Search Results - "Grünwald, Annette"

Terminal Imido Complexes of the Groups 9–11: Electronic Structure and Developments in the Last Decade by Grünwald, Annette, Anjana, S. S., Munz, Dominik

“…We thank the Fonds der Chemischen Industrie (Liebig fellowship for D.M.), the German‐American Fulbright Commission (Fulbright‐Cottrell Award for D.M.) as well…”
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Palladium Terminal Imido Complexes with Nitrene Character by Grünwald, Annette, Goswami, Bhupendra, Breitwieser, Kevin, Morgenstern, Bernd, Gimferrer, Martí, Heinemann, Frank W., Momper, Dajana M., Kay, Christopher W. M., Munz, Dominik

“…Whereas triplet-nitrene complexes of the late transition metals are isolable and key intermediates in catalysis, singlet-nitrene ligands remain elusive. Herein…”
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Transmetalation from Magnesium–NHCs—Convenient Synthesis of Chelating π-Acidic NHC Complexes by Messelberger, Julian, Grünwald, Annette, Stegner, Philipp, Senft, Laura, Heinemann, Frank W., Munz, Dominik

“…The synthesis of chelating N-heterocyclic carbene (NHC) complexes with considerable π-acceptor properties can be a challenging task. This is due to the…”
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Oxidative Addition of Water, Alcohols, and Amines in Palladium Catalysis by Grünwald, Annette, Heinemann, Frank W., Munz, Dominik

“…The homolytic cleavage of O−H and N−H or weak C−H bonds is a key elementary step in redox catalysis, but is thought to be unfeasible for palladium. In stark…”
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Carbene derived diradicaloids - building blocks for singlet fission? by Messelberger, Julian, Grünwald, Annette, Pinter, Piermaria, Hansmann, Max M, Munz, Dominik

“…Organic singlet diradicaloids promise application in non-linear optics, electronic devices and singlet fission. The stabilization of carbon…”
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How to tame a palladium terminal imido by Grünwald, Annette, Munz, Dominik

“…Palladium terminal imido complexes hold promise as catalysts for the amination of CH bonds. This computational study elucidates the electronic structure of…”
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An Isolable Terminal Imido Complex of Palladium and Catalytic Implications by Grünwald, Annette, Orth, Nicole, Scheurer, Andreas, Heinemann, Frank W., Pöthig, Alexander, Munz, Dominik

“…Herein, we report the isolation and a reactivity study of the first example of an elusive palladium(II) terminal imido complex. This scaffold is an alleged key…”
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Elevuniversitet om energi og klima – et samarbejde i netværk: Nye perspektiver for naturfagsinteressen? "Generating science interest through network and collaboration between primary schools and university on climate and energy" by Grunwald, Annette

“…This paper address the need for developing out-reach activities in a way that can increase primary school pupils interest in science. Building on the…”
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Catalytic Functionalization of Strong Bonds by Palladium(Ii) Imido and Palladium(0) Complexes by Grünwald, Annette

“…Summary Aiming towards more sustainable chemistry, the development of efficient catalysts for the valorization of bulk and fine chemicals is a vivid area of…”
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Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation by Messelberger, Julian, Grünwald, Annette, Goodner, Stephen J, Zeilinger, Florian, Pinter, Piermaria, Miehlich, Matthias E, Heinemann, Frank W, Hansmann, Max M, Munz, Dominik

“…We elucidate why some electron rich-olefins such as tetrathiafulvalene (TTF) or paraquat (1,1′-dimethyl-4,4′-bipyridinylidene) form persistent radical cations,…”
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Bright luminescent lithium and magnesium carbene complexes by Pinter, Piermaria, Schüßlbauer, Christoph M, Watt, Fabian A, Dickmann, Nicole, Herbst-Irmer, Regine, Morgenstern, Bernd, Grünwald, Annette, Ullrich, Tobias, Zimmer, Michael, Hohloch, Stephan, Guldi, Dirk M, Munz, Dominik

“…We report on the convenient synthesis of a CNC pincer ligand composed of carbazole and two mesoionic carbenes, as well as the corresponding lithium- and…”
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Carbon Dioxide Activation by a Palladium Terminal Imido Complex by Goodner, Stephen J, Grünwald, Annette, Heinemann, Frank W, Munz, Dominik

“…We recently reported the first example of a palladium(ii) terminal imido complex. We proposed that this complex features exceptional high nucleophilicity at…”
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Carbene derived diradicaloids - building blocks for singlet fission?Electronic supplementary information (ESI) available: Atomic coordinates, energies, delineation of the choice of the active space, FOD-plots, benchmark results, correlation plots, weight of configurations, molecular orbitals. See DOI: 10.1039/c8sc01999a by Messelberger, Julian, Grünwald, Annette, Pinter, Piermaria, Hansmann, Max M, Munz, Dominik

“…Organic singlet diradicaloids promise application in non-linear optics, electronic devices and singlet fission. The stabilization of carbon…”
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals by Grünwald, Annette, Goodner, Stephen J, Munz, Dominik

“…Protocols for the isolation of the commonly employed cyclic (alkyl)(amino) carbene (CAAC) and N-heterocyclic carbene (NHC) are reported. Furthermore, the…”
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Oxidative Addition of Water, Alcohols, and Amines in Palladium Catalysis by Grünwald, Annette, Heinemann, Frank W., Munz, Dominik

“…The homolytic cleavage of O−H and N−H or weak C−H bonds is a key elementary step in redox catalysis, but is thought to be unfeasible for palladium. In stark…”
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Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation by Messelberger, Julian, Grünwald, Annette, Goodner, Stephen J., Zeilinger, Florian, Pinter, Piermaria, Miehlich, Matthias E., Heinemann, Frank W., Hansmann, Max M., Munz, Dominik

“…We elucidate why some electron rich-olefins such as tetrathiafulvalene (TTF) or paraquat (1,1′-dimethyl-4,4′-bipyridinylidene) form persistent radical cations,…”
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Correction: Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation by Messelberger, Julian, Grünwald, Annette, Goodner, Stephen J, Zeilinger, Florian, Pinter, Piermaria, Miehlich, Matthias E, Heinemann, Frank W, Hansmann, Max M, Munz, Dominik

“…Correction for 'Aromaticity and sterics control whether a cationic olefin radical is resistant to disproportionation' by Julian Messelberger et al. , Chem…”
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How lower secondary pupils work with design in green entrepreneurship in STEM education competitions by Dahl, Bettina, Grunwald, Annette

“…This paper analyses how lower secondary pupils experience their participation in the Danish science and green entrepreneurship competition, called Edison. The…”
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Ein isolierbarer terminaler Imidkomplex des Palladiums und katalytische Implikationen by Grünwald, Annette, Orth, Nicole, Scheurer, Andreas, Heinemann, Frank W., Pöthig, Alexander, Munz, Dominik

“…Wir berichten über die erste Isolierung eines terminalen Palladium(II)‐Imidkomplexes und über dessen Reaktivität. Dieses Fragment ist ein Schlüsselintermediat…”
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Ein isolierbarer terminaler Imidkomplex des Palladiums und katalytische Implikationen by Grünwald, Annette, Orth, Nicole, Scheurer, Andreas, Heinemann, Frank W, Pöthig, Alexander, Munz, Dominik

“…Wir berichten über die erste Isolierung eines terminalen Palladium(II)‐Imidkomplexes und über dessen Reaktivität. Dieses Fragment ist ein Schlüsselintermediat…”
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