Search Results - "Golovanov, Ivan"
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Benzothiadiazole vs. iso-Benzothiadiazole: Synthesis, Electrochemical and Optical Properties of D–A–D Conjugated Molecules Based on Them
Published in Molecules (Basel, Switzerland) (14-08-2021)“…This paper presents an improved synthesis of 4,7-dibromobenzo[d][1,2,3]thiadiazole from commercially available reagents. According to quantum-mechanical…”
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Crown-hydroxylamines are pH-dependent chelating N,O-ligands with a potential for aerobic oxidation catalysis
Published in Nature communications (23-11-2023)“…Despite the rich coordination chemistry, hydroxylamines are rarely used as ligands for transition metal coordination compounds. This is partially because of…”
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Merging Boron with Nitrogen–Oxygen Bonds: A Review on BON Heterocycles
Published in Topics in current chemistry (2016) (01-04-2021)“…Cyclic boronate esters play important roles in organic synthesis, pharmacology, supramolecular chemistry and materials science owing to their stability in air…”
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Lack of transgenerational effects of ionizing radiation exposure from the Chernobyl accident
Published in Science (American Association for the Advancement of Science) (14-05-2021)“…Effects of radiation exposure from the Chernobyl nuclear accident remain a topic of interest. We investigated germline de novo mutations (DNMs) in children…”
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The Cyclic Nitronate Route to Pharmaceutical Molecules: Synthesis of GSK's Potent PDE4 Inhibitor as a Case Study
Published in Molecules (Basel, Switzerland) (08-08-2020)“…An efficient asymmetric synthesis of GlaxoSmithKline's potent PDE4 inhibitor was accomplished in eight steps from a catechol-derived nitroalkene. The key…”
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Construction of Saturated Oxazolo[3,2‑b][1,2]oxazines via Tandem [3+2]-Cycloaddition/[1,3]-Rearrangement of Cyclic Nitronates and Ketenes
Published in Journal of organic chemistry (03-12-2021)“…Reaction of six-membered cyclic nitronates with disubstituted ketenes affords hitherto unknown saturated oxazolo[3,2-b][1,2]oxazines possessing up to four…”
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Synthesis of the 4,7‐Dibromo Derivative of Highly Electron‐Deficient [1,2,5]Thiadiazolo[3,4‐d]pyridazine and Its Cross‐Coupling Reactions
Published in European journal of organic chemistry (08-11-2018)“…An efficient synthesis of 4,7‐dibromo[1,2,5]thiadiazolo[3,4‐d]pyridazine is reported. For the first time, palladium‐catalysed cross‐coupling reactions of a…”
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1,4,6,10-Tetraazaadamantanes (TAADs) with N -amino groups: synthesis and formation of boron chelates and host–guest complexes
Published in Beilstein journal of organic chemistry (11-10-2022)“…A synthetic route to 1,4,6,10-tetraazaadamantanes (TAADs) bearing free and protected amino groups at the bridge N -atoms has been developed via intramolecular…”
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Divergent Reactivity of In Situ Generated Metal Azides: Reaction with N,N‐Bis(oxy)enamines as a Case Study
Published in Chemistry : a European journal (03-04-2017)“…Metal azides generated in situ by ion exchange exhibit divergent reactivity in reaction with cyclic N‐alkoxy,N‐siloxy‐enamines. Depending on the nature of…”
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Tandem Deoxygenation/Halogenation of N‐Oxides Under Acylation Conditions: Scope and In Situ IR Spectroscopic Study
Published in European journal of organic chemistry (14-07-2019)“…Acylation of cyclic nitronates with acyl bromides produces 3‐bromomethyl‐substituted 5,6‐dihydro‐2H‐1,2‐oxazines via an unusual multi‐stage process involving…”
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Addition of HO‐Acids to N,N‐Bis(oxy)enamines: Mechanism, Scope and Application to the Synthesis of Pharmaceuticals
Published in European journal of organic chemistry (09-11-2017)“…The regioselectivity of the addition of HO‐acids to the activated π bond in N,N‐bis(oxy)enamines has been found to be dramatically dependent upon the solvent…”
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Acylation of Nitronates: [3,3]-Sigmatropic Rearrangement of in Situ Generated N‑Acyloxy,N‑oxyenamines
Published in Journal of organic chemistry (21-09-2018)“…Acylation of nitronates affords α-acyloxyoxime derivatives via an umpolung functionalization of the α-position. This transformation involves generation of…”
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Radiation and the risk of chronic lymphocytic and other leukemias among chornobyl cleanup workers
Published in Environmental health perspectives (01-01-2013)“…Risks of most types of leukemia from exposure to acute high doses of ionizing radiation are well known, but risks associated with protracted exposures, as well…”
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Risk of thyroid cancer in Ukrainian cleanup workers following the Chornobyl accident
Published in European journal of epidemiology (01-01-2022)“…Although much is known about the radiation-related risk of thyroid cancer in those exposed at young ages, less is known about the risk due to adult exposure,…”
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Iron(IV) complexes with tetraazaadamantane-based ligands: synthesis, structure, applications in dioxygen activation and labeling of biomolecules
Published in Dalton transactions : an international journal of inorganic chemistry (15-03-2022)“…4,6,10-Trihydroxy-1,4,6,10-tetraazaadamantane (TAAD) has been shown to form a stable Fe(IV) complex having a diamantane cage structure, in which the metal…”
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Revealing the Structure of Transition Metal Complexes of Formaldoxime
Published in Inorganic chemistry (19-04-2021)“…Aerobic reactions of iron(III), nickel(II), and manganese(II) chlorides with formaldoxime cyclotrimer (tfoH3) and 1,4,7-triazacyclononane (tacn) produce…”
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Exploiting Coupling of Boronic Acids with Triols for a pH-Dependent “Click-Declick” Chemistry
Published in Journal of organic chemistry (07-09-2018)“…Click-like condensation of boronic acids with specifically designed triols (boronate-triol coupling) produces stable diamantane adducts in aqueous medium,…”
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3D simulations for evaluation of location factors in an urban environment: application of a novel methodology to calculate external exposure doses for evacuees from Pripyat
Published in Radiation and environmental biophysics (01-11-2021)“…This article presents a methodology for assessing the radiation doses in an urban environment due to external irradiation from radionuclides deposited on the…”
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Synthesis of B,O,N-Doped Adamantanes and Diamantanes by Condensation of Oximes with Boronic Acids
Published in Journal of organic chemistry (02-07-2015)“…Condensation of oximes with boronic acids RB(OH)2 or B(OH)3 affords remarkably stable 2,4,10-trioxa-1,5,7-triaza-3-boroadamantanes via an unprecedented…”
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Impact of Uncertainties in Exposure Assessment on Thyroid Cancer Risk among Persons in Belarus Exposed as Children or Adolescents Due to the Chernobyl Accident
Published in PloS one (14-10-2015)“…The excess incidence of thyroid cancer in Ukraine and Belarus observed a few years after the Chernobyl accident is considered to be largely the result of 131I…”
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