Search Results - "Gotsch, Thomas"
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Atomic Insights into the Competitive Edge of Nanosheets Splitting Water
Published in Journal of the American Chemical Society (09-10-2024)“…The oxygen evolution reaction (OER) provides the protons for many electrocatalytic power-to-X processes, such as the production of green hydrogen from water or…”
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Rhodium-Catalyzed Methanation and Methane Steam Reforming Reactions on Rhodium-Perovskite Systems: Metal-Support Interaction
Published in ChemCatChem (21-06-2016)“…Metal–support interaction in rhodium–perovskite systems was studied using LSF (La0.6Sr0.4FeO3−δ) and STF (SrTi0.7Fe0.3O3−δ) supports to disentangle different…”
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The state of zinc in methanol synthesis over a Zn/ZnO/Cu(211) model catalyst
Published in Science (American Association for the Advancement of Science) (06-05-2022)“…The active chemical state of zinc (Zn) in a zinc-copper (Zn-Cu) catalyst during carbon dioxide/carbon monoxide (CO /CO) hydrogenation has been debated to be Zn…”
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Increasing Complexity Approach to the Fundamental Surface and Interface Chemistry on SOFC Anode Materials
Published in Accounts of chemical research (15-09-2020)“…Conspectus In this Account, we demonstrate an increasing complexity approach to gain insight into the principal aspects of the surface and interface chemistry…”
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Surface Chemistry of Perovskite-Type Electrodes During High Temperature CO2 Electrolysis Investigated by Operando Photoelectron Spectroscopy
Published in ACS applied materials & interfaces (18-10-2017)“…Any substantial move of energy sources from fossil fuels to renewable resources requires large scale storage of excess energy, for example, via power to fuel…”
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Surface Carbon as a Reactive Intermediate in Dry Reforming of Methane to Syngas on a 5% Ni/MnO Catalyst
Published in ACS catalysis (07-09-2018)“…A 5% Ni/MnO catalyst has been tested for the dry reforming of methane at different temperatures and reactant partial pressures. Changing the reactant ratio…”
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Preferentially Oriented TiO2 Nanotubes as Anode Material for Li-Ion Batteries: Insight into Li-Ion Storage and Lithiation Kinetics
Published in ACS applied materials & interfaces (25-10-2017)“…Self-organized TiO2 nanotubes (NTs) with a preferential orientation along the [001] direction are anodically grown by controlling the water content in the…”
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Enhancing the Catalytic Activity of Palladium Nanoparticles via Sandwich-Like Confinement by Thin Titanate Nanosheets
Published in ACS catalysis (05-03-2021)“…As atomically thin oxide layers deposited on flat (noble) metal surfaces have been proven to have a significant influence on the electronic structure and thus…”
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Structural Analysis and Redox Properties of Oxygen-“Breathing” A(Mn1–x Cu x )O3 (A = La, Pr) Perovskites
Published in Chemistry of materials (11-06-2024)“…The redox properties of perovskites play an important role in their use in thermo- and electrocatalytic applications. Here, we report the effects of…”
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True Nature of the Transition-Metal Carbide/Liquid Interface Determines Its Reactivity
Published in ACS catalysis (16-04-2021)“…Compound materials, such as transition-metal (TM) carbides, are anticipated to be effective electrocatalysts for the carbon dioxide reduction reaction (CO2RR)…”
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Enhanced Kinetic Stability of Pure and Y‑Doped Tetragonal ZrO2
Published in Inorganic chemistry (15-12-2014)“…The kinetic stability of pure and yttrium-doped tetragonal zirconia (ZrO2) polymorphs prepared via a pathway involving decomposition of pure zirconium and…”
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Synthetic Access to Cubic Rare Earth Molybdenum Oxides RE6MoO12−δ (RE = Tm–Lu) Representing a New Class of Ion Conductors
Published in Chemistry of materials (25-10-2016)“…Materials crystallizing in highly symmetric structures are of particular interest as they display superior physical properties in many relevant technological…”
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Microstructural and Chemical Evolution and Analysis of a Self-Activating CO2‑Selective Cu–Zr Bimetallic Methanol Steam Reforming Catalyst
Published in Journal of physical chemistry. C (10-11-2016)“…The microstructure of the CO2-selective self-activating and self-stabilizing Cu–Zr bimetallic compound Cu51Zr14 has been studied by a combination of…”
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CO2 Reduction on the Pre-reduced Mixed Ionic-Electronic Conducting Perovskites La0.6Sr-0.4FeO3-[delta] and SrTi0.7Fe0.3O3-[delta]
Published in Chemphyschem (05-01-2018)“…The activity of the pre-reduced perovskites La0.6Sr0.4FeO3-[delta] (LSF64) and SrTi0.7Fe0.3O3-[delta] (STF73) for the CO2 reduction to CO was investigated with…”
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Structural and Catalytic Properties of Ag- and Co3O4‑Impregnated Strontium Titanium Ferrite SrTi0.7Fe0.3O3−δ in Methanol Steam Reforming
Published in Industrial & engineering chemistry research (22-11-2017)“…The catalytic performance of Ag- and Co3O4-impregnated strontium titanium ferrite (SrTi0.7Fe0.3O3−δ, STF) has been assessed in methanol steam reforming as a…”
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Cubic Bixbyite‐Structured Phases of Yb6MoO12 and Y6MoO12 Prepared by the Solution Combustion Method at Low Temperatures
Published in European journal of inorganic chemistry (18-04-2017)“…For the first time, Yb6MoO12 was synthesized in the cubic bixbyite structure type (Ia3) under low‐temperature conditions. The solution combustion method was…”
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The Nanoscale Kirkendall Effect in Pd-Based Intermetallic Phases
Published in Journal of physical chemistry. C (07-08-2014)“…Hollow particles of Pd–X intermetallic phases (X = Ga, Ge, Sn) are prepared by reduction of the respective oxide-supported Pd/XO2 and Pd/X2O3 thin films via…”
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From zirconia to yttria: Sampling the YSZ phase diagram using sputter-deposited thin films
Published in AIP advances (01-02-2016)“…Yttria-stabilized zirconia (YSZ) thin films with varying composition between 3 mol% and 40 mol% have been prepared by direct-current ion beam sputtering at a…”
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Preparation and characterization of epitaxially grown unsupported yttria-stabilized zirconia (YSZ) thin films
Published in Applied surface science (15-03-2015)“…[Display omitted] •Preparation of unsupported yttrium-stabilized zirconia films.•Control of ordering and epitaxy by temperature of deposition…”
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Halogen Phases on Pd(110): Compression Structures, Domain Walls, and Corrosion
Published in Journal of physical chemistry. C (19-02-2015)“…Halogens are used as modifiers in catalytic processes, notably including photocatalytic watersplitting; as redox-active species in dye-sensitized solar cells;…”
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