Search Results - "García, Juventino J"
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Non-Pincer Mn(I) Organometallics for the Selective Catalytic Hydrogenation of Nitriles to Primary Amines
Published in ACS catalysis (04-01-2019)“…We report herein selective catalytic hydrogenation of nitriles to primary amines with the use of the non-pincer Mn(I) compound…”
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Hydrogenation of Biomass-Derived Levulinic Acid into γ‑Valerolactone Catalyzed by Palladium Complexes
Published in ACS catalysis (06-03-2015)“…The selective catalytic hydrogenation and cyclization of levulinic acid (LA) into valuable γ-valerolactone (GVL) catalyzed by different palladium compounds was…”
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Homogeneous Manganese-Catalyzed Hydrofunctionalizations of Alkenes and Alkynes: Catalytic and Mechanistic Tendencies
Published in ACS omega (25-10-2022)“…In recent years, many manganese-based homogeneous catalytic precursors have been developed as powerful alternatives in organic synthesis. Among these, the…”
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On the Catalytic Hydrodefluorination of Fluoroaromatics Using Nickel Complexes: The True Role of the Phosphine
Published in Journal of the American Chemical Society (26-03-2014)“…Homogeneous catalytic hydrodefluorination (HDF) of fluoroaromatics under thermal conditions was achieved using nickel(0) compounds of the type…”
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5
Manganese‐Catalyzed Transfer Hydrogenation of Nitriles with 2‐Butanol as the Hydrogen Source
Published in ChemCatChem (07-11-2019)“…We report herein the first example of a homogeneous manganese catalyzed transfer hydrogenation of nitriles using 2‐BuOH as the hydrogen source. Compound…”
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6
Iron Catalyzed CO2 Activation with Organosilanes
Published in Catalysis letters (01-04-2018)“…Iron nanoparticles generated in situ from [Fe 3 (CO) 12 ] catalyzed CO 2 reduction in the presence of Et 3 SiH as a reductant and tetrabutylammonium fluoride…”
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Nickel‐Catalyzed Hydrophosphonylation and Hydrogenation of Aromatic Nitriles Assisted by Lewis Acid
Published in ChemCatChem (20-02-2019)“…In this paper, we describe the catalytic hydrophosphonylation of several aromatic nitriles used to synthesize α‐aminophosphonates (α‐APs) using commercially…”
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Synthesis of pyrrolidones and quinolines from the known biomass feedstock levulinic acid and amines
Published in Tetrahedron letters (17-02-2016)“…[Display omitted] The catalytic conversion of biomass-derived compounds into value-added products such as food additives, agrochemical components, and…”
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Transfer Hydrogenation of Levulinic Acid to γ‐Valerolactone and Pyrrolidones Using a Homogeneous Nickel Catalyst
Published in European journal of inorganic chemistry (05-02-2021)“…We report a well‐defined homogeneous nickel‐based catalyst using the complex [dippeNi(COD)] (dippe=1,2‐bis(diisopropyl phosphino)ethane) as a catalytic…”
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10
Levulinic Acid Hydrogenation with Homogeneous Cu(I) Catalyst
Published in ChemCatChem (20-09-2022)“…We report the first well‐defined homogeneous copper‐based catalyst for levulinic acid (LVA) hydrogenation using complex [(PPh3)2Cu(k2‐O,O‐LVA)] as a copper…”
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11
Catalysis in Latin America
Published in ChemCatChem (21-04-2023)“…This collection of papers from Latin American catalytic researchers was born from online interaction during the trialing times of the COVID‐19 pandemic. The…”
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Mononuclear and Tetranuclear Copper(II) Complexes Bearing Amino Acid Schiff Base Ligands: Structural Characterization and Catalytic Applications
Published in Molecules (Basel, Switzerland) (01-12-2021)“…Two new glycine-Schiff base copper(II) complexes were synthesized. Single crystal X-ray diffraction (SCXRD) allowed us to establish the structure of both…”
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Nickel-catalyzed reduction of ketones with water and triethylsilane
Published in Inorganica Chimica Acta (01-09-2017)“…[Display omitted] •Ketone reduction.•Transfer hydrogenation.•Water and silanes.•Catalytic process.•Enantio selectivity. The acetophenone (1a) reduction using…”
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14
Nickel-Catalyzed Alkylation and Transfer Hydrogenation of α,β-Unsaturated Enones with Methanol
Published in Organometallics (23-01-2012)“…Complexes of the type [{(dippe)Ni} n (η2-Cα,Cβ-1,4-dien-3-one)] (dippe = 1,2-bis(diisopropylphosphino)ethane); n= 1, 2; enone = aromatic 1,4-pentadien-3-ones)…”
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15
Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines
Published in Dalton transactions : an international journal of inorganic chemistry (14-11-2014)“…Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved…”
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Toward Amines, Imines, and Imidazoles: A Viewpoint on the 3d Transition-Metal-Catalyzed Homogeneous Hydrogenation of Nitriles
Published in ACS catalysis (17-07-2020)“…Mn-, Fe-, Co-, and Ni-based catalytic precursors have been reported for the homogeneous 3d transition-metal-catalyzed hydrogenation of nitriles. We present…”
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Stereoselective Hydrogenation of Aromatic Alkynes Using Water, Triethylsilane, or Methanol, Mediated and Catalyzed by Ni(0) Complexes
Published in Inorganic chemistry (05-01-2009)“…The use of complexes of the type [(P-P)Ni(η2-C,C-alkyne)] (P-P = 1,2-bis(di-isopropyl-phosphinoethane or 1,2-bis(diterbutylphosphino-ethane) in the presence of…”
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18
Nickel-Catalyzed Transfer Hydrogenation of Benzonitriles with 2‑Propanol and 1,4-Butanediol as the Hydrogen Source
Published in ACS omega (31-05-2017)“…The homogeneous transfer hydrogenation of benzonitrile with 2-propanol or 1,4-butanediol produced N-benzylidene benzylamine (BBA, 85% yield) using 5 mol %…”
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Experimental and Theoretical Examination of C−CN and C−H Bond Activations of Acetonitrile Using Zerovalent Nickel
Published in Journal of the American Chemical Society (20-06-2007)“…Experimental and density functional theory show that the reaction of acetonitrile with a zerovalent nickel bis(dialkylphosphino)ethane fragment (alkyl =…”
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Experimental and Theoretical Examination of C−CN Bond Activation of Benzonitrile Using Zerovalent Nickel
Published in Organometallics (11-08-2008)“…The nickel(0) fragment [Ni(dippe)] was reacted with benzonitrile and initially formed both η2-nitrile and η2-arene complexes at −60 °C. When the sample was…”
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