Search Results - "Gluyas, Josef B. G"

Mixed-Valence Ruthenium Complexes Rotating through a Conformational Robin-Day Continuum by Parthey, Matthias, Gluyas, Josef B. G., Fox, Mark A., Low , Paul J., Kaupp, Martin

“…The conformational energy landscape and the associated electronic structure and spectroscopic properties (UV/Vis/near‐infrared (NIR) and IR) of three formally…”
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Rational Control of Conformational Distributions and Mixed-Valence Characteristics in Diruthenium Complexes by Gluyas, Josef B. G., Gückel, Simon, Kaupp, Martin, Low, Paul J.

“…The electronic characteristics of mixed‐valence complexes are often inferred from the shape of the inter‐valence charge transfer (IVCT) band, which usually…”
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Refining the Interpretation of Near-Infrared Band Shapes in a Polyynediyl Molecular Wire by Parthey, Matthias, Gluyas, Josef B. G., Schauer, Phil A., Yufit, Dmitry S., Howard, Judith A. K., Kaupp, Martin, Low, Paul J.

“…Spinning to improve (band) shape: A blend of theoretical and experimental work demonstrates that the rotational conformation of mixed‐valence complexes…”
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Electrochemical Single-Molecule Transistors with Optimized Gate Coupling by Osorio, Henrry M, Catarelli, Samantha, Cea, Pilar, Gluyas, Josef B. G, Hartl, František, Higgins, Simon J, Leary, Edmund, Low, Paul J, Martín, Santiago, Nichols, Richard J, Tory, Joanne, Ulstrup, Jens, Vezzoli, Andrea, Milan, David C, Zeng, Qiang

“…Electrochemical gating at the single molecule level of viologen molecular bridges in ionic liquids is examined. Contrary to previous data recorded in aqueous…”
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Iron versus Ruthenium: Clarifying the Electronic Differences between Prototypical Mixed-Valence Organometallic Butadiyndiyl Bridged Molecular Wires by Gückel, Simon, Gluyas, Josef B. G, El-Tarhuni, Sarah, Sobolev, Alexandre N, Whiteley, Mark W, Halet, Jean-François, Lapinte, Claude, Kaupp, Martin, Low, Paul J

“…The electronic structures of the prototypical bimetallic buta-1,3-diyn-1,4-diyl-bridged radical cation complexes [{M­(dppe)­Cp′}2(μ-CCCC)]+ (M= Fe, Cp′ = Cp*…”
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Broad-Band NIR Transient Absorption Spectroscopy of an “All-Carbon”-Bridged Bimetallic Radical Cation Complex by Gluyas, Josef B. G, Sobolev, Alexandre N, Moore, Evan G, Low, Paul J

“…Broad-band near-infrared (NIR) transient absorption (TA) spectroscopy has been used for the first time to probe an all-carbon-bridged organometallic radical…”
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Cross-Conjugated Systems Based On An (E)‑Hexa-3-en-1,5-diyne-3,4-diyl Skeleton: Spectroscopic and Spectroelectrochemical Investigations by Gluyas, Josef B. G, Manici, Valentina, Gückel, Simon, Vincent, Kevin B, Yufit, Dmitry S, Howard, Judith A. K, Skelton, Brian W, Beeby, Andrew, Kaupp, Martin, Low, Paul J

“…A series of cross-conjugated compounds based on an (E)-4,4′-(hexa-3-en-1,5-diyne-3,4-diyl)­bis­(N,N-bis­(4-methoxyphenyl)­aniline) skeleton (1–6) have been…”
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The Use of Bridging Ligand Substituents to Bias the Population of Localized and Delocalized Mixed‐Valence Conformers in Solution by Safari, Parvin, Gückel, Simon, Gluyas, Josef B. G., Moggach, Stephen A., Kaupp, Martin, Low, Paul J.

“…The electronic structure and associated spectroscopic properties of ligand‐bridged, bimetallic ‘mixed‐valence’ complexes of the general form {M}(μ‐B){M+} are…”
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Iron Versus Ruthenium: Evidence for the Distinct Differences in the Electronic Structures of Hexa-1,3,5-triyn-1,6-diyl-bridged Complexes [Cp(dppe)M}{μ-(CC)3}{M(dppe)Cp}]+ (M = Fe, Ru) by Gückel, Simon, Safari, Parvin, Bagher Hosseini Ghazvini, Seyed Mohammad, Hall, Michael R, Gluyas, Josef B. G, Kaupp, Martin, Low, Paul J

“…The spectroelectrochemically generated infrared (IR) and near-infrared spectra of the homo-bimetallic, hexa-1,3,5-triyn-1,6-diyl-bridged complex cations…”
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A Spectroscopic and Computationally Minimal Approach to the Analysis of Charge‐Transfer Processes in Conformationally Fluxional Mixed‐Valence and Heterobimetallic Complexes by Gückel, Simon, Gluyas, Josef B. G., Eaves, Samantha G., Safari, Parvin, Yufit, Dmitry S., Sobolev, Alexandre N., Kaupp, Martin, Low, Paul J.

“…Class II mixed‐valence bimetallic complexes {[Cp′(PP)M]C≡C−C≡N[M′(PP)′Cp′]}2+ (M, M′=Ru, Fe; PP=dppe, (PPh3)2; Cp′=Cp*, Cp) exist as conformational ensembles…”
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Redox Properties of Ferrocenyl Ene-diynyl-Bridged Cp(dppe)M–CC–1,4-(C6H4) Complexes by Makhoul, Rim, Gluyas, Josef B. G, Vincent, Kevin B, Sahnoune, Hiba, Halet, Jean-François, Low, Paul J, Hamon, Jean-René, Lapinte, Claude

“…The complexes FcCHC­{1,4-CC–C6H4–CCM­(dppe)­Cp*}2 (Fc = ferrocenyl (FeCp­(η-C5H4−); M = Fe (1), Ru (2)) were prepared from FcCHC­{1,4-CC–C6H4–CCSiMe3}2…”
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Disila-analogues of the synthetic retinoids EC23 and TTNN: synthesis, structure and biological evaluation by Gluyas, Josef B G, Burschka, Christian, Dörrich, Steffen, Vallet, Judith, Gronemeyer, Hinrich, Tacke, Reinhold

“…Silicon chemistry offers the potential to tune the effects of biologically active organic molecules. Subtle changes in the molecular backbone caused by the…”
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5,6-Disubstituted 1,2,3-Trisilaindanes as Silicon Analogues of Phantolide-Type Musk Odorants: Synthesis, Structure, Reactivity, and Olfactory Properties by Gluyas, Josef B. G, Burschka, Christian, Kraft, Philip, Tacke, Reinhold

“…In an extension of earlier studies concerning drugs and odorants based on disila-substituted tetrahydronaphthalene and indane skeletons, such as the musk…”
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Alkynyl-Phosphine Substituted Fe2S2 Clusters: Synthesis, Structure and Spectroelectrochemical Characterization of a Cluster with a Class III Mixed-Valence [FeFe]3+ Core by Newman, Gregory L., Rahman, Jamil M. A., Gluyas, Josef B. G., Yufit, Dmitry S., Howard, Judith A. K., Low, Paul J.

“…Phosphinoalkynes P(C≡CC 6 H 4 Me-4)Ph 2 ( 1 ) and P(C≡CC 6 H 4 C≡CC 6 H 4 Me-4)Ph 2 ( 2 ) have been prepared from CuI catalysed reactions of the corresponding…”
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Tetrakis(ferrocenylethynyl)ethene: Synthesis, (Spectro)electrochemical and quantum chemical characterisation by Vincent, Kevin B., Gluyas, Josef B.G., Gückel, Simon, Zeng, Qiang, Hartl, František, Kaupp, Martin, Low, Paul J.

“…Tetrakis(ferrocenylethynyl)ethene (1) has been prepared in four steps from ethynyl ferrocene (2). In a dichloromethane solution containing 10−1 M NBu4[PF6],…”
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Synthesis, structure and redox chemistry of the aminoallenylidene complex [Mo{CCC(Me)NEt2}(dppe)(η-C7H7)][BPh4] by Alturaifi, Huriyyah A., Gerriow, Hawa, Gluyas, Josef B.G., Mjörnstedt, Sebastian, Raftery, James, Low, Paul J., Whiteley, Mark W.

“…The reaction of [MoBr(dppe)(η-C7H7)] (dppe = Ph2PCH2CH2PPh2) with HCCCCSiMe3 and Na[BPh4] in 1:1 NHEt2/THF as solvent yields the aminoallenylidene complex…”
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