Search Results - "Green, Gary G. R."
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Iridium N-Heterocyclic Carbene Complexes as Efficient Catalysts for Magnetization Transfer from para-Hydrogen
Published in Journal of the American Chemical Society (27-04-2011)“…While the characterization of materials by NMR is hugely important in the physical and biological sciences, it also plays a vital role in medical imaging. This…”
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Toward Biocompatible Nuclear Hyperpolarization Using Signal Amplification by Reversible Exchange: Quantitative in Situ Spectroscopy and High-Field Imaging
Published in Analytical chemistry (Washington) (04-02-2014)“…Signal amplification by reversible exchange (SABRE) of a substrate and parahydrogen at a catalytic center promises to overcome the inherent insensitivity of…”
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Reversible Interactions with para-Hydrogen Enhance NMR Sensitivity by Polarization Transfer
Published in Science (American Association for the Advancement of Science) (27-03-2009)“…The sensitivity of both nuclear magnetic resonance spectroscopy and magnetic resonance imaging is very low because the detected signal strength depends on the…”
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Strategies for the Hyperpolarization of Acetonitrile and Related Ligands by SABRE
Published in The journal of physical chemistry. B (29-01-2015)“…We report on a strategy for using SABRE (signal amplification by reversible exchange) for polarizing 1H and 13C nuclei of weakly interacting ligands which…”
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Deactivation of signal amplification by reversible exchange catalysis, progress towards in vivo application
Published in Chemical communications (Cambridge, England) (18-06-2015)“…The catalyst which is used in the signal amplification by reversible exchange (SABRE) process facilitates substrate hyperpolarisation while acting to speed up…”
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Involvement of right STS in audio-visual integration for affective speech demonstrated using MEG
Published in PloS one (12-08-2013)“…Speech and emotion perception are dynamic processes in which it may be optimal to integrate synchronous signals emitted from different sources. Studies of…”
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MEG demonstrates a supra-additive response to facial and vocal emotion in the right superior temporal sulcus
Published in Proceedings of the National Academy of Sciences - PNAS (24-11-2009)“…An influential neural model of face perception suggests that the posterior superior temporal sulcus (STS) is sensitive to those aspects of faces that produce…”
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Representations of the temporal envelope of sounds in human auditory cortex: Can the results from invasive intracortical “depth” electrode recordings be replicated using non-invasive MEG “virtual electrodes”?
Published in NeuroImage (Orlando, Fla.) (01-01-2013)“…Magnetoencephalography (MEG) beamformer analyses use spatial filters to estimate neuronal activity underlying the magnetic fields measured by the MEG sensors…”
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Differential patterns of prefrontal MEG activation during verbal & visual encoding and retrieval
Published in PloS one (16-12-2013)“…The spatiotemporal profile of activation of the prefrontal cortex in verbal and non-verbal recognition memory was examined using magnetoencephalography (MEG)…”
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Neural responses to rigidly moving faces displaying shifts in social attention investigated with fMRI and MEG
Published in Neuropsychologia (01-01-2010)“…A widely adopted neural model of face perception (Haxby, Hoffman, & Gobbini, 2000) proposes that the posterior superior temporal sulcus (STS) represents the…”
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Stimulus variability affects the amplitude of the auditory steady-state response
Published in PloS one (03-04-2012)“…In this study we investigate whether stimulus variability affects the auditory steady-state response (ASSR). We present cosinusoidal AM pulses as stimuli where…”
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Utilization of SABRE-Derived Hyperpolarization To Detect Low-Concentration Analytes via 1D and 2D NMR Methods
Published in Journal of the American Chemical Society (08-08-2012)“…The characterization of materials by the inherently insensitive method of NMR spectroscopy plays a vital role in chemistry. Increasingly, hyperpolarization is…”
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13
Extracting amplitude modulations from speech in the time domain
Published in Speech communication (01-07-2011)“…Natural sounds can be characterised by patterns of changes in loudness (amplitude modulations), and human speech perception studies have focused on the low…”
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Spontaneous Transfer of Parahydrogen Derived Spin Order to Pyridine at Low Magnetic Field
Published in Journal of the American Chemical Society (23-09-2009)“…The cationic iridium complex [Ir(COD)(PCy3)(py)]BF4 (1) is shown to react with dihydrogen in the presence of pyridine (py) to form the dihydride complex…”
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Delineating between-subject heterogeneity in alpha networks with Spatio-Spectral Eigenmodes
Published in NeuroImage (Orlando, Fla.) (15-10-2021)“…•A data-driven modal decomposition describes oscillations by their resonant frequency, damping time and network structure.•We show that the full multivariate…”
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Iridium Cyclooctene Complex That Forms a Hyperpolarization Transfer Catalyst before Converting to a Binuclear C–H Bond Activation Product Responsible for Hydrogen Isotope Exchange
Published in Inorganic chemistry (21-11-2016)“…[IrCl(COE)2]2 (1) reacts with pyridine (py) and H2 to form crystallographically characterized IrCl(H)2(COE)(py)2 (2). 2 undergoes py loss to form…”
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Molecular MRI in the Earth’s Magnetic Field Using Continuous Hyperpolarization of a Biomolecule in Water
Published in The journal of physical chemistry. B (30-06-2016)“…In this work, we illustrate a method to continuously hyperpolarize a biomolecule, nicotinamide, in water using parahydrogen and signal amplification by…”
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Catalytic Transfer of Magnetism Using a Neutral Iridium Phenoxide Complex
Published in Organometallics (22-06-2015)“…A novel neutral iridium carbene complex Ir(κC,O-L1)(COD) (1) [where COD = cyclooctadiene and L1 =…”
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Para-Hydrogen Induced Polarization without Incorporation of Para-Hydrogen into the Analyte
Published in Inorganic chemistry (19-01-2009)“…The cationic iridium complexes [Ir(COD)(PR3)2]BF4 (1a-c) (a, R = Ph; b, R = p-tolyl; c, R = p-C6H4−OMe) react with parahydrogen in the presence of pyridine to…”
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Probing signal amplification by reversible exchange using an NMR flow system
Published in Magnetic resonance in chemistry (01-07-2014)“…Hyperpolarization methods are used in NMR to overcome its inherent sensitivity problem. Herein, the biologically relevant target nicotinamide is polarized by…”
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