Search Results - "Gregory R. Lumpkin"
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Perspectives on Pyrochlores, Defect Fluorites, and Related Compounds: Building Blocks for Chemical Diversity and Functionality
Published in Frontiers in chemistry (12-11-2021)“…In this article we provide some perspectives on a range of pyrochlore and defect fluorite type compounds with nominal A B O , A BO , ABC O , and other…”
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Gradual Structural Evolution from Pyrochlore to Defect-Fluorite in Y2Sn2―xZrxO7: Average vs Local Structure
Published in Journal of physical chemistry. C (19-12-2013)Get full text
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The In-Situ Quantification of Structural Radiation Damage in Zircon Using Laser-Induced Confocal Photoluminescence Spectroscopy
Published in Minerals (Basel) (01-01-2020)“…We present a new methodology for laser-induced steady-state photoluminescence (PL) spectroscopy of Dy3+ that aims at a direct quantification of the amorphous…”
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Cation antisite disorder in uranium-doped gadolinium zirconate pyrochlores
Published in Journal of nuclear materials (01-09-2014)“…The incorporation of uranium into gadolinium zirconate (Gd2Zr2O7) is investigated by synchrotron X-ray powder diffraction and X-ray absorption near-edge…”
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Ion irradiation of novel yttrium/ytterbium-based pyrochlores: The effect of disorder
Published in Acta materialia (01-12-2011)“…Pyrochlores based on the general composition Ln2TiO5 (Ln2.67Ti1.33O6.67) and Ln2Ti2O7, where Ln=Y or Yb, have been irradiated through the crystalline–amorphous…”
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The Quantification of Radiation Damage in Orthophosphates Using Confocal μ-Luminescence Spectroscopy of Nd3
Published in Frontiers in chemistry (05-02-2019)“…In this study, we present a new concept based on the steady-state, laser-induced photoluminescence of Nd 3+ , which aims at a direct determination of the…”
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Insight Into Disorder, Stress and Strain of Radiation Damaged Pyrochlores: A Possible Mechanism for the Appearance of Defect Fluorite
Published in Frontiers in chemistry (08-11-2021)“…We have examined the irradiation response of a titanate and zirconate pyrochlore—both of which are well studied in the literature individually—in an attempt to…”
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Microstructural Evolution of an Ion Irradiated Ni–Mo–Cr–Fe Alloy at Elevated Temperatures
Published in MATERIALS TRANSACTIONS (01-03-2014)“…The irradiation behavior of a Ni–Mo–Cr–Fe alloy, of the type currently being considered for use in future molten salt cooled reactors, has been investigated in…”
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Profiling hot isostatically pressed canister–wasteform interaction for Pu‐bearing zirconolite‐rich wasteforms
Published in Journal of the American Ceramic Society (01-08-2022)“…Zirconolite‐rich full ceramic wasteforms designed to immobilize Pu‐bearing wastes were produced via hot isostatic pressing (HIP) using stainless steel (SS) and…”
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Crystal chemistry and ion‐irradiation resistance of Ln2ZrO5 compounds with Ln = Sm, Eu, Gd, and Tb
Published in Journal of the American Ceramic Society (01-05-2022)“…The previously unattained fabrication of single phase Ln2ZrO5 (Ln = Sm, Eu, Gd, and Tb) compounds via relatively low sintering temperature (1400°C) is achieved…”
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Crystal structures and phase transition in the system SrTiO3-La2/3TiO3
Published in Journal of solid state chemistry (01-08-2004)Get full text
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Structures and phase diagram for the system CaTiO3-La2/3TiO3
Published in Journal of solid state chemistry (01-03-2007)Get full text
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Novel complex ceramic oxides, Ln2TiO5 (Ln = La, Sm, Gd, Tb, Dy, Ho, Er, and Yb), for polyphase nuclear waste‐forms
Published in Journal of the American Ceramic Society (01-10-2020)“…As part of a broader study of ceramic nuclear waste‐forms, four different lanthanide titanates were fabricated; La0.1Sm0.1Gd0.1Tb0.1Dy0.3Ho0.1Er0.2YbTiO5,…”
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Micro-compression testing of gold ion irradiated zirconolite glass-ceramics as nuclear waste forms
Published in Journal of nuclear materials (15-12-2019)“…The mechanical properties of zirconolite glass-ceramics designed for immobilising actinide-rich nuclear wastes, have been investigated through…”
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Ion beam irradiation of ABO4 compounds with the fergusonite, monazite, scheelite, and zircon structures
Published in Journal of the American Ceramic Society (01-10-2020)“…The effects of irradiation on CaWO4, SrWO4, BaWO4, YVO4, LaVO4, YNbO4, and LaNbO4 were investigated on thin crystals using 1.0 MeV Kr ions at 50‐1000 K. All of…”
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Porous Zr2SC-carbon composite microspheres: Possible radiation tolerant sorbents and transmutation hosts for technetium-99
Published in Microporous and mesoporous materials (15-03-2018)“…The preparation, characteristics and adsorption properties of novel porous carbon-ceramic composite microspheres are presented. The composites were synthesised…”
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Uranium Sorption on Various Forms of Titanium Dioxide – Influence of Surface Area, Surface Charge, and Impurities
Published in Environmental science & technology (01-07-2011)“…Titanium dioxide (TiO2) has often served as a model substrate for experimental sorption studies of environmental contaminants. However, various forms of…”
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Alpha-decay damage and aqueous durability of actinide host phases in natural systems
Published in Journal of nuclear materials (01-02-2001)“…This paper provides an overview of the geochemical alteration and alpha-decay damage effects observed in the titanate mineral phases brannerite, perovskite,…”
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Novel Chemical Synthesis and Characterization of CeTi2O6 Brannerite
Published in Inorganic chemistry (07-07-2014)“…Cerium titanate CeTi2O6 was prepared by a new soft chemistry route in aqueous solution. A suite of characterization techniques, including X-ray diffraction,…”
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Raman spectroscopic study of natural and synthetic brannerite
Published in Journal of nuclear materials (01-06-2013)“…Raman spectra of a well-characterized natural brannerite and some synthetic brannerite samples have been collected and analysed. For the first time, all 12…”
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