Search Results - "Giannini, Luca"
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Sepiolite-Based Anisotropic Nanoparticles: A New Player in the Rubber Reinforcement Technology for Tire Application
Published in Applied sciences (01-03-2022)“…Elastomer reinforcement with nanofillers has been a main rubber technology topic since the discovery of rubber vulcanization. Starting from carbon black, many…”
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Influence of Resins on the Structure and Dynamics of SBR Compounds: A Solid-State NMR Study
Published in Applied sciences (01-02-2023)“…The tackifying effect of resins used in the tire industry highly depends on the compatibility and interaction strength with the rubber matrix. Here, uncured…”
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A Green Approach for Preparing High-Loaded Sepiolite/Polymer Biocomposites
Published in Nanomaterials (Basel, Switzerland) (31-12-2018)“…Global industry is showing a great interest in the field of sustainability owing to the increased attention for ecological safety and utilization of renewable…”
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Hybrid Interface in Sepiolite Rubber Nanocomposites: Role of Self-Assembled Nanostructure in Controlling Dissipative Phenomena
Published in Nanomaterials (Basel, Switzerland) (27-03-2019)“…Sepiolite (Sep)⁻styrene butadiene rubber (SBR) nanocomposites were prepared by using nano-sized sepiolite (NS-SepS9) fibers, obtained by applying a controlled…”
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Enantioselective Reduction of Ketones by Polymethylhydrosiloxane in the Presence of Chiral Zinc Catalysts
Published in Journal of the American Chemical Society (07-07-1999)“…Enantioselective reduction of ketones, particularly acetophenones, by polymethylhydrosiloxane (PMHS) to the corresponding secondary alcohols can be achieved…”
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Enzymatic Modification of Cellulose To Unlock Its Exploitation in Advanced Materials
Published in Chembiochem : a European journal of chemical biology (16-03-2021)“…Nowadays natural biopolymers have a wide variety of uses in various industrial applications, such as food, adhesives and composite materials. Among them,…”
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Toward More Sustainable Elastomers: Stereoselective Copolymerization of Linear Terpenes with Butadiene
Published in Macromolecules (10-03-2020)“…The copolymerization of renewable monomers such as ocimene (O), myrcene (M), and farnesene (F) with butadiene (B), promoted by…”
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Metal–Ligand Complexes as Dynamic Sacrificial Bonds in Elastic Polymers
Published in Macromolecules (28-06-2022)“…The chemical modification of technical rubbers to fine-tune their properties is a subject of current interest. Here, we report a facile approach for the…”
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Single-phase block copolymers by cross-metathesis of 1,4-cis-polybutadiene and 1,4-cis-polyisoprene
Published in Polymer (Guilford) (09-11-2017)“…Macromolecular Cross-Metathesis (MCM) reactions on commercial Polybutadiene (PBD) and Polyisoprene (PIP) homopolymers, in the presence of first generation…”
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The effect of sulfate half-ester groups on the mechanical performance of cellulose nanocrystal-natural rubber composites
Published in Cellulose (London) (01-09-2023)“…Cellulose nanocrystals (CNCs) are commercially produced via hydrolysis by sulfuric acid, resulting in the formation of sulfate half-ester groups on the surface…”
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Olefin Rearrangements Assisted by a Molecular Metal−Oxo Surface: The Chemistry of Calix[4]arene Tungsten(IV)
Published in Journal of the American Chemical Society (31-03-1999)“…This report deals with the olefin rearrangements achieved on a W-calix[4]arene oxo fragment that mimicks a heterogeneous metal−oxo surface both in the results…”
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Migratory Aptitude of the Zr-C Functionalities Bonded to a Macrocyclic Structure: Thermally- and Solvent-Assisted Intra- and Intermolecular Migrations in Dialkyl(dibenzotetramethyltetraazaannulene)zirconium(IV)
Published in Journal of the American Chemical Society (01-05-1995)Get full text
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About exposure data used in paper “Assessing the potential exposure risk and control for airborne titanium dioxide and carbon black nanoparticles in the workplace”
Published in Environmental science and pollution research international (01-05-2012)“…Issue Title: Special Issue: Understanding effects of global change on water quantity and quality in river basins…”
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The self-assembly of sepiolite and silica fillers for advanced rubber materials: The role of collaborative filler network
Published in Applied clay science (01-03-2022)“…Composite materials based on hybrid filler systems can be a promising approach to produce advanced rubber nanocomposites (NCs). Recently, the positive effect…”
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Titanium-carbon functionalities on an oxo surface defined by a calix [4] arene moiety and its redox chemistry
Published in Inorganica Chimica Acta (02-04-1998)“…Lithiation of [ p-Bu t-calix[4]-(OMe) 2(OH) 2] ( 1), followed by reaction with TiCl 3(thf) 3 or TiCl 4(thf) 2, led to the corresponding titanium-calix[4]arene…”
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Mechanochemical Methacrylation of Lignin for Biobased Reinforcing Filler in Rubber Compounds
Published in ACS sustainable chemistry & engineering (05-09-2024)“…The inclusion of biobased materials as fillers for rubber compounds is an emerging topic in the tire industry. This study investigates the use of kraft lignin,…”
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Al2O3 decorated with polyhedral silsesquioxane units: An unconventional filler system for upgrading thermal conductivity and mechanical properties of rubber composites
Published in Composites science and technology (03-05-2023)“…The present study reports on the development and exploitation of an original filler system, based on alumina nanoparticles (NPs) and polyhedral silsesquioxane…”
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Influence of Sulfur-Curing Conditions on the Dynamics and Crosslinking of Rubber Networks: A Time-Domain NMR Study
Published in Polymers (16-02-2022)“…The characterization of the structural and dynamic properties of rubber networks is of fundamental importance in rubber science and technology to design…”
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Glassy and Polymer Dynamics of Elastomers by 1H‑Field-Cycling NMR Relaxometry: Effects of Fillers
Published in The journal of physical chemistry. B (06-05-2021)“…1H spin–lattice relaxation rate (R 1) dispersions were acquired by field-cycling (FC) NMR relaxometry between 0.01 and 35 MHz over a wide temperature range on…”
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