Search Results - "Gordon, John C."

Metal–Ligand Bifunctional Catalysis: The “Accepted” Mechanism, the Issue of Concertedness, and the Function of the Ligand in Catalytic Cycles Involving Hydrogen Atoms by Dub, Pavel A, Gordon, John C

“…For years, following the ideas of Shvo and Noyori, the core assumption of metal–ligand bifunctional molecular catalysis has relied on the direct involvement of…”
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The role of the metal-bound N–H functionality in Noyori-type molecular catalysts by Dub, Pavel A., Gordon, John C.

“…Noyori-type catalysts have found numerous applications in research and industrial settings. The central mechanistic component of such catalysts is a metal…”
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Why Does Alkylation of the N–H Functionality within M/NH Bifunctional Noyori-Type Catalysts Lead to Turnover? by Dub, Pavel A, Scott, Brian L, Gordon, John C

“…Molecular metal/NH bifunctional Noyori-type catalysts are remarkable in that they are among the most efficient artificial catalysts developed to date for the…”
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Efficient Regeneration of Partially Spent Ammonia Borane Fuel by Davis, Benjamin L., Dixon, David A., Garner, Edward B., Gordon, John C., Matus, Myrna H., Scott, Brian, Stephens, Frances H.

“…Going full circle: Ammonia borane is a potential H2‐releasing fuel. Polyborazylene, a form of the spent fuel, can be regenerated efficiently in a one‐pot…”
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Importance of Out-of-State Spin–Orbit Coupling for Slow Magnetic Relaxation in Mononuclear FeII Complexes by Lin, Po-Heng, Smythe, Nathan C, Gorelsky, Serge I, Maguire, Steven, Henson, Neil J, Korobkov, Ilia, Scott, Brian L, Gordon, John C, Baker, R. Tom, Murugesu, Muralee

“…Two mononuclear high-spin FeII complexes with trigonal planar ([FeII(N(TMS)2)2(PCy3)] (1) and distorted tetrahedral ([FeII(N(TMS)2)2(depe)] (2) geometries are…”
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Iron Complex-Catalyzed Ammonia–Borane Dehydrogenation. A Potential Route toward B–N-Containing Polymer Motifs Using Earth-Abundant Metal Catalysts by Baker, R. Tom, Gordon, John C, Hamilton, Charles W, Henson, Neil J, Lin, Po-Heng, Maguire, Steven, Murugesu, Muralee, Scott, Brian L, Smythe, Nathan C

“…Ammonia–borane (NH3BH3, AB) has garnered interest as a hydrogen storage material due to its high weight percent hydrogen content and ease of H2 release…”
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Aerobic Oxidation of Lignin Models Using a Base Metal Vanadium Catalyst by Hanson, Susan K, Baker, R. Tom, Gordon, John C, Scott, Brian L, Thorn, David L

“…Dipicolinate vanadium(V) complexes oxidize lignin model complexes pinacol monomethyl ether (A), 2-phenoxyethanol (B), 1-phenyl-2-phenoxyethanol (C), and…”
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Methodology to calculate forest stand level maximum potential productivity, potential achievable productivity and ecosystem fit by Klock, Angela M., Vogt, Kristiina A., Vogt, Daniel J., Gordon, John C.

“…A modified Loomis-William model was originally developed to estimate the theoretical maximum yields of crops. That model was adapted in this paper to measure…”
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Design, synthesis, and evaluation of (2S,4R)-Ketoconazole sulfonamide analogs as potential treatments for Metabolic Syndrome by Blass, Benjamin E., Iyer, Pravin, Abou-Gharbia, Magid, Childers, Wayne E., Gordon, John C., Ramanjulu, Mercy, Morton, George, Arumugam, Premkumar, Boruwa, Joshodeep, Ellingboe, John, Mitra, Sayan, Nimmareddy, Rajashekar Reddy, Paliwal, Shalini, Rajasekhar, Jamallamudi, Shivakumar, Savithiri, Srivastava, Pratima, Tangirala, Raghuram S., Venkataramanaiah, Konda, Yanamandra, Mahesh

“…[Display omitted] Metabolic Syndrome, also referred to as ‘Syndrome X’ or ‘Insulin Resistance Syndrome,’ remains a major, unmet medical need despite over…”
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Ammonia Borane as a Hydrogen Carrier: Dehydrogenation and Regeneration by Smythe, Nathan C., Gordon, John C.

“…Interest in sustainable non‐hydrocarbon‐based fuels for transportation has grown as the realization that the supply of fossil fuels is limited and the…”
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Unravelling the Mechanism of the Asymmetric Hydrogenation of Acetophenone by [RuX2(diphosphine)(1,2-diamine)] Catalysts by Dub, Pavel A, Henson, Neil J, Martin, Richard L, Gordon, John C

“…The mechanism of catalytic hydrogenation of acetophenone by the chiral complex trans-[RuCl2{(S)-binap}{(S,S)-dpen}] and KO-t-C4H9 in propan-2-ol is revised on…”
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Mediating Oxidation States in Decamethyleuropocene Complexes. The Role of the Diazabutadiene Fragment by Moore, Jennifer A, Cowley, Alan H, Gordon, John C

“…The Eu diazabutadiene complexes (C5Me5)2Eu(DADBu-t) and (C5Me5)2Eu(DADC6F5) (DADBu-t = t-BuNC(H)C(H)NBu-t; DADC6F5 = C6F5NC(Me)C(Me)NC6F5) have been prepared,…”
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The hydrodeoxygenation of bioderived furans into alkanes by Sutton, Andrew D., Waldie, Fraser D., Wu, Ruilian, Schlaf, Marcel, ‘Pete’ Silks, Louis A., Gordon, John C.

“…The conversion of biomass into fuels and chemical feedstocks is one part of a drive to reduce the world's dependence on crude oil. For transportation fuels in…”
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Synthesis and Characterization of (Mono)pentamethylcyclopentadienyl Lutetium Complexes:  Formation of Bipyridyl-Stabilized Alkyls, Anilides, and Terminal Acetylides by Cameron, Thomas M, Gordon, John C, Scott, Brian L

“…The alkyl complex [Lu(CH2SiMe3)3(THF)2] reacts with pentamethylcyclopentadiene (Cp*H), giving [Cp*Lu(CH2SiMe3)2(THF)] (1). Complex 1 reacts with…”
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Regeneration of Ammonia Borane Spent Fuel by Direct Reaction with Hydrazine and Liquid Ammonia by Sutton, Andrew D., Burrell, Anthony K., Dixon, David A., Garner, Edward B., Gordon, John C., Nakagawa, Tessui, Ott, Kevin C., Robinson, J. Pierce, Vasiliu, Monica

“…Ammonia borane (H₃N-BH₃, AB) is a lightweight material containing a high density of hydrogen (H₂) that can be readily liberated for use in fuel cell—powered…”
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Perspectives on How Nature Employs the Principles of Organometallic Chemistry in Dihydrogen Activation in Hydrogenases by Gordon, John C, Kubas, Gregory J

“…Relatively recent developments in metalloenzyme and organometallic chemistry have targeted a growing link between these outwardly incongruous fields, giving…”
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Air-Stable NNS (ENENES) Ligands and Their Well-Defined Ruthenium and Iridium Complexes for Molecular Catalysis by Dub, Pavel A, Scott, Brian L, Gordon, John C

“…We introduce ENENES, a new family of air-stable and low-cost NNS ligands bearing NH functionalities of the general formula E­(CH2) m NH­(CH2) n SR, where E is…”
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Synthesis and Characterization of Cerium(IV) Metallocenes by Sutton, Andrew, Clark, David, Scott, Brian, Gordon, John

“…By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we…”
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Glutamate metabolism in HIV-1 infected macrophages: Role of HIV-1 Vpr by Datta, Prasun K, Deshmane, Satish, Khalili, Kamel, Merali, Salim, Gordon, John C, Fecchio, Chiara, Barrero, Carlos A

“…HIV-1 infected macrophages play a significant role in the neuropathogenesis of AIDS. HIV-1 viral protein R (Vpr) not only facilitates HIV-1 infection but also…”
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H++: a server for estimating pKas and adding missing hydrogens to macromolecules by Gordon, John C., Myers, Jonathan B., Folta, Timothy, Shoja, Valia, Heath, Lenwood S., Onufriev, Alexey

“…The structure and function of macromolecules depend critically on the ionization (protonation) states of their acidic and basic groups. A number of existing…”
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