Search Results - "Gentleman, Alexander S"

IR Signature of Size‐Selective CO2 Activation on Small Platinum Cluster Anions, Ptn− (n=4–7) by Green, Alice E., Justen, Jasmin, Schöllkopf, Wieland, Gentleman, Alexander S., Fielicke, André, Mackenzie, Stuart R.

“…Infrared multiple photon dissociation spectroscopy (IR‐MPD) has been employed to determine the nature of CO2 binding to size‐selected platinum cluster anions,…”
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Investigation of the Substrate Range of CYP199A4: Modification of the Partition between Hydroxylation and Desaturation Activities by Substrate and Protein Engineering by Bell, Stephen G., Zhou, Ruimin, Yang, Wen, Tan, Adrian B. H., Gentleman, Alexander S., Wong, Luet-Lok, Zhou, Weihong

“…The cytochrome P450 enzyme CYP199A4, from Rhodopseudomonas palustris HaA2, can efficiently demethylate 4‐methoxybenzoic acid. It is also capable of oxidising a…”
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Bridging Plastic Recycling and Organic Catalysis: Photocatalytic Deconstruction of Polystyrene via a C–H Oxidation Pathway by Li, Tengfei, Vijeta, Arjun, Casadevall, Carla, Gentleman, Alexander S., Euser, Tijmen, Reisner, Erwin

“…Chemical recycling of synthetic polymers represents a promising strategy to deconstruct plastic waste and make valuable products. Inspired by small-molecule…”
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Infrared Spectroscopy of Gas-Phase M+(CO2) n (M = Co, Rh, Ir) Ion–Molecule Complexes by Iskra, Andreas, Gentleman, Alexander S, Kartouzian, Aras, Kent, Michael J, Sharp, Alastair P, Mackenzie, Stuart R

“…The structures of gas-phase M+(CO2) n (M = Co, Rh, Ir; n = 2–15) ion–molecule complexes have been investigated using a combination of infrared…”
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In situ Detection of Cobaloxime Intermediates During Photocatalysis Using Hollow‐Core Photonic Crystal Fiber Microreactors by Lawson, Takashi, Gentleman, Alexander S., Pinnell, Jonathan, Eisenschmidt, Annika, Antón‐García, Daniel, Frosz, Michael H., Reisner, Erwin, Euser, Tijmen G.

“…Hollow‐core photonic crystal fibers (HC‐PCFs) provide a novel approach for in situ UV/Vis spectroscopy with enhanced detection sensitivity. Here, we…”
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Influence of Electron Donors on the Charge Transfer Dynamics of Carbon Nanodots in Photocatalytic Systems by Macpherson, Stuart, Lawson, Takashi, Abfalterer, Anna, Andrich, Paolo, Lage, Ava, Reisner, Erwin, Euser, Tijmen G., Stranks, Samuel D., Gentleman, Alexander S.

“…Carbon nanodots (CNDs) are nanosized light-harvesters emerging as next-generation photosensitizers in photocatalytic reactions. Despite their ever-increasing…”
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A velocity map imaging study of multiphoton photodissociation and photoionisation dynamics in niobium oxide, NbO by Köckert, Hansjochen, Gentleman, Alexander S., Pickering, Jack, Mackenzie, Stuart R.

“…Velocity map imaging has transformed our capabilities in terms of determining photofragmentation and photoionisation thresholds. Here, we present an…”
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Low-Volume Reaction Monitoring of Carbon Dot Light Absorbers in Optofluidic Microreactors by Lawson, Takashi, Gentleman, Alexander S., Lage, Ava, Casadevall, Carla, Xiao, Jie, Petit, Tristan, Frosz, Michael H., Reisner, Erwin, Euser, Tijmen G.

“…Optical monitoring and screening of photocatalytic batch reactions using cuvettes ex situ is time-consuming, requires substantial amounts of samples, and does…”
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Infrared Signature of Structural Isomers of Gas–Phase M+(N2O) n (M = Cu, Ag, Au) Ion–Molecule Complexes by Cunningham, Ethan M, Gentleman, Alexander S, Beardsmore, Peter W, Iskra, Andreas, Mackenzie, Stuart R

“…Gas-phase metal ion–ligand complexes offer model environments to study molecular interactions that are key to many catalytic processes. Here, we present a…”
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Infrared Study of OCS Binding and Size-Selective Reactivity with Gold Clusters, Aun+ (n = 1-10) by Green, Alice E, Schaller, Sascha, Meizyte, Gabriele, Rhodes, Benjamin J, Kealy, Sean P, Gentleman, Alexander S, Schöllkopf, Wieland, Fielicke, André, Mackenzie, Stuart R

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Infrared Study of OCS Binding and Size-Selective Reactivity with Gold Clusters, Au n + (n = 1–10) by Green, Alice E, Schaller, Sascha, Meizyte, Gabriele, Rhodes, Benjamin J, Kealy, Sean P, Gentleman, Alexander S, Schöllkopf, Wieland, Fielicke, André, Mackenzie, Stuart R

“…OCS binding to and reactivity with isolated gold cluster cations, Au n + (n = 1–10), has been studied by infrared multiple photon dissociation (IR-MPD)…”
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Infrared spectroscopy of closed s-shell gas-phase M+(N2O)n (M = Li, Al) ion-molecule complexes by Cunningham, Ethan M., Gentleman, Alexander S., Beardsmore, Peter W., Mackenzie, Stuart R.

“…We present the results of a combined experimental and computational study of the structures of gas-phase M + (N 2 O) n (M = Li, Al) complexes. Infrared spectra…”
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Optofluidic Photonic Crystal Fiber Microreactors for In Situ Studies of Carbon Nanodot-Driven Photoreduction by Koehler, Philipp, Lawson, Takashi, Neises, Julian, Willkomm, Janina, Martindale, Benjamin C. M, Hutton, Georgina A. M, Antón-García, Daniel, Lage, Ava, Gentleman, Alexander S, Frosz, Michael H, Russell, Philip St.J, Reisner, Erwin, Euser, Tijmen G

“…Performing quantitative in situ spectroscopic analysis on minuscule sample volumes is a common difficulty in photochemistry. To address this challenge, we use…”
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IR Signature of Size-Selective CO 2 Activation on Small Platinum Cluster Anions, Pt n - (n=4-7) by Green, Alice E, Justen, Jasmin, Schöllkopf, Wieland, Gentleman, Alexander S, Fielicke, André, Mackenzie, Stuart R

“…Infrared multiple photon dissociation spectroscopy (IR-MPD) has been employed to determine the nature of CO binding to size-selected platinum cluster anions,…”
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Infrared Spectroscopy of Au+(CH4)n Complexes and Vibrationally-Enhanced C–H Activation Reactions by Gentleman, Alexander S., Green, Alice E., Price, Daniel R., Cunningham, Ethan M., Iskra, Andreas, Mackenzie, Stuart R.

“…A combined spectroscopic and computational study of gas-phase Au + (CH 4 ) n ( n  = 3–8) complexes reveals a strongly-bound linear Au + (CH 4 ) 2 core…”
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In situ Detection of Cobaloxime Intermediates During Photocatalysis Using Hollow‐Core Photonic Crystal Fiber Microreactors by Lawson, Takashi, Gentleman, Alexander S., Pinnell, Jonathan, Eisenschmidt, Annika, Antón‐García, Daniel, Frosz, Michael H., Reisner, Erwin, Euser, Tijmen G.

“…Hollow‐core photonic crystal fibers (HC‐PCFs) provide a novel approach for in situ UV/Vis spectroscopy with enhanced detection sensitivity. Here, we…”
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Far-Infrared Synchrotron Spectroscopy and Torsional Analysis of the Important Interstellar Molecule, Vinyl Alcohol by Bunn, Hayley, Hudson, Rohan J, Gentleman, Alexander S, Raston, Paul L

“…We report far-infrared spectra (100–600 cm–1) covering the torsional bands of the important interstellar molecule, vinyl alcohol. We observed the fundamental…”
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Anion−π Interactions of Hexaaryl[3]radialenes by Evans, Jack D, Hollis, Courtney A, Hack, Sandra, Gentleman, Alexander S, Hoffmann, Peter, Buntine, Mark A, Sumby, Christopher J

“…Coordination polymers and discrete metallo-supramolecular assemblies of hexaaryl[3]radialene compounds exhibit intriguing structures with short anion to…”
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IR Signature of Size‐Selective CO2 Activation on Small Platinum Cluster Anions, Ptn− (n=4–7) by Green, Alice E., Justen, Jasmin, Schöllkopf, Wieland, Gentleman, Alexander S., Fielicke, André, Mackenzie, Stuart R.

“…Infrared multiple photon dissociation spectroscopy (IR‐MPD) has been employed to determine the nature of CO2 binding to size‐selected platinum cluster anions,…”
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Facile Decarboxylation of Propiolic Acid on a Ruthenium Center and Related Chemistry by Bowie, John H, Bruce, Michael I, Buntine, Mark A, Gentleman, Alexander S, Graham, David C, Low, Paul J, Metha, Gregory F, Mitchell, Cassandra, Parker, Christian R, Skelton, Brian W, White, Allan H

“…Spontaneous decarboxylation of RCCCO2H (R = H, Ph) occurs in reactions with RuCl(PP)Cp (PP = (PPh3)2, dppe) to give [Ru(CCHR)(PP)Cp]+. Computational studies…”
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