Search Results - "Grenèche, Jean Marc"
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A microporous multi‐cage metal–organic framework for an effective one‐step separation of branched alkanes feeds
Published in Angewandte Chemie International Edition (08-04-2024)“…The improvement of the Total Isomerization Process (TIP) for the production of high-quality gasoline with the ultimate goal of reaching a Research Octane…”
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Deciphering the Thermal and Electrochemical Behaviors of Dual Redox-Active Iron Croconate Violet Coordination Complexes
Published in Inorganic chemistry (20-06-2022)“…Interest in coordination compounds based on non-innocent ligands (NILs) for electrochemical energy storage has risen in the last few years. We have focused our…”
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Bioinspired Iron Sulfide Nanoparticles for Cheap and Long-Lived Electrocatalytic Molecular Hydrogen Evolution in Neutral Water
Published in ACS catalysis (07-02-2014)“…Alternative materials to platinum-based catalysts are required to produce molecular hydrogen from water at low overpotentials. Transition-metal chalcogenide…”
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Low-Cost Nanostructured Iron Sulfide Electrocatalysts for PEM Water Electrolysis
Published in ACS catalysis (01-04-2016)“…In the context of increased application of proton exchange membrane electrolyzers, the development of cheap and long-lived transition-metal hydrogen evolution…”
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Comparison of Porous Iron Trimesates Basolite F300 and MIL-100(Fe) As Heterogeneous Catalysts for Lewis Acid and Oxidation Reactions: Roles of Structural Defects and Stability
Published in ACS catalysis (05-10-2012)“…Two porous iron trimesates, namely, commercial Basolite F300 (Fe(BTC); BTC = 1,3,5-benzenetricarboxylate) with unknown structure and synthetic MIL-100(Fe) (MIL…”
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Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions
Published in Journal of the American Chemical Society (27-01-2010)“…The synthesis on the gram scale and characterization of a series of flexible functionalized iron terephthalate MIL-53(Fe) type solids are reported. Chemical…”
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How Defects Impact the In Vitro Behavior of Iron Carboxylate MOF Nanoparticles
Published in Chemistry of materials (09-01-2024)“…Nanoparticles of biocompatible iron carboxylate metal–organic frameworks (MOFs) or nanoMOFs are of great interest for biomedicine, in particular, for…”
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High-Pressure Synthesis of Trigonal LiFe2F6: New Iron Fluoride with Li+ Tunnels as a Potential Cathode for Lithium-Ion Batteries
Published in Journal of physical chemistry. C (19-05-2022)“…To overcome the challenge of synthesizing new and promising iron fluoride cathode materials, high-pressure synthesis was employed to obtain a new form of…”
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Biodegradable therapeutic MOFs for the delivery of bioactive molecules
Published in Chemical communications (Cambridge, England) (01-01-2010)“…A new metal organic framework (MOF) built up from non-toxic iron and the therapeutically active linker nicotinic acid, with pellagra-curative, vasodilating,…”
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Mixed-Valence Li/Fe-Based Metal-Organic Frameworks with Both Reversible Redox and Sorption Properties
Published in Angewandte Chemie (01-01-2007)“…There's more to LiFe: When used as an electrode in a lithium half cell, the metal–organic framework [LixFeIIxFeIII1−x(OH)0.8F0.2L] (L=O2CC6H4CO2) shows a…”
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Room-Temperature Bistability in Spin Crossover-Loaded Metal–Organic Frameworks
Published in Chemistry of materials (24-01-2023)“…In this article, we present an unprecedented strategy to prepare bistable porous nanocrystals based on the anchoring of switchable molecules in the pores of a…”
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Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption
Published in Angewandte Chemie (International ed.) (09-08-2010)“…Gas grabber: Reduction of the porous metal–organic framework MIL‐100(Fe) (see picture; X−: OH− or F−; red: O of trimesate ligands) to form coordinatively…”
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Synthesis, Structure, Characterization, and Redox Properties of the Porous MIL-68(Fe) Solid
Published in European Journal of Inorganic Chemistry (01-08-2010)“…A new porous FeIII‐based MOF, formulated Fe(OH)(BDC)·(dmf)x with x ≈ 1.1 and presenting the MIL‐68 topology, was prepared by reaction of an iron(III) salt and…”
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Mössbauer spectrometry insights into the redox reactivity of Fe-bearing phases in the environment
Published in Journal of materials research (28-02-2023)“…Rates and mechanisms of important reactions in the cycling of electrons via the geochemical transformations of iron have been identified using Mössbauer…”
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New Amorphous Iron-Based Oxyfluorides as Cathode Materials for High-Capacity Lithium-Ion Batteries
Published in Journal of physical chemistry. C (05-09-2019)“…A novel two-step strategy to prepare amorphous oxyfluorides, containing both divalent and trivalent 3d-metals, as cathode materials for lithium batteries is…”
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Assessing the reactivity of Fe(II) sorbed on smectite surface towards U(VI) reduction
Published in Journal of materials research (28-05-2023)“…The reactivity of Fe(II) sorbed on clay edges towards U(VI) reduction is investigated at pH 6.0 using Fe-free synthetic montmorillonite (MONT), Fe-poor natural…”
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Geochemistry and palaeo-hydrogeology of the weathered zone in the Opalinus Clay
Published in Applied clay science (01-02-2023)“…The effects of weathering and decompaction on the Opalinus Clay in northern Switzerland were studied on the basis of a 146 m long drillcore profile. Below 6 m…”
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Contribution of Mössbauer spectrometry to structural characterizations of iron-based fluorinated materials: Application to pyrochlore (NH4)CuFeF6 and a new derived hydrate
Published in Journal of materials research (28-02-2023)“…This paper brings together the latest studies on iron-based fluorides, anhydrous, hydrates, or hybrids, particularly composed of HTB sheets, with the help of…”
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Atomic scale modeling of iron-doped biphasic calcium phosphate bioceramics
Published in Acta biomaterialia (01-03-2017)“…[Display omitted] Biphasic calcium phosphates (BCPs) are bioceramics composed of hydroxyapatite (HAp, Ca10(PO4)6(OH)2) and beta-Tricalcium Phosphate (β-TCP,…”
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New Features and Uncovered Benefits of Polycrystalline Magnetite as Reusable Catalyst in Reductive Chemical Conversion
Published in Journal of physical chemistry. C (16-11-2017)“…Magnetite is one of the most well-characterized and used iron oxides in a variety of research and industrial fields. Its easy separation by magnetism has…”
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