Search Results - "Gleaves, John T"
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Oxygen and CO Adsorption on Au/SiO2 Catalysts Prepared by Magnetron Sputtering: The Role of Oxygen Storage
Published in Industrial & engineering chemistry research (03-11-2010)“…Temporal Analysis of Products (TAP) reactor system was used to investigate CO oxidation behavior on Au/SiO2 catalysts prepared via the physical vapor…”
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Truth is, we all are transients: A perspective on the time-dependent nature of reactions and those who study them
Published in Catalysis today (01-05-2023)“…Understanding and mastery of Transient Kinetics in the context of multi-scale transport-reaction systems employed in catalysis is one of the ultimate frontiers…”
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Temporal analysis of products (TAP)—Recent advances in technology for kinetic analysis of multi-component catalysts
Published in Journal of molecular catalysis. A, Chemical (15-01-2010)“…This paper presents an overview of the evolution, advancements, and capabilities of the temporal analysis of products (TAP) reactor system as a unique catalyst…”
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“State defining” experiment in chemical kinetics—primary characterization of catalyst activity in a TAP experiment
Published in Chemical engineering science (01-11-2003)“…This paper presents a new strategy, “state-by-state transient screening”, for kinetic characterization of states of a multicomponent catalyst as applied to TAP…”
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Shadowing Effect in Catalyst Activity: Experimental Observation
Published in ACS catalysis (06-05-2022)“…The influence of the spatial distribution of catalyst particles in a fixed bed reactor on the observed reaction rates has historically been of central interest…”
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The Y-Procedure methodology for the interpretation of transient kinetic data: Analysis of irreversible adsorption
Published in Chemical engineering science (15-12-2011)“…This paper deals with the analysis of transient kinetic data obtained in the Thin-Zone (TZ) configuration of the Temporal Analysis of Products (TAP) reactor…”
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Elucidating complex catalytic mechanisms based on transient pulse-response kinetic data
Published in Chemical engineering science (03-05-2014)“…We describe a strategy for discriminating reaction mechanisms based on the non-steady-state coherency of kinetic characteristics including net production rates…”
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Rate-Reactivity Model: A New Theoretical Basis for Systematic Kinetic Characterization of Heterogeneous Catalysts
Published in International journal of chemical kinetics (01-06-2016)“…ABSTRACT Non‐steady‐state kinetic measurements contain a wealth of information about catalytic reactions and other gas–solid chemical interactions, which is…”
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Momentary Equilibrium in Transient Kinetics and Its Application for Estimating the Concentration of Catalytic Sites
Published in Industrial & engineering chemistry research (06-11-2013)“…We describe the novel concept of momentary equilibrium (ME), a special event during a pulse-response transient experiment in which the non-steady-state rates…”
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Sun, Surf, and Toned Bodies: California’s Impact on the History of Sport and Leisure
Published in Journal of sport history (01-03-2019)Get full text
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Moment-Based Analysis of Transient Response Catalytic Studies (TAP Experiment)
Published in Industrial & engineering chemistry research (01-06-1998)“…A new moment-based theoretical approach for the analysis of TAP (temporal analysis of products) pulse-response data is described. The distinguishing feature of…”
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Activation of Vanadium Phosphorus Oxide Catalysts for Alkane Oxidation. The Influence of the Oxidation State on Catalyst Selectivity
Published in Industrial & engineering chemistry research (01-12-1994)“…The selective conversion of light alkanes to oxygenates is important to both the petrochemical and energy industries. Oxygenates are used in the preparation of…”
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Needle in a haystack catalysis
Published in Applied catalysis. A, General (15-06-2008)“…Comparison of CO 2 produced during TAP vacuum pump-probe experiments and atmospheric flow experiments for CO oxidation over single Pt particle with the same…”
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Thin-zone TAP reactor as a basis of “state-by-state transient screening”
Published in Chemical engineering science (01-11-2004)“…Thin-zone TAP reactor is presented as a basis of the new state-by-state transient screening approach which has been proposed by the authors for…”
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Combining TAP-2 experiments with atomic beam deposition of Pd on quartz particles
Published in Catalysis today (30-03-2007)“…This paper presents a new approach for precisely tailoring the surface of complex catalytic particles at the atomic level. We describe a new apparatus of…”
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TAP Vacuum Pulse-Response and Normal-Pressure Studies of Propane Oxidation over MoVTeNb Oxide Catalysts
Published in Industrial & engineering chemistry research (03-08-2005)“…The economic advantages of switching to a propane feedstock in the production of acrylic acid have been a motivating force for extensive research studies…”
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Sun, Surf, and Toned Bodies: California’s Impact on the History of Sport and Leisure: Introduction
Published in Journal of sport history (01-04-2019)Get full text
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Symmetrical Cylindrical Model for TAP Pulse Response Experiments and Validity of the One-Dimensional TAP Model
Published in Industrial & engineering chemistry research (04-08-1997)“…A two-dimensional symmetrical cylindrical transport model for TAP pulse response experiments is analyzed and compared with the one-dimensional TAP model. It is…”
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