Search Results - "García Gómez, Carlos"
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A High‐Capacity Negative Electrode for Asymmetric Supercapacitors Based on a PMo12 Coordination Polymer with Novel Water‐Assisted Proton Channels
Published in Small (Weinheim an der Bergstrasse, Germany) (01-07-2020)“…The development of a negative electrode for supercapacitors is a critical challenge for the next‐generation of energy‐storage devices. Herein, two new…”
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Efficient Electron Transfer from an Electron‐Reservoir Polyoxometalate to Dual‐Metal‐Site Metal‐Organic Frameworks for Highly Efficient Electroreduction of Nitrogen
Published in Advanced functional materials (01-07-2023)“…Precise design and construction of catalysts with satisfied performance for ambient electrolytic nitrogen reduction reaction (e‐NRR) is extremely challenging…”
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Polyoxometalate-based metal-organic frameworks for boosting electrochemical capacitor performance
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-10-2019)“…[Display omitted] •Integrating POMs with MOFs to construct stable and versatile POMOFs.•Five novel crystalline POMOFs are innovatively employed as capacitor…”
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Polyoxometalate Metal–Organic Frameworks: Keggin Clusters Encapsulated into Silver-Triazole Nanocages and Open Frameworks with Supercapacitor Performance
Published in Inorganic chemistry (02-12-2019)“…To investigate the relationship between the structures of polyoxometalate host–guest materials and their energy-storage performance, three novel…”
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Solvent-Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer
Published in Advanced materials (Weinheim) (18-04-2013)“…A coordination polymer is fully exfoliated by solvent‐assisted interaction only. The soft‐delamination process results from the structure of the starting…”
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Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals
Published in Nature chemistry (01-08-2016)“…The consequence of unpaired electrons in organic molecules has fascinated and confounded chemists for over a century. The study of open-shell molecules has…”
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Nanosheets of Two-Dimensional Magnetic and Conducting Fe(II)/Fe(III) Mixed-Valence Metal–Organic Frameworks
Published in ACS applied materials & interfaces (09-08-2017)“…We report the synthesis, magnetic properties, electrical conductivity, and delamination into thin nanosheets of two anilato-based Fe(II)/Fe(III)…”
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Two Novel Polyoxometalate-Encapsulated Metal–Organic Nanotube Frameworks as Stable and Highly Efficient Electrocatalysts for Hydrogen Evolution Reaction
Published in ACS applied materials & interfaces (19-09-2018)“…Two novel polyoxometalate (POM)-encapsulated metal–organic nanotube (MONT) framework crystalline materials with unprecedented copper-mixed ligands, HUST-200…”
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Molecule Isomerism Modulates the Diradical Properties of Stable Singlet Diradicaloids
Published in Journal of the American Chemical Society (22-01-2020)“…Inclusion of quinoidal cores in conjugated hydrocarbons is a common strategy to modulate the properties of diradicaloids formed by aromaticity recovery within…”
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Metal vs Ligand Oxidation: Coexistence of Both Metal-Centered and Ligand-Centered Oxidized Species
Published in Inorganic chemistry (25-03-2024)“…A series of two-electron-oxidized cobalt porphyrin dimers have been synthesized upon controlled oxidations using halogens. Rather unexpectedly, X-ray…”
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Monoradicals and Diradicals of Dibenzofluoreno[3,2‑b]fluorene Isomers: Mechanisms of Electronic Delocalization
Published in Journal of the American Chemical Society (02-12-2020)“…The preparation of a series of dibenzo- and tetrabenzo-fused fluoreno[3,2-b]fluorenes is disclosed, and the diradicaloid properties of these molecules are…”
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Cobalt Electrolyte/Dye Interactions in Dye-Sensitized Solar Cells: A Combined Computational and Experimental Study
Published in Journal of the American Chemical Society (28-11-2012)“…We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO2 surfaces…”
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Dinor[7]helicene and Beyond: Divergent Synthesis of Chiral Diradicaloids with Variable Open-Shell Character
Published in Angewandte Chemie International Edition (18-09-2023)“…Diradicaloid helicenes constructed formally by non-benzenoid double π-extension of phenanthrene were synthesized by a common strategy involving double…”
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POMCPs with Novel Two Water‐Assisted Proton Channels Accommodated by MXenes for Asymmetric Supercapacitors
Published in Small (Weinheim an der Bergstrasse, Germany) (01-07-2022)“…To develop high‐performance supercapacitors, the negative electrode is at present viewed as one of the most challenging tasks for obtaining the next‐generation…”
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Synthesis of a Polyoxometalate-Encapsulated Metal–Organic Framework via In Situ Ligand Transformation Showing Highly Catalytic Activity in Both Hydrogen Evolution and Dye Degradation
Published in Inorganic chemistry (01-08-2022)“…In situ molecular transformation under hydrothermal conditions is a feasible method to introduce distinct organic ligands and suppress competitive reactions…”
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Anilato‐Based Coordination Polymers with Slow Relaxation of the Magnetization: Role of the Synthetic Method and Anilato Ligand
Published in Chemistry : a European journal (17-05-2024)“…We have prepared and characterized three coordination polymers formulated as [Dy2(C6O4Cl2)3(fma)6] ⋅ 4.5fma (1) and [Dy2(C6O4X2)3(fma)6] ⋅ 4fma ⋅ 2H2O with…”
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Probing the Influence of Alkyne Substitution on the Electronic and Magnetic Properties of Diindeno[1,2‑b;1′,2′‑i]anthracenes
Published in Journal of organic chemistry (04-10-2024)“…To further the ability to manipulate the properties of open-shell molecules, logical and incremental modifications to molecular structure are key steps that…”
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A Family of Layered Chiral Porous Magnets Exhibiting Tunable Ordering Temperatures
Published in Inorganic chemistry (03-09-2013)“…A simple change of the substituents in the bridging ligand allows tuning of the ordering temperatures, T c, in the new family of layered chiral magnets…”
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An Open‐Shell Coronoid with Hybrid Chichibabin–Schlenk Conjugation
Published in Angewandte Chemie International Edition (04-10-2021)“…A hexaradicaloid molecule with alternating Kekulé and non‐Kekulé connectivities between adjacent spin centers was obtained by fusing two conjugation motifs in…”
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Medium Diradical Character, Small Hole and Electron Reorganization Energies and Ambipolar Transistors in Difluorenoheteroles
Published in Angewandte Chemie International Edition (15-08-2022)“…Four difluorenoheteroles having a central quinoidal core with the heteroring varying as furan, thiophene, its dioxide derivative and pyrrole have shown to be…”
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