Search Results - "Garibay, Sergio J."

Room-Temperature Synthesis of UiO-66 and Thermal Modulation of Densities of Defect Sites by DeStefano, Matthew R, Islamoglu, Timur, Garibay, Sergio J, Hupp, Joseph T, Farha, Omar K

“…UiO-66 is an archetypal zirconium-based metal–organic framework (MOF) that is constructed from hexanuclear zirconium oxide clusters as secondary building units…”
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A porous, electrically conductive hexa-zirconium(iv) metal-organic framework by Goswami, Subhadip, Ray, Debmalya, Otake, Ken-Ichi, Kung, Chung-Wei, Garibay, Sergio J, Islamoglu, Timur, Atilgan, Ahmet, Cui, Yuexing, Cramer, Christopher J, Farha, Omar K, Hupp, Joseph T

“…Engendering electrical conductivity in high-porosity metal-organic frameworks (MOFs) promises to unlock the full potential of MOFs for electrical energy…”
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Room Temperature Synthesis of an 8‑Connected Zr-Based Metal–Organic Framework for Top-Down Nanoparticle Encapsulation by Noh, Hyunho, Kung, Chung-Wei, Islamoglu, Timur, Peters, Aaron W, Liao, Yijun, Li, Peng, Garibay, Sergio J, Zhang, Xuan, DeStefano, Matthew R, Hupp, Joseph T, Farha, Omar K

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Postsynthetic Modification: A Versatile Approach Toward Multifunctional Metal-Organic Frameworks by Garibay, Sergio J, Wang, Zhenqiang, Tanabe, Kristine K, Cohen, Seth M

“…An isoreticular metal-organic framework (IRMOF-3) containing 2-amino-1,4-benzenedicarboxylic acid (NH2−BDC) as a building block is shown to undergo chemical…”
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Microwave-Assisted Cyanation of an Aryl Bromide Directly on a Metal−Organic Framework by Kim, Min, Garibay, Sergio J, Cohen, Seth M

“…A microwave-assisted postsynthetic modification (PSM) reaction on a metal−organic framework (MOF) has been realized. Cyanation of the Zr4+-based UiO-66-Br was…”
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Single-Atom Ligand Changes Affect Breathing in an Extended Metal–Organic Framework by Dau, Phuong V, Kim, Min, Garibay, Sergio J, Münch, Frédéric H. L, Moore, Curtis E, Cohen, Seth M

“…2-Phenylpyridine-5,4′-dicarboxylic acid (1, dcppy), a derivative of 4,4′-biphenyldicarboxylic (2, bpdc) was used as the organic linking component for several…”
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Isoreticular synthesis and modification of frameworks with the UiO-66 topology by Garibay, Sergio J, Cohen, Seth M

“…Amino, bromo, nitro, and naphthalene functionalized UiO-66 metal-organic frameworks have been synthesized through reticular chemistry. UiO-66-NH(2) is shown to…”
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Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)NiII Complexes by Madrahimov, Sherzod T, Gallagher, James R, Zhang, Guanghui, Meinhart, Zachary, Garibay, Sergio J, Delferro, Massimiliano, Miller, Jeffrey T, Farha, Omar K, Hupp, Joseph T, Nguyen, SonBinh T

“…NU-1000-(bpy)­Ni II , a highly porous MOF material possessing well-defined (bpy)­NiII moieties, was prepared through solvent-assisted ligand incorporation…”
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Evaluation of Heterogeneous Metal−Organic Framework Organocatalysts Prepared by Postsynthetic Modification by Garibay, Sergio J, Wang, Zhenqiang, Cohen, Seth M

“…A metal−organic framework (MOF) containing 2-amino-1,4-benzenedicarboxylate (NH2−BDC) as a building block is shown to undergo chemical modification with a set…”
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Optimizing Toxic Chemical Removal through Defect‐Induced UiO‐66‐NH2 Metal–Organic Framework by Peterson, Gregory W., Destefano, Matthew R., Garibay, Sergio J., Ploskonka, Ann, McEntee, Monica, Hall, Morgan, Karwacki, Christopher J., Hupp, Joseph T., Farha, Omar K.

“…For the first time, an increasing number of defects were introduced to the metal–organic framework UiO‐66‐NH2 in an attempt to understand the…”
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Tunable Photocatalytic Singlet Oxygen Generation by Metal–Organic Frameworks via Functionalization of Pyrene-Containing Linkers by Kulisiewicz, Ann M., Garibay, Sergio J., Pozza, Gabrielle R., Browe, Matthew A., Sparr, Owen, Singh, Sukhvir, Kelly, Lisa A., DeCoste, Jared B.

“…Metal–organic frameworks (MOFs) are highly versatile materials that have shown great promise in chemical warfare agent (CWA) adsorption and decontamination…”
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Matching the Activity of Homogeneous Sulfonic Acids: The Fructose-to-HMF Conversion Catalyzed by Hierarchically Porous Sulfonic-Acid-Functionalized Porous Organic Polymer (POP) Catalysts by Du, Matthew, Agrawal, Ananya M, Chakraborty, Sanjiban, Garibay, Sergio J, Limvorapitux, Rungmai, Choi, Baikleem, Madrahimov, Sherzod T, Nguyen, SonBinh T

“…Three HO3S-functionalized porous organic polymers (HO3S-POPs) with high surface areas (500–700 m2/g) and a broad range of porosity profiles were synthesized…”
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Spectroscopically Resolved Binding Sites for the Adsorption of Sarin Gas in a Metal–Organic Framework: Insights beyond Lewis Acidity by Harvey, Jacob A, McEntee, Monica L, Garibay, Sergio J, Durke, Erin M, DeCoste, Jared B, Greathouse, Jeffery A, Sava Gallis, Dorina F

“…Here we report molecular level details regarding the adsorption of sarin (GB) gas in a prototypical zirconium-based metal–organic framework (MOF, UiO-66). By…”
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Optimizing Toxic Chemical Removal through Defect-Induced UiO-66-NH 2 Metal-Organic Framework by Peterson, Gregory W, Destefano, Matthew R, Garibay, Sergio J, Ploskonka, Ann, McEntee, Monica, Hall, Morgan, Karwacki, Christopher J, Hupp, Joseph T, Farha, Omar K

“…For the first time, an increasing number of defects were introduced to the metal-organic framework UiO-66-NH in an attempt to understand the structure-activity…”
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Controlling the heterogeneous catalysis of zirconium clusters within a porous SBA-15 scaffold by Kulisiewicz, Ann M., Garibay, Sergio J., Tovar, Trenton B., Browe, Matthew A., Harland, Jill B., Navin, Jason K.

“…Metal-organic frameworks (MOFs) with Zr-based secondary building units (SBUs) have shown promise as materials for the catalytic degradation of chemical warfare…”
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Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)Ni II Complexes by Madrahimov, Sherzod T., Gallagher, James R., Zhang, Guanghui, Meinhart, Zachary, Garibay, Sergio J., Delferro, Massimiliano, Miller, Jeffrey T., Farha, Omar K., Hupp, Joseph T., Nguyen, SonBinh T.

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A porous, electrically conductive hexa-zirconium(iv) metal-organic frameworkElectronic supplementary information (ESI) available: Specifics on materials used, synthesis of the MOFs, fabrication of pressed pellets for conductivity measurements, details of characterization, instrumentation, and computational methods are available in the supporting information. See DOI: 10.1039/c8sc00961a by Goswami, Subhadip, Ray, Debmalya, Otake, Ken-ichi, Kung, Chung-Wei, Garibay, Sergio J, Islamoglu, Timur, Atilgan, Ahmet, Cui, Yuexing, Cramer, Christopher J, Farha, Omar K, Hupp, Joseph T

“…Engendering electrical conductivity in high-porosity metal-organic frameworks (MOFs) promises to unlock the full potential of MOFs for electrical energy…”
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A porous, electrically conductive hexa-zirconium(iv) metal–organic framework† †Electronic supplementary information (ESI) available: Specifics on materials used, synthesis of the MOFs, fabrication of pressed pellets for conductivity measurements, details of characterization, instrumentation, and computational methods are available in the supporting information. See DOI: 10.1039/c8sc00961a by Goswami, Subhadip, Ray, Debmalya, Otake, Ken-ichi, Kung, Chung-Wei, Garibay, Sergio J., Islamoglu, Timur, Atilgan, Ahmet, Cui, Yuexing, Cramer, Christopher J., Farha, Omar K., Hupp, Joseph T.

“…Electrical conductivity is engendered in a pyrene containing hexa-zirconium( iv ) metal–organic framework by physically encapsulating fullerenes within MOF…”
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Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)Ni II Complexes by Madrahimov, Sherzod T., Gallagher, James R., Zhang, Guanghui, Meinhart, Zachary, Garibay, Sergio J., Delferro, Massimiliano, Miller, Jeffrey T., Farha, Omar K., Hupp, Joseph T., Nguyen, SonBinh T.

“…NU-1000-(bpy)Ni-II, a highly porous MOF material possessing well-defined (bpy)Ni-II moieties, was prepared through solvent-assisted ligand incorporation…”
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Functionalization of Metal-Organic Frameworks with Metalloligands and Postsynthetic Modification by Garibay, Sergio J

“…Metal-organic frameworks (MOFs) are a hybrid class of porous materials that are comprised of metal clusters and bridging organic ligands. The modular nature…”
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