Search Results - "Gour, Kritika"
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N-heterocyclic carbene supported halosilylenes: New frontiers in an emerging field
Published in Coordination chemistry reviews (15-12-2018)“…[Display omitted] •Synthesis, spectral properties and structural futures of NHC stabilized halosilylene have been reviewed.•Reactions of NHC stabilized…”
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2
Readily available lithium compounds as catalysts for the hydroboration of carbodiimides and esters
Published in Journal of organometallic chemistry (15-09-2021)“…(a)The catalytic application of organolithium compounds is very limited due to their high reactivity and aggregation phenomena. However, the paradigm started…”
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Activation of the Olefinic C–H Bond of NHC and NHO by Perimidine-Based Silicon and Germanium Compounds
Published in Organometallics (14-08-2023)“…In this manuscript, several backbone germylene-functionalized zwitterionic compounds were prepared conveniently from the corresponding N-heterocyclic carbenes…”
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4
The Hypersilyl Substituent in Heavier Low‐Valent Group 14 Chemistry
Published in European journal of inorganic chemistry (20-04-2022)“…The isolation of unusual compounds with low‐valent main‐group elements would not have been possible without the development of a series of sterically demanding…”
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Germylene Mediated Reductive C-C and C‒N Coupling of an Isocyanide and its Device Application
Published in Angewandte Chemie International Edition (09-11-2024)“…We have demonstrated a unique reductive coupling of 4-iodophenyl isocyanide, facilitated by a perimidine-based N-heterocyclic germylene (NHGe), which yields a…”
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6
Six‐Membered NHC Stabilized Monomeric Zinc Complexes
Published in European journal of inorganic chemistry (25-07-2023)“…This paper describes the rare use of a 6‐membered saturated N‐heterocyclic carbene (NHC) known as 1,3‐di(2,6‐diisopropylphenyl) tetrahydropyrimidine‐2‐ylidene…”
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Germylene Mediated Reductive C−C and C−N Coupling of an Isocyanide and its Device Application
Published in Angewandte Chemie (09-11-2024)“…We have demonstrated a unique reductive coupling of 4‐iodophenyl isocyanide, facilitated by a perimidine‐based N‐heterocyclic germylene (NHGe), which yields a…”
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A Tale of Biphenyl and Terphenyl Substituents for Structurally Diverse Ketiminato Magnesium, Calcium and Germanium Complexes
Published in Chemistry, an Asian journal (16-03-2020)“…In this paper, we have used two N,O‐ketiminato ligands (L1 and L2) with biphenyl and terphenyl substituent on the nitrogen atom. Deprotonation of L1 with…”
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