Search Results - "Gatineau, David"

Bulky, Optically Active P-Stereogenic Phosphine–Boranes from Pure H-Menthylphosphinates by Gatineau, David, Giordano, Laurent, Buono, Gérard

“…The transformation of readily available pure-H-menthylphosphinates into chiral phosphinous acid-boranes permits the elaboration of bulky P-stereogenic…”
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Secondary Phosphine Oxides as Multitalented Preligands En Route to the Chemoselective Palladium‐Catalyzed Oxidation of Alcohols by Vasseur, Alexandre, Membrat, Romain, Gatineau, David, Tenaglia, Alphonse, Nuel, Didier, Giordano, Laurent

“…Secondary phosphine oxides O=PHR2 (SPOs) were identified as multitalented preligands for the chemoselective Pd‐catalyzed oxidation of alcohols by a…”
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Experimental bond dissociation energies of benzylpyridinium thermometer ions determined by threshold-CID and RRKM modeling by Gatineau, David, Memboeuf, Antony, Milet, Anne, Cole, Richard B., Dossmann, Héloïse, Gimbert, Yves, Lesage, Denis

“…[Display omitted] •BDE of benzylpyridinium ions were determined by TCID measurements and RRKM modeling.•Commercial QhQ enables relative measurements of…”
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When NHC Ligands Make a Difference in Gold Catalysis by Gatineau, David, Goddard, Jean-Philippe, Mouriès-Mansuy, Virginie, Fensterbank, Louis

“…Thanks to their unique electronic and steric properties, carbene ligands offer highly valuable features for catalysis, including homogenous gold catalysis. The…”
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Making Fe(BPBP)-catalyzed C-H and C[double bond, length as m-dash]C oxidations more affordable by Yazerski, Vital A, Spannring, Peter, Gatineau, David, Woerde, Charlotte H M, Wieclawska, Sara M, Lutz, Martin, Kleijn, Henk, Gebbink, Robertus J M Klein

“…The limited availability of catalytic reaction components may represent a major hurdle for the practical application of many catalytic procedures in organic…”
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Benchmarking Higher Energy Collision Dissociation (HCD) by Investigation of Binding Energies of Gas-phase Host\textendash Guest Complexes of Hemicryptophane Cages by Bayat, Parisa, Gatineau, David, Lesage, Denis, Martinez, Alexandre, Cole, Richard

“…Synthesis of host molecules that feature well-defined characteristics for molecular recognition of guest molecules is often a major aim of synthetic host–guest…”
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Understanding Gold‐Alkyne Activation from Bond Dissociation Energies of Gold‐Alkyne Complexes by Gatineau, David, Lesage, Denis, Guéret, Rodolphe, Mador, Samuel Danladi, Milet, Anne, Gimbert, Yves

“…A detailed approach into electronic effects of ligands on gold‐alkyne interactions has been carried out in the gas phase using tandem mass spectrometry. A…”
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A Non‐Macrocycle Thiolate‐Based Cobalt Catalyst for Selective O 2 Reduction into H 2 O by Sun, Lili, Gutierrez, Javier, Goff, Alan Le, Gatineau, David, Jackson, Timothy A., Gennari, Marcello, Duboc, Carole

“…Abstract The reduction of dioxygen to produce selectively H 2 O 2 or H 2 O is crucial in various fields. While platinum‐based materials excel in 4H + /4e −…”
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Benchmarking higher energy collision dissociation (HCD) by investigation of binding energies of gas‐phase host–guest complexes of hemicryptophane cages by Bayat, Parisa, Gatineau, David, Lesage, Denis, Martinez, Alexandre, Cole, Richard B.

“…Synthesis of host molecules that feature well‐defined characteristics for molecular recognition of guest molecules is often a major aim of synthetic host–guest…”
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Potassium Carbonate to Unlock a GaCl 3 -Catalyzed C–H Propargylation of Arenes by Vayer, Marie, Rodrigues, Sophie, Miaskiewicz, Solène, Gatineau, David, Gimbert, Yves, Gandon, Vincent, Bour, Christophe

“…A gallium-catalyzed C-H propargylation of arenes using bromoallenes is described. The development of this new reaction was first hampered by a side…”
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Exploring Phosphine Electronic Effects on Molybdenum Complexes: A Combined Photoelectron Spectroscopy and Energy Decomposition Analysis Study by Dossmann, Héloïse, Gatineau, David, Clavier, Hervé, Memboeuf, Antony, Lesage, Denis, Gimbert, Yves

“…In organometallic chemistry, especially in the catalysis area, accessing the finest tuning of a catalytic reaction pathway requires a detailed knowledge of the…”
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Potassium Carbonate to Unlock a GaCl3‑Catalyzed C–H Propargylation of Arenes by Vayer, Marie, Rodrigues, Sophie, Miaskiewicz, Solène, Gatineau, David, Gimbert, Yves, Gandon, Vincent, Bour, Christophe

“…A gallium-catalyzed C–H propargylation of electron-rich arenes using bromoallenes is described. The development of this reaction was first hampered by a side…”
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Investigation of activation energies for dissociation of host‐guest complexes in the gas phase using low‐energy collision induced dissociation by Bayat, Parisa, Gatineau, David, Lesage, Denis, Marhabaie, Sina, Martinez, Alexandre, Cole, Richard B.

“…A low‐energy collision induced dissociation (CID) (low‐energy CID) approach that can determine both activation energy and activation entropy has been used to…”
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A Non‐Macrocycle Thiolate‐Based Cobalt Catalyst for Selective O2 Reduction into H2O by Sun, Lili, Gutierrez, Javier, Goff, Alan Le, Gatineau, David, Jackson, Timothy A., Gennari, Marcello, Duboc, Carole

“…The reduction of dioxygen to produce selectively H2O2 or H2O is crucial in various fields. While platinum‐based materials excel in 4H+/4e− oxygen reduction…”
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Ligand effects in gold-carbonyl complexes: Evaluation of the bond dissociation energies using blackbody infrared radiative dissociation by Gatineau, David, Dossmann, Héloïse, Clavier, Hervé, Memboeuf, Antony, Drahos, László, Gimbert, Yves, Lesage, Denis

“…In a previous work, the ability of gold-carbonyl bond dissociation energies (BDEs) to describe ligand effects in gold(I) complexes was probed using…”
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H‑Adamantylphosphinates as Universal Precursors of P‑Stereogenic Compounds by Gatineau, David, Nguyen, Duc Hanh, Hérault, Damien, Vanthuyne, Nicolas, Leclaire, Julien, Giordano, Laurent, Buono, Gérard

“…A new family of H-adamantylphosphinates as universal precursors of P-stereogenic ligands was obtained in one step from commercial chlorophosphines. Both…”
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N‐Heterocyclic Carbene Boranes: Dual Reagents for the Synthesis of Gold Nanoparticles by Hippolyte, Laura, Sadek, Omar, Ba Sowid, Salem, Porcheron, Alexandre, Bridonneau, Nathalie, Blanchard, Sébastien, Desage‐El Murr, Marine, Gatineau, David, Gimbert, Yves, Mercier, Dimitri, Marcus, Philippe, Chauvier, Clément, Chanéac, Corinne, Ribot, François, Fensterbank, Louis

“…N‐Heterocyclic carbenes (NHCs) have drawn considerable interest in the field of nanomaterials chemistry as highly stabilizing ligands enabling the formation of…”
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Investigation of Hemicryptophane Host-Guest Binding Energies Using High-Pressure Collision-Induced Dissociation in Combination with RRKM Modeling by Bayat, Parisa, Gatineau, David, Lesage, Denis, Robert, Vincent, Martinez, Alexandre, Cole, Richard B.

“…In advancing host-guest (H-G) chemistry, considerable effort has been spent to synthesize host molecules with specific and well-defined molecular recognition…”
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Stereospecific Synthesis of α- and β-Hydroxyalkyl P-Stereogenic Phosphine-Boranes and Functionalized Derivatives: Evidence of the PO Activation in the BH3-Mediated Reduction by Lemouzy, Sébastien, Nguyen, Duc Hanh, Camy, Valentine, Jean, Marion, Gatineau, David, Giordano, Laurent, Naubron, Jean-Valère, Vanthuyne, Nicolas, Hérault, Damien, Buono, Gérard

“…Access to hydroxy‐functionalized P‐chiral phosphine–boranes has become an important field in the synthesis of P‐stereogenic compounds used as ligands in…”
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Racemization mechanism of lithium tert‐butylphenylphosphido‐borane: A kinetic insight by Fortrie, Rémy, Gatineau, David, Hérault, Damien, Béal, Aurélie, Naubron, Jean‐Valère, Giordano, Laurent, Buono, Gérard

“…The racemization mechanism of tert‐butylphenylphosphido‐borane is investigated experimentally and theoretically. Based on this converging approach, it is…”
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