Search Results - "Gogoi, Achyut Ranjan"
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General and Practical Route to Diverse 1‑(Difluoro)alkyl-3-aryl Bicyclo[1.1.1]pentanes Enabled by an Fe-Catalyzed Multicomponent Radical Cross-Coupling Reaction
Published in ACS catalysis (07-10-2022)“…Bicyclo[1.1.1]pentanes (BCPs) are of great interest to the agrochemical, materials, and pharmaceutical industries. In particular, synthetic methods to access…”
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Dearomatization of aromatic asmic isocyanides to complex cyclohexadienes
Published in Nature communications (28-10-2022)“…A dearomatization-dislocation-coupling cascade rapidly transforms aromatic isocyanides into highly functionalized cyclohexadienes. The facile cascade installs…”
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Molecular Insights on Solvent Effects in Organic Reactions as Obtained through Computational Chemistry Tools
Published in Journal of organic chemistry (04-02-2022)“…Molecular understanding of the role of protic solvents in a gamut of organic transformations can be developed using density functional and ab initio…”
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Photoinduced Acylations Via Azolium-Promoted Intermolecular Hydrogen Atom Transfer
Published in Journal of the American Chemical Society (25-01-2023)“…Photoinduced hydrogen atom transfer (HAT) has been developed as a powerful tool to generate synthetically valuable radical species. The direct photoexcitation…”
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General and Practical Route to Diverse 1-(Difluoro)alkyl-3-aryl Bicyclo1.1.1pentanes Enabled by an Fe-Catalyzed Multicomponent Radical Cross-Coupling Reaction
Published in ACS catalysis (07-10-2022)“…Bicyclo[1.1.1]pentanes (BCPs) are of great interest to the agrochemical, materials, and pharmaceutical industries. In particular, synthetic methods to access…”
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Insight into Radical Initiation, Solvent Effects, and Biphenyl Production in Iron–Bisphosphine Cross-Couplings
Published in ACS catalysis (07-07-2023)“…Iron–bisphosphines have attracted broad interest as highly effective and versatile catalytic systems for two- and three-component cross-coupling strategies…”
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Breaking the tert-Butyllithium Contact Ion Pair: A Gateway to Alternate Selectivity in Lithiation Reactions
Published in Journal of the American Chemical Society (17-05-2023)“…The effects of Lewis basic phosphoramides on the aggregate structure of t-BuLi have been investigated in detail by NMR and DFT methods. It was determined that…”
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Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of α‑Boryl Radicals
Published in Organic letters (24-11-2023)“…Despite recent interest in the development of iron-catalyzed transformations, methods that use iron-based catalysts capable of controlling the…”
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Elucidating electron-transfer events in polypyridine nickel complexes for reductive coupling reactions
Published in Nature catalysis (01-03-2023)“…Polypyridine-ligated nickel complexes are widely used as privileged catalysts in a variety of cross-coupling reactions. The rapid adoption of these complexes…”
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