Search Results - "Grasset, Laurent"
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Assessment of the Efficiency of Chemical and Thermochemical Depolymerization Methods for Lignin Valorization: Principal Component Analysis (PCA) Approach
Published in Polymers (04-01-2022)“…Energy demand and the use of commodity consumer products, such as chemicals, plastics, and transportation fuels, are growing nowadays. These products, which…”
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Application of Unsupervised Learning for the Evaluation of Burial Behavior of Geomaterials in Peatlands: Case of Lignin Moieties Yielded by Alkaline Oxidative Cleavage
Published in Polymers (27-02-2023)“…Tropical Peatlands accumulate organic matter (OM) and a significant source of carbon dioxide (CO ) and methane (CH ) under anoxic conditions. However, it is…”
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3
Changes in microbial community structure and function following Sphagnum peatland restoration
Published in Soil biology & biochemistry (01-02-2010)“…This study examines the recovery of the microbial compartment following active restoration of a North American ombrotrophic peatland extracted for…”
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Carbohydrates as proxies in ombrotrophic peatland: DFRC molecular method coupled with PCA
Published in Chemical geology (20-09-2022)“…Understanding organic matter (OM) dynamics in peat remains challenging as molecular-level carbohydrate studies of organic geochemistry are still generally…”
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The application of DFRC method for the analysis of carbohydrates in a peat bog: Validation and comparison with conventional chemical and thermochemical degradation techniques
Published in Chemical geology (05-07-2020)“…Traditional acid hydrolysis is the main method used for carbohydrates characterization in soils and sediments. It has been used to cleave the glycosidic bond,…”
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Distribution of PAH residues in humic and mineral fractions of sediments from stormwater infiltration basins
Published in Journal of soils and sediments (01-03-2013)“…Purpose The management of sediments from stormwater infiltration basins is nowadays a key issue for local authorities to ensure long-term performance…”
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Plant versus microbial signature in densimetric fractions of Mediterranean forest soils: a study by thermochemolysis gas chromatography mass spectrometry
Published in Journal of soils and sediments (01-01-2019)“…Purpose Soil organic matter (SOM) ageing may be measured by means of molecular signatures, ratios between organic compounds which inform us about the origin…”
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Hydrogen peroxide oxidation of humic acids and lignite
Published in Fuel (Guildford) (15-10-2014)“…The H2O2 degradation of humic acids and lignite from Mir mine (South Moravian region, Czech Republic) resulted in oxidation of aromatic structures and cleavage…”
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The application of unsupervised machine learning for the elucidation of the burial effect of lignin in peatland: Case of TMAH thermochemolysis
Published in Journal of analytical and applied pyrolysis (01-10-2024)“…Lignin is one of the major components of organic macromolecules in peatland. Analysis of lignin in sediments is considered as a valuable tool for understanding…”
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Molecular biomarkers study of an ombrotrophic peatland impacted by an anthropogenic clay deposit
Published in Organic geochemistry (01-03-2017)“…•Insight into molecular composition of an ombrotrophic peatland impacted by an anthropogenic clay deposit.•Lipids, lignin monomers and carbohydrates used as…”
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Comparison between Rock-Eval® and temperature-programmed pyrolysis/mass spectrometry for the analysis of environmental and geological samples
Published in Journal of analytical and applied pyrolysis (01-08-2023)“…Natural organic matter (OM) has a complex structure whose complete structural and chemical description remains a challenge. Rock-Eval® device constitutes a…”
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12
Orientation measurements of clay minerals by polarized attenuated total reflection infrared spectroscopy
Published in Journal of colloid and interface science (01-05-2020)“…[Display omitted] •Orientation of clay particles was examined by polarized ATR-FTIR spectroscopy.•The appropriate optical constants and equations were…”
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The characterization of South Moravian lignite in its natural and treated forms using thermal degradation methods
Published in Journal of analytical and applied pyrolysis (01-11-2017)“…•Analyses of the evolved gases and residues are mutually complementary.•The thermal stabilities of different functional groups were investigated.•Treatments of…”
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14
Ester- and ether bond cleavage in immature kerogens
Published in Organic geochemistry (01-06-1996)“…Quaternary ammonium salt Aliquat 336 and 18-Crown-6 enhance hydrolysis of Timahdit-M kerogen when used as a phase transfer catalyst. The yield of hydrolysis…”
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Journal Article Conference Proceeding -
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Experimental warming differentially affects microbial structure and activity in two contrasted moisture sites in a Sphagnum-dominated peatland
Published in The Science of the total environment (01-04-2015)“…Several studies on the impact of climate warming have indicated that peat decomposition/mineralization will be enhanced. Most of these studies deal with the…”
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16
Determination of the distribution and speciation of selenium in an argillaceous sample using chemical extractions and post-extractions analyses: application to the hydrogeological experimental site of Poitiers
Published in Environmental science and pollution research international (01-05-2016)“…To better understand selenium’s dynamics in environmental systems, the present study aims to investigate selenium speciation and distribution in black…”
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Study of water-extractable fractions from South Moravian lignite
Published in Environmental earth sciences (01-04-2015)“…Lignite can be applied directly in natural form on agricultural fields as a soil conditioner. However, there is little information on leaching of risky…”
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TMAH-preparative thermochemolysis for the characterization of organic matter in densimetric fractions of a Mediterranean forest soil
Published in Journal of analytical and applied pyrolysis (01-05-2009)“…Physical protection is one of the most important ways for stabilization of organic carbon in soils, and in order to properly manage soils as a sink for carbon,…”
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Molecular compounds generated by ruthenium tetroxide oxidation and preparative off line thermochemolysis of lignite humic acids from South Moravia: Implications for molecular structure
Published in Fuel (Guildford) (01-11-2009)“…The composition of humic acids (HAs) isolated from a South Moravian lignite deposit was examined via thermochemolysis and RuO 4 oxidation. The combination of…”
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Reactivity and transport mapping of Cu(II) ions in humic hydrogels
Published in Journal of soils and sediments (01-02-2014)“…PURPOSE: Reactivity and transport properties of metal ions are important both for evaluating and understanding role of humic substances in natural systems and…”
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