Search Results - "Gilhula, James C"
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Tetragonal phosphorus() cations as tunable and robust catalytic Lewis acids
Published in Chemical science (Cambridge) (14-08-2019)“…The synthesis and catalytic reactivity of a class of water-tolerant cationic phosphorus-based Lewis acids is reported. Corrole-based phosphorus( v ) cations of…”
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Robust and Porous β‑Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation
Published in Journal of the American Chemical Society (16-03-2016)“…We have designed a strategy for postsynthesis installation of the β-diketiminate (NacNac) functionality in a metal–organic framework (MOF) of UiO-topology…”
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Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes
Published in Chemical science (Cambridge) (14-05-2018)“…The syntheses and 1,2-addition reactivities of nontrigonal phosphazenes supported by trianionic tricoordinating chelates of the type L P[double bond, length as…”
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Successful Coupling of a Bis-Amidoxime Uranophile with a Hydrophilic Backbone for Selective Uranium Sequestration
Published in ACS applied materials & interfaces (23-08-2017)“…The amidoxime group (−RNH2NOH) has long been used to extract uranium from seawater on account of its high affinity toward uranium. The development of tunable…”
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Peroxide-treated metal-organic framework templated adsorbents for remediation of high level nuclear waste
Published in Journal of hazardous materials (05-03-2019)“…[Display omitted] •Peroxide treated MOF-templated adsorbents showed orders of magnitude performance gains.•Materials showed excellent removal of Am and Eu from…”
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Tetragonal phosphorus(v) cations as tunable and robust catalytic Lewis acids† †Electronic supplementary information (ESI) available. CCDC 1904833 and 1904834. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02463h
Published in Chemical science (Cambridge) (18-06-2019)“…The synthesis and catalytic reactivity of a class of water-tolerant cationic phosphorus-based Lewis acids is reported. The synthesis and catalytic reactivity…”
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Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenesElectronic supplementary information (ESI) available. CCDC 1821116-1821122. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc00929e
Published 09-05-2018“…The syntheses and 1,2-addition reactivities of nontrigonal phosphazenes supported by trianionic tricoordinating chelates of the type L 3 P&z.dbd;Ndipp ( 3 : L…”
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Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes† †Electronic supplementary information (ESI) available. CCDC 1821116–1821122. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc00929e
Published in Chemical science (Cambridge) (06-04-2018)“…The syntheses and 1,2-addition reactivities of nontrigonal phosphazenes supported by trianionic tricoordinating chelates of the type L 3 P Created by potrace…”
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