Search Results - "Grün, Alajos"
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Asymmetric cyclopropanation reactions catalyzed by carbohydrate-based crown ethers
Published in Tetrahedron (05-07-2018)“…Optically active cyclopropane derivatives were prepared by a novel, simple and green approach in high enantioselectivities using monosaccharide-based chiral…”
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2
Synthesis of Hydroxymethylenebisphosphonic Acid Derivatives in Different Solvents
Published in Molecules (Basel, Switzerland) (11-08-2016)“…The syntheses of hydroxymethylenebisphosphonic acid derivatives (dronic acid derivatives) starting from the corresponding substituted acetic acids and…”
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3
Crown ether derived from d-glucose as an efficient phase-transfer catalyst for the enantioselective Michael addition of malonates to enones
Published in Tetrahedron: asymmetry (15-10-2016)“…[Display omitted] A monoaza-15-crown-5 lariat ether derived from d-glucose 1 has been applied as a chiral phase-transfer catalyst in the Michael addition of…”
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4
Stereoselective synthesis of trans-dihydronarciclasine derivatives containing a 1,4-benzodioxane moiety
Published in Monatshefte für Chemie (2018)“…Some new trans -dihydronarciclasine derivatives containing a 1,4-benzodioxane moiety were stereoselectively synthesised using our feasible and efficient method…”
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5
Solid-Liquid Phase C-Alkylation of Active Methylene Containing Compounds under Microwave Conditions
Published in Catalysts (01-06-2015)“…The solid–liquid phase C-alkylation of active methylene containing compounds with C=O or P=O functions under phase transfer catalysis or microwave conditions…”
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6
“Greener” synthesis of bisphosphonic/dronic acid derivatives
Published in Green processing and synthesis (01-04-2014)“…According to literature, the synthesis of dronic acid derivatives from the corresponding carboxylic acids using phosphorus trichloride and phosphorous acid as…”
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7
Synthesis and alkali cation extraction ability of 1,3-alt-thiacalix[4]bis(crown) ethers
Published in Tetrahedron letters (03-06-2002)“…The first representatives of 1,3-alt-thiacalix[4]arene bis(crown-5 and -6) ethers were synthesized by the cyclocondensation of thiacalix[4]arenes with…”
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8
Synthesis and alkali cation extraction ability of 1,3-alt-thiacalix[4]mono(crown) ethers
Published in Tetrahedron letters (14-10-2002)“…The first representatives of 1,3-alt-thiacalix[4]mono(crown-5 and -6) ethers were synthesized by the cyclocondensation of 25,27-dialkoxythiacalix[4]arenes with…”
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9
Green Chemical Tools in Organophosphorus Chemistry-Organophosphorus Tools in Green Chemistry
Published in Phosphorus, sulfur, and silicon and the related elements (31-03-2011)“…A variety of reactions including esterifications, alkylations, additions, cycloadditions, fragmentations, and condensations were carried out under microwave…”
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10
The First Enantioselective Total Synthesis of (−)-trans-Dihydronarciclasine
Published in Journal of natural products (Washington, D.C.) (23-06-2017)“…A feasible and enantioselective total synthesis of (−)-trans-dihydronarciclasine [(−)-1], a highly biologically active alkaloid, was devised starting from…”
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11
Synthetic study on the T3P®-promoted one-pot preparation of 1-substituted-3,4-dihydro-β-carbolines by the reaction of tryptamine with carboxylic acids
Published in Tetrahedron letters (04-05-2016)“…[Display omitted] •Novel one-pot method for β-carboline synthesis from tryptamine.•Beneficial synergy of the MW irradiation with a green reagent.•Efficient…”
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12
Synthesis of l‐threitol‐based crown ethers and their application as enantioselective phase transfer catalyst in Michael additions
Published in Chirality (New York, N.Y.) (01-06-2017)“…A few new l‐threitol‐based lariat ethers incorporating a monoaza‐15‐crown‐5 unit were synthesized starting from diethyl l‐tartrate. These macrocycles were used…”
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13
Enantioselective Michael addition of malonates to aromatic nitroalkenes catalyzed by monosaccharide-based chiral crown ethers
Published in Tetrahedron: asymmetry (31-01-2014)“…The asymmetric Michael addition of diethyl malonate and α-substituted diethyl malonates to aromatic nitroalkenes was carried out under mild reaction conditions…”
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14
The synthesis of hydroxymethylenebisphosphonic- (dronic-) and acyl-ethoxycarbonyl-methylphosphonate derivatives
Published in Phosphorus, sulfur, and silicon and the related elements (22-06-2022)“…Recent results on the synthesis of substituted hydroxymethylenebisphosphonic acids (A and B), as well as acylated ethoxycarbonyl-methylphosphonate derivatives…”
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15
Proton dissociation properties of arylphosphonates: Determination of accurate Hammett equation parameters
Published in Journal of pharmaceutical and biomedical analysis (05-09-2017)“…[Display omitted] •Determination of the proton dissociation constants of arylphosphonic acid derivatives.•Comparison of our experimental values to predicted…”
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16
Efficient syntheses of zoledronic acid as an active ingredient of a drug against osteoporosis
Published in Synthetic communications (19-03-2018)“…The reaction of 1H-imidazol-1-ylacetic acid and two equivalents of phosphorus trichloride/phosphorous acid at 75 °C in sulfolane, or in the presence of…”
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17
Asymmetric C–C bond formation via Darzens condensation and Michael addition using monosaccharide-based chiral crown ethers
Published in Tetrahedron letters (30-03-2011)“…Liquid–liquid phase asymmetric Darzens condensations were promoted by d-glucose- and d-mannose-based crown ethers. The corresponding aromatic and…”
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18
Microwave irradiation and catalysis in organophosphorus chemistry
Published in Phosphorus, sulfur, and silicon and the related elements (27-05-2019)“…The possible combinations and connections of microwave (MW) and catalysts are discussed. MW-assisted reactions, such as the direct esterification or the…”
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19
Calixarene/Nafion-Modified Bismuth-Film Electrodes for Adsorptive Stripping Voltammetric Determination of Lead
Published in Electroanalysis (New York, N.Y.) (01-09-2009)“…This paper presents an enhanced adsorptive stripping voltammetric procedure (AdSV) for the determination of Pb2+, which relies on the accumulation of the…”
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20
Green chemical syntheses and applications within organophosphorus chemistry
Published in Structural chemistry (01-04-2017)“…Application of the microwave (MW) technique offers many advantages in organophosphorus syntheses. Reluctant reactions may take place on MW irradiation. In most…”
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