Search Results - "Greenbaum, Steve G."
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Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries
Published in Proceedings of the National Academy of Sciences - PNAS (06-02-2018)“…Lithium metal has gravimetric capacity ∼10× that of graphite which incentivizes rechargeable Li metal batteries (RLMB) development. A key factor that limits…”
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Effect of CO2 absorption on ion and water mobility in an anion exchange membrane
Published in Journal of power sources (15-03-2018)“…We report the measured water uptake, density, ionic conductivity and water transport properties in Tokuyama A201 membrane in OH−, HCO3− and Cl− forms. The…”
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3
Nuclear Magnetic Resonance Relaxation Pathways in Electrolytes for Energy Storage
Published in International journal of molecular sciences (20-06-2023)“…Nuclear Magnetic Resonance (NMR) spin relaxation times have been an instrumental tool in deciphering the local environment of ionic species, the various…”
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4
A Key concept in Magnesium Secondary Battery Electrolytes
Published in ChemSusChem (21-09-2015)“…A critical roadblock toward practical Mg‐based energy storage technologies is the lack of reversible electrolytes that are safe and electrochemically stable…”
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5
Quantifying Lithium Ion Exchange in Solid Electrolyte Interphase (SEI) on Graphite Anode Surfaces
Published in Inorganics (17-05-2022)“…Solid Electrolyte Interphase (SEI) has been identified as the most important and least understood component in lithium-ion batteries. Despite extensive studies…”
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6
Subsurface diffusion of oxide electrolyte decomposition products in metal fluoride nanocomposite electrodes
Published in Electrochimica acta (01-01-2013)“…► XPS and NMR study of interactions of electrolytes with BiF3 during conversion. ► SEI decomposes during reconversion, resulting in oxyfluoride interfacial…”
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7
NMR studies of lithium and sodium battery electrolytes
Published in Progress in nuclear magnetic resonance spectroscopy (01-08-2024)“…[Display omitted] •NMR Characterization of Battery Electrolytes.•Ion transport.•Liquid, gel, and solid-state electrolytes.•Electrolyte…”
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8
Examination of methods to determine free-ion diffusivity and number density from analysis of electrode polarization
Published in Physical review. E, Statistical, nonlinear, and soft matter physics (18-04-2013)“…Electrode polarization analysis is frequently used to determine free-ion diffusivity and number density in ionic conductors. In the present study, this…”
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9
Strengthening Aqueous Electrolytes without Strengthening Water
Published in Angewandte Chemie International Edition (28-08-2023)“…Aqueous electrolytes typically suffer from poor electrochemical stability; however, eutectic aqueous solutions—25 wt.% LiCl and 62 wt.% H3PO4—cooled to −78 °C…”
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10
The role of ozone in the formation and structural evolution of graphene oxide obtained from nanographite
Published in Carbon (New York) (01-10-2017)“…Chemical exfoliation of graphite under strong oxidizing conditions yields graphene oxide nanosheets with oxy functional groups on the carbon basal plane. The…”
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11
Alkyl chain length effects of hydroxyl-functionalized imidazolium ionic liquids in the ionothermal synthesis of LiFePO4
Published in Phosphorus, sulfur, and silicon and the related elements (27-05-2019)“…LiFePO 4 is one of the most promising cathode materials for lithium ion batteries. To investigate the role of the cation in the ionothermal synthesis of LiFePO…”
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Inorganic–organic membranes based on Nafion, [(ZrO2)·(HfO2)0.25] and [(SiO2)·(HfO2)0.28] nanoparticles. Part II: Relaxations and conductivity mechanism
Published in International journal of hydrogen energy (01-04-2012)“…Two classes of hybrid inorganic–organic proton-conducting membranes consisting of Nafion and either [(ZrO2)·(HfO2)0.25] or [(SiO2)·(HfO2)0.28] nanofiller are…”
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Journal Article Conference Proceeding -
13
Iodide-conducting polymer electrolytes based on poly-ethylene glycol and MgI2: Synthesis and structural characterization
Published in Electrochimica acta (15-12-2011)Get full text
Conference Proceeding Journal Article -
14
Multifunctional MnO2−Carbon Nanoarchitectures Exhibit Battery and Capacitor Characteristics in Alkaline Electrolytes
Published in Journal of physical chemistry. C (15-10-2009)“…We demonstrate that, when distributed as nanoscale coatings on the walls of carbon nanofoam substrates, manganese oxides exhibit voltammetric signatures in…”
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15
Strengthening Aqueous Electrolytes without Strengthening Water
Published in Angewandte Chemie (28-08-2023)“…Aqueous electrolytes typically suffer from poor electrochemical stability; however, eutectic aqueous solutions—25 wt.% LiCl and 62 wt.% H3PO4—cooled to −78 °C…”
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Journal Article -
16
Charge transfer in Li/CFx–silver vanadium oxide hybrid cathode batteries revealed by solid state 7Li and 19F nuclear magnetic resonance spectroscopy
Published in Journal of power sources (15-05-2014)“…Solid state 7Li and 19F magic angle spinning nuclear magnetic resonance (MAS NMR) experiments are conducted on several cathodes containing CFx–Silver vanadium…”
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17
A Fundamental Study of the Transport Properties of Aqueous Superacid Solutions
Published in The journal of physical chemistry. B (15-07-2010)“…An extensive investigation of the transport properties of aqueous acid solutions was undertaken. The acids studied were trifluoromethanesulfonic (CF3SO3H),…”
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Inside Back Cover: A Key concept in Magnesium Secondary Battery Electrolytes (ChemSusChem 18/2015)
Published in ChemSusChem (21-09-2015)Get full text
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19
NMR and Raman spectroscopic characterization of single walled carbon nanotube composites of polybutadiene
Published in Journal of materials research (01-07-2009)“…Significant shifts of the frequency of the Raman spectra of the tangential mode of single walled carbon nanotubes (SWNTs) and fluorinated tubes (FSWNTs) in…”
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20
Water and proton transport properties of hexafluorinated sulfonated poly(arylenethioethersulfone) copolymers for applications to proton exchange membrane fuel cells
Published in Journal of power sources (15-11-2007)“…In the present study, we examine the water and proton transport properties of hexafluorinated sulfonated poly(arylenethioethersulfone) (6F-SPTES) copolymer…”
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Journal Article Conference Proceeding