Search Results - "Goulas, Konstantinos A."
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Synergistic Effects in Bimetallic Palladium–Copper Catalysts Improve Selectivity in Oxygenate Coupling Reactions
Published in Journal of the American Chemical Society (01-06-2016)“…Condensation reactions such as Guerbet and aldol are important since they allow for C–C bond formation and give higher molecular weight oxygenates. An initial…”
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Syngas production from polyolefins in a semi‐batch reactor system
Published in AIChE journal (01-12-2021)“…We investigate syngas production from polyolefins commonly found in solid waste in a semi‐batch reactor system via gasification and catalytic reforming. We…”
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3
Combining microbial production with chemical upgrading
Published in Current opinion in biotechnology (01-04-2016)“…Graphical abstract…”
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4
Acylation of methylfuran with Brønsted and Lewis acid zeolites
Published in Applied catalysis. A, General (25-08-2018)“…[Display omitted] •Lewis and Bronsted acidic zeolites are compared for acylation of methylfuran and furan.•Bronsted acid zeolite beta shows the highest…”
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Highly Selective Condensation of Biomass-Derived Methyl Ketones as a Source of Aviation Fuel
Published in ChemSusChem (22-05-2015)“…Aviation fuel (i.e., jet fuel) requires a mixture of C9–C16 hydrocarbons having both a high energy density and a low freezing point. While jet fuel is…”
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Direct Catalytic Conversion of Ethanol to C5+ Ketones: Role of Pd–Zn Alloy on Catalytic Activity and Stability
Published in Angewandte Chemie International Edition (17-08-2020)“…Ethanol can be used as a platform molecule for synthesizing valuable chemicals and fuel precursors. Direct synthesis of C5+ ketones, building blocks for…”
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110th Anniversary: Kinetics and X‑ray Absorption Spectroscopy in Methane Total Oxidation over Alumina-Supported Pt, Pd, and Ag–Pd Catalysts
Published in Industrial & engineering chemistry research (25-09-2019)“…The kinetics of methane oxidation over Pt/Al2O3, Pd/Al2O3, and Ag–Pd/Al2O3 is investigated as a function of the O2/CH4 ratio. We show that as the oxygen…”
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X-ray tomography measurements identify structure-reactivity correlations in catalysts for oxygenates coupling reactions
Published in Catalysis today (01-10-2019)“…[Display omitted] •Reactivity of supported PdCu nanoparticles in aldol-condensation reaction was tested.•Particles stability was identified by X-ray tomography…”
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PdCu Alloy Catalyst for Inhibition‐free, Low‐temperature CO Oxidation
Published in ChemCatChem (08-01-2024)“…Designing robust catalysts for low‐temperature oxidation is pertinent to the development of advanced combustion engines to meet increasingly stringent…”
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Oxidation of aromatic oxygenates for the production of terephthalic acid
Published in Applied catalysis. A, General (25-02-2018)“…[Display omitted] •Oxidation of di-hydroxymethyl-benzene at mild conditions over an Ir catalyst results in a yield of 76% terephthalic acid.•In this process,…”
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Transition metal oxides in CO2 driven oxidative dehydrogenation: Uncovering their redox properties
Published in Journal of CO2 utilization (01-06-2024)“…Extensive research efforts have been devoted to using greenhouse gas CO2 in upgrading bio-derived feedstock to value-added chemicals using the oxidative…”
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Kinetics of the Homogeneous and Heterogeneous Coupling of Furfural with Biomass‐Derived Alcohols
Published in ChemCatChem (07-06-2018)“…The tandem dehydrogenation and aldol condensation of butanol with furfural was investigated over homogeneous and heterogeneous catalysts using kinetics and…”
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ABE Condensation over Monometallic Catalysts: Catalyst Characterization and Kinetics
Published in ChemCatChem (21-02-2017)“…Herein, we present work on the catalyst development and the kinetics of acetone‐butanol‐ethanol (ABE) condensation. After examining multiple combinations of…”
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14
Thermal stability of mobility in methylammonium lead iodide
Published in JPhys materials (13-01-2020)“…Metal halide perovskites (MHPs) are a fascinating class of photovoltaic materials; possessing distinctive optoelectronic properties and simple processing…”
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15
Hybrid Biological–Chemical Approach Offers Flexibility and Reduces the Carbon Footprint of Biobased Plastics, Rubbers, and Fuels
Published in ACS sustainable chemistry & engineering (05-11-2018)“…A critical challenge for the bioenergy research community has been producing drop-in hydrocarbon fuels and chemicals at yields sufficient to compete with their…”
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Direct Catalytic Conversion of Ethanol to C5+ Ketones: Role of Pd–Zn Alloy on Catalytic Activity and Stability
Published in Angewandte Chemie (17-08-2020)“…Ethanol can be used as a platform molecule for synthesizing valuable chemicals and fuel precursors. Direct synthesis of C5+ ketones, building blocks for…”
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Back Cover: Highly Selective Condensation of Biomass-Derived Methyl Ketones as a Source of Aviation Fuel (ChemSusChem 10/2015)
Published in ChemSusChem (22-05-2015)“…The Back Cover shows a depiction of the carbon cycle for a tunable set of chemistry that can be used to synthesize exceptional jet fuel via n-alkyl methyl…”
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Spectroscopic determination of metal redox and segregation effects during CO and CO/NO oxidation over silica-supported Pd and PdCu catalysts
Published in Applied catalysis. B, Environmental (01-03-2024)“…We report the effects of alloying Cu into silica supported Pd nanoparticles on the catalytic activity, surface composition, and particle structure during CO…”
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19
Upcycling of polyvinyl chloride to hydrocarbon waxes via dechlorination and catalytic hydrogenation
Published in Applied catalysis. B, Environmental (05-12-2023)“…Converting polymer waste to marketable products is a promising method to incentivize the development of competitive waste upcycling processes. Polyvinyl…”
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Spectroscopic determination of metal redox and segregation effects during CO and CO/NO oxidation over silica-supported Pd and PdCu catalysts
Published in Applied catalysis. B, Environmental (26-09-2023)“…Here, we report the effects of alloying Cu into silica supported Pd nanoparticles on the catalytic activity, surface composition, and particle structure during…”
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