Search Results - "Geckeis, Horst"
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Mineral–Water Interface Reactions of Actinides
Published in Chemical reviews (13-02-2013)“…An examination of how light actinide ions react at the mineral-aqeuous solution interface is offered, focusing on sorption reaction and actinide surface…”
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Sorption of Eu(III) on quartz at high salt concentrations
Published in Colloids and surfaces. A, Physicochemical and engineering aspects (05-10-2019)“…[Display omitted] Sorption of Eu(III) onto quartz from highly saline solutions (up to 5 M NaCl) for pHc 2–9 ha s been studied by measuring sorption edges. The…”
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Implementation of cryogenic tender X‐ray HR‐XANES spectroscopy at the ACT station of the CAT‐ACT beamline at the KIT Light Source
Published in Journal of synchrotron radiation (01-01-2022)“…The ACT experimental station of the CAT‐ACT wiggler beamline at the Karlsruhe Institute of Technology (KIT) Light Source is dedicated to the investigation of…”
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Combined X-ray absorption and SEM–EDX spectroscopic analysis for the speciation of thorium in soil
Published in Scientific reports (11-04-2023)“…Mobility and bioavailability of radionuclides in the environment strongly depend on their aqueous speciation, adsorption behavior and the solubility of…”
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Reactive Transport Modelling of the Long-Term Interaction between Carbon Steel and MX-80 Bentonite at 25 °C
Published in Minerals (Basel) (01-11-2021)“…The geological disposal in deep bedrock repositories is the preferred option for the management of high-level radioactive waste (HLW). In some of these…”
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Adaptation of an Analytical Procedure for Concurrent Determination of Np and Pu in clay samples
Published in Clays and clay minerals (01-06-2019)“…Np and Pu are two important actinides of concern for the safe long-term disposal of nuclear waste. Both actinides are, in addition, constituents of global…”
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Sensitive Redox Speciation of Iron, Neptunium, and Plutonium by Capillary Electrophoresis Hyphenated to Inductively Coupled Plasma Sector Field Mass Spectrometry
Published in Analytical chemistry (Washington) (06-10-2015)“…The long-term safety assessment for nuclear waste repositories requires a detailed understanding of actinide (geo)chemistry. Advanced analytical tools are…”
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Radioactive wastes and disposal options
Published in EPJ Web of conferences (01-01-2018)“…This paper provides for a summary of facts which are indispensable for nuclear waste disposal. Information is presented on types of radioactive wastes and the…”
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Interlink between solubility, structure, surface and thermodynamics in the ThO2(s, hyd)–H2O(l) system
Published in Frontiers in chemistry (15-11-2022)“…The impact of temperature on a freshly precipitated ThO 2 (am, hyd) solid phase was investigated using a combination of undersaturation solubility experiments…”
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Bentonite Nanoparticle Stability and the Effect of Fulvic Acids: Experiments and Modelling
Published in Colloids and interfaces (01-06-2020)“…In this study, the critical coagulation concentration (CCC) for FEBEX bentonite colloids is determined by colloid coagulation studies under variation of pH,…”
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Fifteen Years of Radionuclide Research at the KIT Synchrotron Source in the Context of the Nuclear Waste Disposal Safety Case
Published in Geosciences (Basel) (01-02-2019)“…For more than 120 years, systematic studies of X-ray interaction with matter have been the basis for our understanding of materials—both of natural or man-made…”
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A Spectroscopic Characterization and Quantification of M(III)/Clay Mineral Outer-Sphere Complexes
Published in Environmental science & technology (15-10-2008)“…For the long-term safety assessment of deep radioactive waste repositories an understanding of the interactions of actinides with mineral surfaces at a…”
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13
Sorption of Eu(III) on a Natural Hematite: Application of a Surface Complexation Model
Published in Journal of colloid and interface science (01-12-1998)“…The solid/water interface reaction is investigated for the sorption of the Eu3+ion onto a well-characterized natural hematite at pH ≤6 in 0.1 mol/L NaClO4…”
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Retention of Iodide and Chloride by Formation of a Green Rust Solid Solution GR-Cl1-xIx: A Multiscale Approach
Published in Inorganic chemistry (19-07-2021)Get full text
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Citrate sorption on cement hydrates
Published in Cement and concrete research (01-04-2024)“…The interaction of citrate with hydrated Portland cement and its main hydrates: C-S-H (0.8 ≤ Ca/Si ≤ 1.4), ettringite, monosulfo-, hemi- and monocarboaluminate…”
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Retention of Iodide and Chloride by Formation of a Green Rust Solid Solution GR-Cl1–x I x : A Multiscale Approach
Published in Inorganic chemistry (19-07-2021)“…The uptake of iodide and chloride during the synthesis of green rust (GR), the Fe endmember of the layered double hydroxide (LDH) group, was investigated. GR…”
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Retention of Iodide and Chloride by Formation of a Green Rust Solid Solution GR-Cl 1– x I x : A Multiscale Approach
Published in Inorganic chemistry (19-07-2021)Get full text
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Corrigendum to “Sorption of americium / europium onto magnetite under saline conditions: Batch experiments, surface complexation modelling and X-ray absorption spectroscopy study” [J. Colloid Interface Sci. 561 (2020) 708–718]
Published in Journal of colloid and interface science (15-02-2024)Get full text
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Uptake of Cm (III) and Eu (III) by C–S–H phases under saline conditions in presence of EDTA: A batch sorption and TRLFS study
Published in Applied geochemistry (01-09-2024)“…Eu (III) and Cm (III) uptake by calcium silicate hydrate phases (C–S–H) was investigated in presence of EDTA in NaCl and CaCl2 solutions. Different…”
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Sorption of Cm(III) and Eu(III) onto clay minerals under saline conditions: Batch adsorption, laser-fluorescence spectroscopy and modeling
Published in Geochimica et cosmochimica acta (15-02-2015)“…The present work reports experimental data for trivalent metal cation (Cm/Eu) sorption onto illite (Illite du Puy) and montmorillonite (Na-SWy-2) in NaCl…”
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