Search Results - "Gilbertson, John D."

Zero-Reabsorption Doped-Nanocrystal Luminescent Solar Concentrators by Erickson, Christian S, Bradshaw, Liam R, McDowall, Stephen, Gilbertson, John D, Gamelin, Daniel R, Patrick, David L

“…Optical concentration can lower the cost of solar energy conversion by reducing photovoltaic cell area and increasing photovoltaic efficiency. Luminescent…”
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Uncoupled Redox-Inactive Lewis Acids in the Secondary Coordination Sphere Entice Ligand-Based Nitrite Reduction by Burns, Kyle T, Marks, Walker R, Cheung, Pui Man, Seda, Takele, Zakharov, Lev N, Gilbertson, John D

“…Metal complexes composed of redox-active pyridinediimine (PDI) ligands are capable of forming ligand-centered radicals. In this Forum article, we demonstrate…”
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Square planar Cu(I) stabilized by a pyridinediimine ligand by Cheung, Pui Man, Berger, Robert F, Zakharov, Lev N, Gilbertson, John D

“…A set of distorted square planar Cu(I) complexes were synthesized and characterized utilizing the sterically encumbering pyridinediimine ligand, (iPr)PDI…”
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Ultrafast Optical Study of Small Gold Monolayer Protected Clusters: A Closer Look at Emission by Yau, Sung Hei, Varnavski, Oleg, Gilbertson, John D, Chandler, Bert, Ramakrishna, Guda, Goodson, Theodore

“…Monolayer-protected metal nanoclusters (MPCs) were investigated to probe their fundamental excitation and emission properties. In particular, gold MPCs were…”
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Kinetic Evaluation of Highly Active Supported Gold Catalysts Prepared from Monolayer-Protected Clusters: An Experimental Michaelis−Menten Approach for Determining the Oxygen Binding Constant during CO Oxidation Catalysis by Long, Cormac G, Gilbertson, John D, Vijayaraghavan, Ganesh, Stevenson, Keith J, Pursell, Christopher J, Chandler, Bert D

“…Thiol monolayer-protected Au clusters (MPCs) were prepared using dendrimer templates, deposited onto a high-surface-area titania, and then the thiol…”
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Reduction of N2 to Ammonia and Hydrazine Utilizing H2 as the Reductant by Gilbertson, John D, Szymczak, Nathaniel K, Tyler, David R

“…The trans-Fe(DMeOPrPE)2Cl2 complex (where DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) undergoes a series of reactions that involve the activation of…”
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Harnessing the active site triad: merging hemilability, proton responsivity, and ligand-based redox-activity by Baumgardner, Douglas F, Parks, Wyatt E, Gilbertson, John D

“…Metalloenzymes catalyze many important reactions by managing the proton and electron flux at the enzyme active site. The motifs utilized to facilitate these…”
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Sequential Deoxygenation of CO2 and NO2 – via Redox-Control of a Pyridinediimine Ligand with a Hemilabile Phosphine by Lewine, Hanalei R., Teigen, Allison G., Trausch, April M., Lindblom, Kaitlyn M., Seda, Takele, Reinheimer, Eric W., Kowalczyk, Tim, Gilbertson, John D.

“…The deoxygenation of environmental pollutants CO2 and NO2 – to form value-added products is reported. CO2 reduction with subsequent CO release and NO2 –…”
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NO Coupling by Nonclassical Dinuclear Dinitrosyliron Complexes to Form N2O Dictated by Hemilability by Marks, Walker R, Reinheimer, Eric W, Seda, Takele, Zakharov, Lev N, Gilbertson, John D

“…Selective coupling of NO by a nonclassical dinuclear dinitrosyliron complex (D-DNIC) to form N2O is reported. The coupling is facilitated by the…”
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Pyridinediimine Iron Complexes with Pendant Redox-Inactive Metals Located in the Secondary Coordination Sphere by Delgado, Mayra, Ziegler, Joshua M, Seda, Takele, Zakharov, Lev N, Gilbertson, John D

“…A series of pyridinediimine (PDI) iron complexes that contain a pendant 15-crown-5 located in the secondary coordination sphere were synthesized and…”
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Sterically Engineered Perylene Dyes for High Efficiency Oriented Fluorophore Luminescent Solar Concentrators by Benjamin, Willie E, Veit, Darren R, Perkins, Matt J, Bain, Edward, Scharnhorst, Kelsey, McDowall, Stephen, Patrick, David L, Gilbertson, John D

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Ligand-Based Reduction of CO2 and Release of CO on Iron(II) by Thammavongsy, Zachary, Seda, Takele, Zakharov, Lev N, Kaminsky, Werner, Gilbertson, John D

“…A synthetic cycle for the CO2-to-CO conversion (with subsequent release of CO) based on iron(II), a redox-active pydridinediimine ligand (PDI), and an O-atom…”
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Probing the Protonation State and the Redox-Active Sites of Pendant Base Iron(II) and Zinc(II) Pyridinediimine Complexes by Delgado, Mayra, Sommer, Samantha K, Swanson, Seth P, Berger, Robert F, Seda, Takele, Zakharov, Lev N, Gilbertson, John D

“…Utilizing the pyridinediimine ligand [(2,6-iPrC6H3)­NCMe)­(N­(iPr)2­C2H4)­NCMe)­C5H3N] (didpa), the zinc­(II) and iron­(II) complexes Zn­(didpa)­Cl2 (1),…”
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Enhanced Oxygen Activation over Supported Bimetallic Au−Ni Catalysts by Chandler, Bert D, Long, Cormac G, Gilbertson, John D, Pursell, Christopher J, Vijayaraghavan, Ganesh, Stevenson, Keith J

“…New bimetallic Ni−Au supported nanoparticle catalysts were prepared by using dendrimer templated nanoparticles. Amine-terminated generation 5 polyamidoamine…”
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Synthesis and Stabilization of a Monomeric Iron(II) Hydroxo Complex via Intramolecular Hydrogen Bonding in the Secondary Coordination Sphere by Kendall, Alexander J, Zakharov, Lev N, Gilbertson, John D

“…Utilizing the pyridinediimine ligand [(2,6-iPrC6H3)NCMe)(N(iPr)2C2H4)NCMe)C5H3N] (didpa), the iron(II) complexes Fe(didpa)Br2 (1), [Fe(Hdidpa)Br2][PF6] (2),…”
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Hemilabile Proton Relays and Redox Activity Lead to {FeNO} x and Significant Rate Enhancements in NO2 – Reduction by Cheung, Pui Man, Burns, Kyle T, Kwon, Yubin M, Deshaye, Megan Y, Aguayo, Kristopher J, Oswald, Victoria F, Seda, Takele, Zakharov, Lev N, Kowalczyk, Tim, Gilbertson, John D

“…Incorporation of the triad of redox activity, hemilability, and proton responsivity into a single ligand scaffold is reported. Due to this triad, the complexes…”
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Hemilabile Proton Relays and Redox Activity Lead to {FeNO} x and Significant Rate Enhancements in NO 2 - Reduction by Cheung, Pui Man, Burns, Kyle T, Kwon, Yubin M, Deshaye, Megan Y, Aguayo, Kristopher J, Oswald, Victoria F, Seda, Takele, Zakharov, Lev N, Kowalczyk, Tim, Gilbertson, John D

“…Incorporation of the triad of redox activity, hemilability, and proton responsivity into a single ligand scaffold is reported. Due to this triad, the complexes…”
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Coordination Chemistry of H2 and N2 in Aqueous Solution. Reactivity and Mechanistic Studies Using trans-FeII(P2)2X2-Type Complexes (P2 = a Chelating, Water-Solubilizing Phosphine) by Gilbertson, John D, Szymczak, Nathaniel K, Crossland, Justin L, Miller, Warren K, Lyon, David K, Foxman, Bruce M, Davis, Joclyn, Tyler, David R

“…The reactions of the trans-Fe(DMeOPrPE)2Cl2 complex (I; DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) and its derivatives were studied in aqueous and…”
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Pyridinediimine Iron Dicarbonyl Complexes with Pendant Lewis Bases and Lewis Acids Located in the Secondary Coordination Sphere by Thammavongsy, Zachary, LeDoux, Micah E., Breuhaus-Alvarez, Andrew G., Seda, Takele, Zakharov, Lev N., Gilbertson, John D.

“…A series of asymmetric iron(II) dichloride and dicarbonyl pyridinediimine (PDI) complexes that contain either pendant Lewis bases or Lewis acids located in the…”
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Dendrimer templates for supported Au catalysts by Korkosz, Rachel J., Gilbertson, John D., Prasifka, Kristin S., Chandler, Bert D.

“…Dendrimer templated thiol stabilized gold nanoparticles were evaluated as potential precursors for supported gold catalysts. Gold nanoparticles were prepared…”
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