Search Results - "Girolami, G.S."

Field-directed sputter sharpening for tailored probe materials and atomic-scale lithography by Schmucker, S.W., Kumar, N., Abelson, J.R., Daly, S.R., Girolami, G.S., Bischof, M.R., Jaeger, D.L., Reidy, R.F., Gorman, B.P., Alexander, J., Ballard, J.B., Randall, J.N., Lyding, J.W.

“…Fabrication of ultrasharp probes is of interest for many applications, including scanning probe microscopy and electron-stimulated patterning of surfaces…”
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HfB2 and Hf-B-N hard coatings by chemical vapor deposition by JAYARAMAN, S, GERBI, J. E, YANG, Y, KIM, D. Y, CHATTERJEE, A, BELLON, P, GIROLAMI, G. S, CHEVALIER, J. P, ABELSON, J. R

“…Hard, dense and conformal hafnium diboride (HfB2) thin films were obtained by CVD from the precursor Hf[BH4]4 at deposition temperatures < or = 350 deg C…”
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HfB 2 and Hf–B–N hard coatings by chemical vapor deposition by Jayaraman, S., Gerbi, J.E., Yang, Y., Kim, D.Y., Chatterjee, A., Bellon, P., Girolami, G.S., Chevalier, J.P., Abelson, J.R.

“…Hard, dense and conformal hafnium diboride (HfB 2) thin films were obtained by CVD from the precursor Hf[BH 4] 4 at deposition temperatures ≤ 350 °C…”
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Surface-selective deposition of palladium and silver films from metal-organic precursors: a novel metal-organic chemical vapor deposition redox transmetalation process by Lin, Wenbin, Warren, Timothy H, Nuzzo, Ralph G, Girolami, Gregory S

“…We report the first surface-selective depositions of Pd and Ag films from metal-organic precursors. We also describe mechanistic studies of this process by in…”
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Synthesis of hydride and alkyl compounds containing the CpOs([eta][sup 3]-allyl) fragment. Crystal structures of CpOs([eta][sup 3]-C[sub 8]H[sub 13])Br[sub 2] and [CpOs([eta][sup 3]-C[sub 4]H[sub 7])Me(H[sub 2]O)][BF[sub 4]] by Mui, H.D., Brumaghim, J.L., Gross, C.L., Girolami, G.S.

“…Treatment of Cp*[sub 2]Os[sub 2]Br[sub 4] with 3-bromo-2-methylpropene or 1,3-cyclooctadiene affords the 2-methylpropenyl and cyclooctenyl products…”
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Reversible silicon-carbon bond cleavage process. Dynamics and reactivity of Cp[sub 2]Ru[sub 2]([mu]-CH[sub 2]) (SiMe[sub 3]) ([mu]-Cl) by Lin, W., Wilson, S.R., Girolami, G.S.

“…The methylene/silyl complex Cp*[sub 2]Ru[sub 2]([mu]-CH[sub 2]) (SiMe[sub 3])([mu]-Cl), where Cp* = C[sub 5]Me[sub 5], has been prepared by alkylation of…”
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Synthesis of a Novel Volatile Platinum Complex for Use in CVD and a Study of the Mechanism of Its Thermal Decomposition in Solution by Tagge, Christopher D, Simpson, Robert D, Bergman, Robert G, Hostetler, Michael J, Girolami, Gregory S, Nuzzo, Ralph G

“…The synthesis, characterization, chemical vapor deposition, and mechanistic investigation of the thermal decomposition in aromatic solvents of…”
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Mechanistic studies of copper thin-film growth from Cu[sup I] and Cu[sup II] [beta]-diketonates by Girolami, G.S., Jeffries, P.M., Dubois, L.H.

“…The kinetics and mechanism of copper film growth from the reactions of bis(acetylacetonato)copper(II), bis(hexafluoroacetylacetonato)copper(II), and…”
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Structures and Reactivities of Cycloheptane, Cycloheptene, 1,3-Cycloheptadiene, and Cycloheptatriene on Pt(111) by Manner, William L, Hostetler, Michael J, Girolami, Gregory S, Nuzzo, Ralph G

“…The structures and reactivities of various cyclic C7 hydrocarbons (cycloheptane, cycloheptene, 1,3-cycloheptadiene, and cycloheptatriene) adsorbed on Pt(111)…”
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Structure-reactivity correlations in the reactions of hydrocarbons on transition metal surfaces. 2. Hydrogenation of norbornene and bicyclo[2. 2. 2]octene on platinum(111) by Hostetler, M.J., Nuzzo, R.G., Girolami, G.S.

“…The reactivity of two bicyclic alkenes, bicyclo[2.2.2]octene (BOE) and norbonene (NBE), has been studied on Pt(111) in both the absence and the presence of…”
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Chemical vapor deposition of copper and copper oxide thin films from copper(I) tert-butoxide by Jeffries, Patrick M, Girolami, Gregory S

“…Work is described to produce a chemical vapor deposition < CVD > of Cu and/or copper oxide from a non-halide precursor. Heating of (Cu(O-t-Bu)) in vacuum…”
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Sequential Dehydrogenation of Unsaturated Cyclic C5 and C6 Hydrocarbons on Pt(111) by Manner, William L, Girolami, Gregory S, Nuzzo, Ralph G

“…The structures and reactivities of various cyclic C5 and C6 hydrocarbons (cyclopentene, cyclopentadiene, cyclohexene, 1,3-cyclohexadiene, and…”
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Reactions of Primary Organosilanes on Transition Metal Surfaces. Identification of the First Surface-Bound Silylynes by Hostetler, Michael J, Nuzzo, Ralph G, Girolami, Gregory S

“…Transition metal silicides have numerous applications in the microelectronics industry. Primary organosilanes (RSiH[sub 3]) are attractive alternative silicon…”
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"Tailored" organometallics as precursors for the chemical vapor deposition of high-purity palladium and platinum thin films by Gozum, John E, Pollina, Deborah M, Jensen, James A, Girolami, Gregory S

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Chemical Vapor Deposition of Zinc from Diallyl Zinc Precursors by Cheon, Jinwoo, Dubois, Lawrence H, Girolami, Gregory S

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Electronically asymmetric bis(porphyrin) sandwich complexes by Girolami, Gregory S, Gorlin, Philip A, Suslick, Kenneth S

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Organometallic route to the chemical vapor deposition of titanium carbide films at exceptionally low temperatures by Girolami, Gregory S, Jensen, James A, Pollina, Deborah M, Allocca, Clare M, Kaloyeros, Alain E, Williams, Wendell S

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Two-Dimensional Melting Transitions of Rod-like Molecules Analyzed by Reflection-Absorption Infrared Spectroscopy by Hostetler, Michael J, Manner, William L, Nuzzo, Ralph G, Girolami, Gregory S

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Synthesis and structure of transition-metal bis(porphyrinato) complexes. Characterization of Zr(TPP) sub 2 and Zr(OEP) sub 2 by Kim, Kimoon, Lee, W.S., Kim, Heejoon, Cho, Sunghee, Girolami, G.S., Gorlin, P.A., Suslick, K.S.

“…Treatment of Zr(Net{sub 2}){sub 4} with the free-base porphyrins 5, 10, 15, 20-tetraphenylporphyrin (H{sub 2}TPP) or 2,3,7,8,12,13,17,18-octaethylporphyrin…”
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Ring contraction of cyclooctene, 1,3-cyclooctadiene, 1,5-cyclooctadiene, and cyclooctatetraene to benzene on platinum(111) surfaces by Hostetler, Michael J, Dubois, Lawrence H, Nuzzo, Ralph G, Girolami, Gregory S

“…The authors report the discovery and mechanistic studies of the conversion of cyclic C[sub 8] alkenes, including cyclooctene (COE), 1,3-cyclooctadiene…”
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