Search Results - "Gebbink, Robertus J M Klein"

Enantioselective C–H Lactonization of Unactivated Methylenes Directed by Carboxylic Acids by Cianfanelli, Marco, Olivo, Giorgio, Milan, Michela, Klein Gebbink, Robertus J. M, Ribas, Xavi, Bietti, Massimo, Costas, Miquel

“…The formidable challenges of controlling site-selectivity, enantioselectivity, and product chemoselectivity make asymmetric C–H oxidation a generally unsolved…”
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Non-Noble Metal Aromatic Oxidation Catalysis: From Metalloenzymes to Synthetic Complexes by Eduard Masferrer-Rius, Robertus J. M. Klein Gebbink

“…The development of selective aromatic oxidation catalysts based on non-noble metals has emerged over the last decades, mainly due to the importance of phenol…”
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Catalytic Performance of Symmetrical and Unsymmetrical Sulfur-Containing Pincer Complexes: Synthesis and Tandem Catalytic Activity of the First PCS-Pincer Palladium Complex by Gagliardo, Marcella, Selander, Nicklas, Mehendale, Nilesh C., van Koten, Gerard, Klein Gebbink, Robertus J. M., Szabó, Kálmán J.

“…The synthesis and catalytic applications of a new aryl‐based unsymmetrical PCS‐pincer complex are reported. Preparation of the robust air‐ and moisture‐stable…”
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Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies by Bruijnincx, Pieter C A, van Koten, Gerard, Klein Gebbink, Robertus J M

“…Iron-containing enzymes are one of Nature's main means of effecting key biological transformations. The mononuclear non-heme iron oxygenases and oxidases have…”
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Synthesis and Characterization of a Brønsted Pair Functionalized Shape-Persistent Macrocycle by Vliegenthart, Annette B, Welling, Frank A. L, Roemelt, Michael, Klein Gebbink, Robertus J. M, Otte, Matthias

“…The first shape-persistent macrocycle 1 offering a Brønsted pair functionalized interior is described. Via postcyclization transformation, this heterosequenced…”
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Efficient Exciton Transport in Layers of Self-Assembled Porphyrin Derivatives by Huijser, Annemarie, Suijkerbuijk, Bart M. J. M, Klein Gebbink, Robertus J. M, Savenije, Tom J, Siebbeles

“…The photosynthetic apparatus of green sulfur bacteria, the chlorosome, is generally considered as a highly efficient natural light-harvesting system. The…”
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Synthesis, Structure and Reactivity of a Mononuclear N,N,O‐Bound Fe(II) α‐Keto‐Acid Complex by Monkcom, Emily C., Gómez, Laura, Lutz, Martin, Ye, Shengfa, Bill, Eckhard, Costas, Miquel, Klein Gebbink, Robertus J. M.

“…A bulky, tridentate phenolate ligand (ImPh2NNOtBu) was used to synthesise the first example of a mononuclear, facial, N,N,O‐bound iron(II) benzoylformate…”
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Combining metal-metal cooperativity, metal-ligand cooperativity and chemical non-innocence in diiron carbonyl complexes by van Beek, Cody B, van Leest, Nicolaas P, Lutz, Martin, de Vos, Sander D, Klein Gebbink, Robertus J M, de Bruin, Bas, Broere, Daniël L J

“…Several metalloenzymes, including [FeFe]-hydrogenase, employ cofactors wherein multiple metal atoms work together with surrounding ligands that mediate…”
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E‐selective Semi‐hydrogenation of Alkynes under Mild Conditions by a Diruthenium Hydride Complex by Beek, Cody B., Killian, Lars, Lutz, Martin, Weingarth, Markus, Asundi, Arun S., Sarangi, Ritimukta, Klein Gebbink, Robertus J. M., Broere, Daniël L. J.

“…The synthesis, characterization and catalytic activity of a new class of diruthenium hydrido carbonyl complexes bound to the tBuPNNP expanded pincer ligand is…”
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A Cp‐based Molybdenum Catalyst for the Deoxydehydration of Biomass‐derived Diols by Li, Jing, Lutz, Martin, Klein Gebbink, Robertus J. M.

“…Dioxo‐molybdenum complexes have been reported as catalysts for the deoxydehydration (DODH) of diols and polyols. Here, we report on the DODH of diols using…”
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Synthesis of Cyclopentadienyl‐Based Tricarbonyl Rhenium Complexes and Some Unusual Reactivities of Cyclopentadienyl Substituents by Raju, Suresh, van Slagmaat, Christian A. M. R., Lutz, Martin, Kleijn, Hendrik, Jastrzebski, Johann T. B. H., Moret, Marc‐Etienne, Klein Gebbink, Robertus J. M.

“…Cyclopentadienyl‐based (Cp‐based) tricarbonyl rhenium complexes [Cp′Re(CO)3] are convenient precursors for the corresponding Cp‐based trioxorhenium complexes…”
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Structurally Modelling the 2‐His‐1‐Carboxylate Facial Triad with a Bulky N,N,O Phenolate Ligand by Monkcom, Emily C., Bruin, Daniël, Vries, Annemiek J., Lutz, Martin, Ye, Shengfa, Klein Gebbink, Robertus J. M.

“…We present the synthesis and coordination chemistry of a bulky, tripodal N,N,O ligand, ImPh2NNOtBu (L), designed to model the 2‐His‐1‐carboxylate facial triad…”
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Hydrogen Evolution Electrocatalysis with a Molecular Cobalt Bis(alkylimidazole)methane Complex in DMF: a Critical Activity Analysis by Vos, Sander D., Otten, Maartje, Wissink, Tim, Broere, Daniël L. J., Hensen, Emiel J. M., Klein Gebbink, Robertus J. M.

“…[Co(HBMIMPh2)2](BF4)2 (1) [HBMIMPh2=bis(1‐methyl‐4,5‐diphenyl‐1H‐imidazol‐2‐yl)methane] was investigated for its electrocatalytic hydrogen evolution…”
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Facile electrochemical affinity measurements of small and large molecules by Zaree, Pouya, Tomris, Ilhan, de Vos, Sander D, van der Woude, Roosmarijn, Flesch, Frits M, Klein Gebbink, Robertus J. M, de Vries, Robert P, Pieters, Roland J

“…A novel miniaturized sensor for electrochemical detection that contains graphene- and gold nanoparticles was functionalized with proteins. Using cyclic…”
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Aryl Radical Geometry Determines Nanographene Formation on Au(111) by Jacobse, Peter H., van den Hoogenband, Adri, Moret, Marc-Etienne, Klein Gebbink, Robertus J. M., Swart, Ingmar

“…The Ullmann coupling has been used extensively as a synthetic tool for the formation of C−C bonds on surfaces. Thus far, most syntheses made use of aryl…”
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Mono- and Dinuclear Iron Complexes of Bis(1-methylimidazol-2-yl)ketone (bik): Structure, Magnetic Properties, and Catalytic Oxidation Studies by Bruijnincx, Pieter C. A, Buurmans, Inge L. C, Huang, Yuxing, Juhász, Gergely, Viciano-Chumillas, Marta, Quesada, Manuel, Reedijk, Jan, Lutz, Martin, Spek, Anthony L, Münck, Eckard, Bominaar, Emile L, Klein Gebbink, Robertus J. M

“…The newly synthesized dinuclear complex [FeIII 2(μ-OH)2(bik)4](NO3)4 (1) (bik, bis(1-methylimidazol-2-yl)ketone) shows rather short Fe···Fe (3.0723(6) Å) and…”
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Catalytic Deoxydehydration of Diols to Olefins by using a Bulky Cyclopentadiene-based Trioxorhenium Catalyst by Raju, Suresh, Jastrzebski, Johann T. B. H., Lutz, Martin, Klein Gebbink, Robertus J. M.

“…A bulky cyclopentadienyl (Cp)‐based trioxorhenium compound was developed for the catalytic deoxydehydration of vicinal diols to olefins. The…”
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Periodic Trends in the Binding of a Phosphine‐Tethered Ketone Ligand to Fe, Co, Ni, and Cu by Verhoeven, Dide G. A., van Wiggen, Maxime A. C., Kwakernaak, Joost, Lutz, Martin, Klein Gebbink, Robertus J. M., Moret, Marc‐Etienne

“…π‐Coordinating ligands are commonly found in intermediate structures in homogeneous catalysis, and are gaining interest as supporting ligands for the…”
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Synthesis of and Evidence for Electronic Communication within Heteromultimetallic Tetrakis(NCN-pincer metal)−(Metallo)porphyrin Hybrids by Suijkerbuijk, Bart M. J. M, Tooke, Duncan M, Lutz, Martin, Spek, Anthony L, Jenneskens, Leonardus W, van Koten, Gerard, Klein Gebbink, Robertus J. M

“…Several heteromultimetallic pincer−porphyrin hybrids have been prepared in excellent yields by stepwise metalation of a general precursor, [2H(Br(NCN)) 4 ],…”
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Making Fe(BPBP)-catalyzed C-H and C[double bond, length as m-dash]C oxidations more affordable by Yazerski, Vital A, Spannring, Peter, Gatineau, David, Woerde, Charlotte H M, Wieclawska, Sara M, Lutz, Martin, Kleijn, Henk, Gebbink, Robertus J M Klein

“…The limited availability of catalytic reaction components may represent a major hurdle for the practical application of many catalytic procedures in organic…”
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