore Communication: Ligand-to-Ligand and Host-to-Guest Energy Transfer in Hybrid Crystalline Scaffolds
Published in Angewandte Chemie International Edition (09-11-2015)“…Efficient multiple‐chromophore coupling in a crystalline metal–organic scaffold was achieved by mimicking a protein system possessing 100 % energy‐transfer…”
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Compact Biocompatible Quantum Dots via RAFT-Mediated Synthesis of Imidazole-Based Random Copolymer Ligand
Published in Journal of the American Chemical Society (20-01-2010)“…We present a new class of polymeric ligands for quantum dot (QD) water solubilization to yield biocompatible and derivatizable QDs with compact size (∼10−12 nm…”
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6
Two-Photon Absorbing Nanocrystal Sensors for Ratiometric Detection of Oxygen
Published in Journal of the American Chemical Society (16-09-2009)“…Two nanocrystal-osmium(II) polypyridyl (NC-Os(II)PP) conjugates have been designed to detect oxygen in biological environments. Polypyridines appended with a…”
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Purification and In Situ Ligand Exchange of Metal-Carboxylate-Treated Fluorescent InP Quantum Dots via Gel Permeation Chromatography
Published in The journal of physical chemistry letters (07-09-2017)“…Recently the addition of M2+ Lewis acids (M = Cd, Zn) to InP quantum dots (QDs) has been shown to enhance the photoluminescence quantum yield (PL QY). Here we…”
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Copolymerization and Synthesis of Multiply Binding Histamine Ligands for the Robust Functionalization of Quantum Dots
Published in Macromolecules (09-12-2014)“…The polymeric functionalization of quantum dots via ligand exchange is a robust method for the preparation of stable fluorescent particles with high quantum…”
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9
Fulleretic Well-Defined Scaffolds: Donor-Fullerene Alignment Through Metal Coordination and Its Effect on Photophysics
Published in Angewandte Chemie International Edition (25-07-2016)“…Herein, we report the first example of a crystalline metal–donor–fullerene framework, in which control of the donor–fullerene mutual orientation was achieved…”
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10
Single Crystal to Single Crystal Polymerization of a Self-Assembled Diacetylene Macrocycle Affords Columnar Polydiacetylenes
Published in Crystal growth & design (05-03-2014)“…This manuscript describes a single-crystal-to-single-crystal polymerization of the dihydrate of diacetylene 1 (1·2H2O) to give an unusual polydiacetylene (PDA)…”
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11
Hierarchical Corannulene‐Based Materials: Energy Transfer and Solid‐State Photophysics
Published in Angewandte Chemie (International ed.) (10-04-2017)“…We report the first example of a donor–acceptor corannulene‐containing hybrid material with rapid ligand‐to‐ligand energy transfer (ET). Additionally, we…”
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12
Gel permeation chromatography as a multifunctional processor for nanocrystal purification and on-column ligand exchange chemistry
Published in Chemical science (Cambridge) (01-01-2016)“…This article illustrates the use of gel permeation chromatography (GPC, organic-phase size exclusion chromatography) to separate nanocrystals from weakly-bound…”
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13
Isothermal Titration Calorimetry Resolves Sequential Ligand Exchange and Association Reactions in Treatment of Oleate-Capped CdSe Quantum Dots with Alkylphosphonic Acid
Published in Journal of physical chemistry. C (29-10-2020)“…This article examines a prototypical nanocrystal surface reaction, the replacement of carboxylate ligands with alkylphosphonate on CdSe quantum dots (QDs), in…”
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14
Size-Dependent PbS Quantum Dot Surface Chemistry Investigated via Gel Permeation Chromatography
Published in Chemistry of materials (11-08-2020)“…We report the first comprehensive study on the purification of PbS quantum dots (QDs) using gel permeation chromatography (GPC). GPC enables the efficient and…”
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15
Combined NMR and Isothermal Titration Calorimetry Investigation Resolves Conditions for Ligand Exchange and Phase Transformation in CsPbBr3 Nanocrystals
Published in Journal of physical chemistry. C (19-08-2021)“…Inorganic halide perovskite nanocrystals (NCs), such as CsPbBr3 quantum dots, have emerged as an intriguing alternative to traditional semiconductors in…”
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Quantum Yield Regeneration: Influence of Neutral Ligand Binding on Photophysical Properties in Colloidal Core/Shell Quantum Dots
Published in ACS nano (24-03-2015)“…This article describes an experiment designed to identify the role of specific molecular ligands in maintaining the high photoluminescence (PL) quantum yield…”
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Effective Purification of CsPbBr3 Nanocrystals with High Quantum Yield and High Colloidal Stability via Gel Permeation Chromatography
Published in Journal of physical chemistry. C (18-02-2021)“…Inorganic halide perovskites such as CsPbX3 (X = Cl, Br, I) have emerged as an intriguing alternative to chalcogenide and pnictide nanocrystals due to their…”
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Compact Biocompatible Quantum Dots Functionalized for Cellular Imaging
Published in Journal of the American Chemical Society (30-01-2008)“…We present a family of water-soluble quantum dots (QDs) that exhibit low nonspecific binding to cells, small hydrodynamic diameter, tunable surface charge,…”
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19
Measuring the Surface Area of Carbon Black Using BET Isotherms: An Experiment in Physical Chemistry
Published in Journal of chemical education (12-12-2023)“…We describe an experiment in which students use research-grade instrumentation to collect gas adsorption data in triplicate in a single 3 h laboratory period…”
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Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties
Published in Angewandte Chemie (International ed.) (06-04-2021)“…Acquiring fundamental knowledge of properties of actinide‐based materials is a necessary step to create new possibilities for addressing the current challenges…”
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