Synthesis and Crystal Structure of a Novel Mixed Ligand Cadmium(II) Complex of Benz-1,3-Thiazoline-2-Thione and 1,10-Phenanthroline
A novel cadmium complex [Cd(C 7 H 4 NS 2 ) 2 (phen)] was synthesized by the reaction of a polymeric complex, [Cd(C 7 H 4 NS 2 ) 2 ] n , with 1,10-phenanthroline (phen) as a ligand. The crystal structure was determined by single-crystal X-ray diffraction. The crystallographic data are: triclinic , a...
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| Published in: | Journal of chemical crystallography Vol. 39; no. 5; pp. 368 - 371 |
|---|---|
| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Boston
Springer US
01-05-2009
|
| Subjects: | |
| Online Access: | Get full text |
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| Summary: | A novel cadmium complex [Cd(C
7
H
4
NS
2
)
2
(phen)] was synthesized by the reaction of a polymeric complex, [Cd(C
7
H
4
NS
2
)
2
]
n
, with 1,10-phenanthroline (phen) as a ligand. The crystal structure was determined by single-crystal X-ray diffraction. The crystallographic data are: triclinic
,
a
= 8.3670(6) Å,
b
= 10.9898(8) Å,
c
= 17.1404(13) Å, α = 95.567(2)º, β = 95.881(2)º, γ = 109.034(1)º,
V
= 1471.26(19) Å
3
and
Z
= 2. The final
R
value is 0.0375 for 7154 reflections. The compound [Cd(C
7
H
4
NS
2
)
2
(phen)] is monomeric revealing a coordination sphere of N
4
S
2
type. The Cd atom is surrounded by two thiazole N atoms, two exocyclic S atoms from two bidentate 1,3-benzothiazole-2-thiolate anions and two 1,10-phenanthroline N atoms. The Cd cation is six-coordinate with a distorted octahedral geometry.
Graphical Abstract
The synthesis and crystal structure of a novel monomeric complex ‘[Cd(C
7
H
4
NS
2
)
2
(phen)]’ obtained by the reaction of polymeric complex, [Cd(C
7
H
4
NS
2
)
2
]
n
, with 1,10-phenanthroline is reported. |
|---|---|
| ISSN: | 1074-1542 1572-8854 |
| DOI: | 10.1007/s10870-008-9487-7 |