Search Results - "Gómez, Enrique"

Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C–O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates by Cornella, Josep, Gómez-Bengoa, Enrique, Martin, Ruben

“…A mechanistic and computational study on the reductive cleavage of C–OMe bonds catalyzed by Ni(COD)2/PCy3 with silanes as reducing agents is reported herein…”
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Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation by Martín, Jaime, Gómez‐Bengoa, Enrique, Genoux, Alexandre, Nevado, Cristina

“…A catalytic method to synthesize a broad array of cyclometalated (C^N)gold(III) complexes is reported here. An unprecedented Rh‐to‐AuIII transmetalation allows…”
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Palladium-Catalyzed Stereoselective Formation of Substituted Allylic Thioethers and Sulfones by Gómez, José Enrique, Guo, Wusheng, Kleij, Arjan W

“…A general method is reported for the stereoselective preparation of highly functionalized allylic thioethers. This protocol is based on a Pd-catalyzed…”
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Four‐Step Synthesis of (−)‐4‐epi‐Presilphiperfolan‐8α‐ol by Intramolecular Iron Hydride Atom Transfer‐Mediated Ketone‐Alkene Coupling and Studies to Access trans‐Hydrindanols with a Botryane Scaffold by Saladrigas, Mar, Gómez‐Bengoa, Enrique, Bonjoch, Josep, Bradshaw, Ben

“…From an (R)‐(+)‐pulegone‐derived building block that incorporates the stereo‐defined tertiary carbon bearing a methyl group, as found in the targeted…”
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Women in Spanish Municipal Councils and Budgetary Policies by Cabaleiro-Casal, Roberto, Buch-Gómez, Enrique J.

“…As men and women are sociologically different, scientific literature attempts to explain differences in public outcomes in terms of the gender of elected…”
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Adhesion of Catechol‐Functionalized Linear‐Dendritic Block Copolymers: Dendritic Effect, Self‐Assembly, and Bioadhesion by Lancelot, Alexandre, Meger, Mitchell E., Guerreiro Gómez, Enrique, Sierra, Teresa, Wilker, Jonathan J.

“…Abstract Inspired by mussels protein adhesives, two series of catechol‐functionalized Linear‐Dendritic Block Copolymer (LDBC) adhesives are synthesized. They…”
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Ring Walking Mediated by Ni–Ni Species as a Vehicle for Enabling Distal C(sp2)–H Functionalization of Aryl Pivalates by Odena, Carlota, Gómez-Bengoa, Enrique, Martin, Ruben

“…Herein, we report the utilization of Ni–Ni species as a manifold for enabling a “ring-walking” event by dynamic translocation of the metal center over the…”
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Selective C(sp2)–H Halogenation of “Click” 4‑Aryl-1,2,3-triazoles by Goitia, Asier, Gómez-Bengoa, Enrique, Correa, Arkaitz

“…Selective bromination reactions of “click compounds” are described. Electron-neutral and electron-deficient arenes selectively undergo unprecedented…”
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Depopulation of Toledo's historical centre in Spain? Challenge for local politics in world heritage cities by Larraz, Beatriz, García-Gómez, Enrique

“…The historical centre of the city of Toledo (Spain) was declared a World Heritage City by UNESCO in 1986. Since then, it has lost almost a quarter of its…”
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Clinical utility of checkpoint inhibitors against metastatic bladder cancer: overcoming challenges to find a way forward by Bilé-Silva, Andreia, Lopez-Beltran, Antonio, Blanca, Ana, Lopez-Rios, Fernando, Gómez-Gómez, Enrique, Cimadamore, Alessia, Montironi, Rodolfo, Vau, Nuno, Cheng, Liang

“…Cisplatin-based chemotherapy is currently considered the gold-standard treatment for metastatic urothelial carcinoma (mUC). Nevertheless, most mUC patients…”
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Expeditious diastereoselective synthesis of elaborated ketones via remote Csp3–H functionalization by Shu, Wei, Lorente, Adriana, Gómez-Bengoa, Enrique, Nevado, Cristina

“…The quest for selective C–H functionalization reactions, able to provide new strategic opportunities for the rapid assembly of molecular complexity, represents…”
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The recipient metabolome explains the asymmetric ovarian impact on fetal sex development after embryo transfer in cattle by Gimeno, Isabel, Salvetti, Pascal, Carrocera, Susana, Gatien, Julie, Le Bourhis, Daniel, Gómez, Enrique

“…In cattle, lateral asymmetry affects ovarian function and embryonic sex, but the underlying molecular mechanisms remain unknown. The plasma metabolome of…”
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α‐Branched Ketone Dienolates: Base‐Catalysed Generation and Regio‐ and Enantioselective Addition Reactions by Urruzuno, Iñaki, Mugica, Odei, Zanella, Giovanna, Vera, Silvia, Gómez‐Bengoa, Enrique, Oiarbide, Mikel, Palomo, Claudio

“…In this study, the unique capacity of bifunctional Brønsted bases to generate α‐branched ketone dienolates and control both site‐ and stereoselectivity of…”
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Manganese‐Catalyzed Multicomponent Synthesis of Tetrasubstituted Propargylamines: System Development and Theoretical Study by Neofotistos, Stavros P., Tzouras, Nikolaos V., Pauze, Martin, Gómez‐Bengoa, Enrique, Vougioukalakis, Georgios C.

“…Herein, we report a catalytic system based on the earth‐abundant manganese for the ketone, amine, alkyne (KA2) reaction. The efficiency of manganese manifests…”
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Mechanistic Insights in Gold-Stabilized Nonclassical Carbocations: Gold-Catalyzed Rearrangement of 3-Cyclopropyl Propargylic Acetates by Garayalde, David, Gómez-Bengoa, Enrique, Huang, Xiaogen, Goeke, Andreas, Nevado, Cristina

“…The reaction of 3-cyclopropyl propargylic carboxylates with Au(I) and Au(III) catalysts affords selectively 5-(E)-alkylidenecyclopentenyl acetates via…”
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The First Gold(III) Formate: Evidence for β‐Hydride Elimination by Kumar, Roopender, Krieger, Jean‐Philippe, Gómez‐Bengoa, Enrique, Fox, Thomas, Linden, Anthony, Nevado, Cristina

“…The first stable gold(III) formate and experimental evidence for its β‐hydride elimination are described. A catalytic dehydrogenation of formic acid together…”
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Directed C−H Allylation of Aromatic Carboxamides with Allyl Aryl Ethers under CpCo(III)‐Catalysis by Carral‐Menoyo, Asier, Barbolla, Iratxe, Santiago, Carlos, Espinel, Martín, Sotomayor, Nuria, Gómez‐Bengoa, Enrique, Lete, Esther

“…The Cp*Co(III) C−H allylation of (hetero)arenes with allyl aryl ethers has been developed using an amide as directing group (24 examples). DFT calculations…”
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Brønsted Base Catalyzed One‐Pot Synthesis of Stereodefined Six‐Member Carbocycles Featuring Transient Trienolates and a Key Intramolecular 1,6‐Addition by Olaizola, Olatz, Iriarte, Igor, Zanella, Giovanna, Gómez‐Bengoa, Enrique, Ganboa, Iñaki, Oiarbide, Mikel, Palomo, Claudio

“…A catalyst‐driven one‐pot reaction sequence is developed for the enantio‐ and diastereoselective synthesis of tetrasubstituted cyclohexenes from simple…”
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Plasma Ceramides, Mediterranean Diet, and Incident Cardiovascular Disease in the PREDIMED Trial (Prevención con Dieta Mediterránea) by Wang, Dong D, Toledo, Estefanía, Hruby, Adela, Rosner, Bernard A, Willett, Walter C, Sun, Qi, Razquin, Cristina, Zheng, Yan, Ruiz-Canela, Miguel, Guasch-Ferré, Marta, Corella, Dolores, Gómez-Gracia, Enrique, Fiol, Miquel, Estruch, Ramón, Ros, Emilio, Lapetra, José, Fito, Montserrat, Aros, Fernando, Serra-Majem, Luis, Lee, Chih-Hao, Clish, Clary B, Liang, Liming, Salas-Salvadó, Jordi, Martínez-González, Miguel A, Hu, Frank B

“…Although in vitro studies and investigations in animal models and small clinical populations have suggested that ceramides may represent an intermediate link…”
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Organocatalytic Enantioselective α‑Nitrogenation of α,α-Disubstituted Aldehydes in the Absence of a Solvent by Torregrosa-Chinillach, Alejandro, Carral-Menoyo, Asier, Gómez-Bengoa, Enrique, Chinchilla, Rafael

“…A highly efficient enantioselective α-nitrogenation method of α,α-disubstituted aldehydes with azodicarboxylates promoted by a chiral carbamate-monoprotected…”
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