Search Results - "Gapurenko, Olga A."

From a (Silatrigerma)cyclobutenylium Ion to a (Silatrigerma)cyclobutenyl Radical and Back by Lee, Vladimir Ya, Ito, Yuki, Gapurenko, Olga A, Minyaev, Ruslan M, Gornitzka, Heinz, Sekiguchi, Akira

“…(Silatrigerma)­cyclobutenylium ion salt 2 + ·[B­(C 6 F 5 ) 4 ] – was readily prepared by the reaction of cyclotrigermene 1 with an equimolar amount of…”
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Titanium Germylidenes by Lee, Vladimir Ya, Sakai, Ryo, Takanashi, Kazunori, Gapurenko, Olga A., Minyaev, Ruslan M., Gornitzka, Heinz, Sekiguchi, Akira

“…Two novel 18‐electron titanium germylene complexes, Cp2Ti(L)=Ge[Si3(SiMetBu2)4] 3 b (L=Me3P) and 3 c (L=XylNC), were synthesized, isolated, and structurally…”
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A Cationic Phosphapyramidane by Lee, Vladimir Ya, Sugasawa, Haruka, Gapurenko, Olga A., Minyaev, Ruslan M., Minkin, Vladimir I., Gornitzka, Heinz, Sekiguchi, Akira

“…Pyramidanes C[C4R4] constitute a novel class of highly strained and reactive polyhedral clusters that attracted a great deal of attention of both theoreticians…”
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[2+2] Cycloadduct of Titanium Silylidene and Benzonitrile by Lee, Vladimir Ya, Horiguchi, Satoru, Gapurenko, Olga A., Minyaev, Ruslan M., Minkin, Vladimir I., Gornitzka, Heinz, Sekiguchi, Akira

“…The first [2+2] cycloadduct of the transition metal silylene complex and nitrile was synthesized by the reaction of titanium silylidene and benzonitrile. Only…”
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Pentagermapyramidane: Crystallizing the "Transition-State" Structure by Lee, Vladimir Ya, Ito, Yuki, Gapurenko, Olga A., Sekiguchi, Akira, Minkin, Vladimir I., Minyaev, Ruslan M., Gornitzka, Heinz

“…The first example of the homonuclear pyramidanes, pentagermapyramidane, was synthesized, fully characterized, and computationally studied to reveal its…”
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From a Si3-Cyclopropene to a Si3S-Bicyclo[1.1.0]butane to a Si3S-Cyclopropene to a Si3S2-Bicyclo[1.1.0]butane: Back-and-Forth, and In-Between by Lee, Vladimir Ya, Gapurenko, Olga A., Miyazaki, Shogo, Sekiguchi, Akira, Minyaev, Ruslan M., Minkin, Vladimir I., Gornitzka, Heinz

“…Compact and highly reactive bicyclo[1.1.0]butanes constitute one of the most fascinating classes of organic compounds. Furthermore, interplay of…”
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Theoretical Prediction for Synthetic Realization: Pyramidal Systems ClE[E′4R4] (E = B–Ga, E′ = C–Ge, R = SiMe3, SiMetBu2): A DFT Study by Minkin, Vladimir I., Minyaev, Ruslan M., Lee, Vladimir Ya, Gapurenko, Olga A.

“…Structure and bonding of hybrid group 13/14 pyramidal molecules ClE[E′4R4] (E = B–Ga, E′ = C–Ge, R = SiMe3, SiMetBu2) were studied by DFT calculations. Six…”
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Titanium Germylidenes by Lee, Vladimir Ya, Sakai, Ryo, Takanashi, Kazunori, Gapurenko, Olga A., Minyaev, Ruslan M., Gornitzka, Heinz, Sekiguchi, Akira

“…Two novel 18‐electron titanium germylene complexes, Cp2Ti(L)=Ge[Si3(SiMetBu2)4] 3 b (L=Me3P) and 3 c (L=XylNC), were synthesized, isolated, and structurally…”
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Heavy Tetrel Clusters Based on the Bicyclobutane Framework: Bicyclo[1.1.0]butanes, [1.1.1]Propellanes, and Tricyclo[2.1.0.02,5]pentanes by Ya. Lee, Vladimir, Gapurenko, Olga A.

“…In this review, the current state of affairs in the novel field of the group 14 element clusters based on the bicyclo[1.1.0]butane framework, namely,…”
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Tuning Philicity of Dichlorosilylene: Nucleophilic Behavior of the Dichlorosilylene–NHC Complex Cl2Si–IPr by Lee, Vladimir Ya, Horiguchi, Satoru, Sekiguchi, Akira, Gapurenko, Olga A, Gribanova, Tatyana N, Minkin, Vladimir I, Gornitzka, Heinz

“…Novel unsaturated four-membered ring disilene, 3,3-dichloro-1,2,4,4-tetrakis­[di-tert-butyl­(methyl)­silyl]-1Δ-1,2,3,4-trisilagermetene, was synthesized by the…”
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Electrophilic Behavior of the “Nucleophilic” Pyramidane: Reactivity of Ge‐Pyramidane towards Organolithium Reagents by Lee, Vladimir Ya, Wang, Junkang, Sasamori, Takahiro, Gapurenko, Olga A., Minyaev, Ruslan M., Minkin, Vladimir I., Takeuchi, Katsuhiko, Fukaya, Norihisa, Gornitzka, Heinz

“…The particular reactivity of the recently discovered class of the main group element polyhedral clusters, pyramidanes, remains largely unexplored. In this…”
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Hybrid Bicyclo[1.1.0]butanes [(R4Si3)CH2] and [(R4Si2Ge)CH2] (R = SiMe t Bu2): Synthesis and Thermal Isomerization to Alkyl-Substituted Cyclopropenes [R3Si3]CH2R and [R3Si2Ge]CH2R by Lee, Vladimir Ya, Yasuda, Hiroyuki, Gapurenko, Olga A., Minyaev, Ruslan M., Gornitzka, Heinz, Sekiguchi, Akira

“…Hybrid bicyclo[1.1.0]­butanes comprised of different group 14 elements, namely, 1,2,3-trisilabicyclo[1.1.0]­butane and 1,3-disila-2-germabicyclo[1.1.0]­butane,…”
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1‑Chloroalumole by Lee, Vladimir Ya, Sugasawa, Haruka, Gapurenko, Olga A, Minyaev, Ruslan M, Minkin, Vladimir I, Gornitzka, Heinz, Sekiguchi, Akira

“…A representative of the stable alumoles with a chlorine substituent at the aluminum atom was synthesized by the coupling of a cyclobutadiene dianion derivative…”
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From Borapyramidane to Borole Dianion by Lee, Vladimir Ya, Sugasawa, Haruka, Gapurenko, Olga A, Minyaev, Ruslan M, Minkin, Vladimir I, Gornitzka, Heinz, Sekiguchi, Akira

“…Nonclassical pyramidanes with their inverted tetrahedral configuration of the apical atom are among the most challenging synthetic targets in cluster…”
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Bis(stibahousene) by Lee, Vladimir Ya, Ota, Kei, Ito, Yuki, Gapurenko, Olga A, Sekiguchi, Akira, Minyaev, Ruslan M, Minkin, Vladimir I, Gornitzka, Heinz

“…Strained hydrocarbons constitute one of the most prominent classes of organic compounds. Among them, bicyclo[2.1.0]­pentene (“housene”) derivatives represent a…”
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Pentagermapyramidane: Crystallizing the "Transition-State" Structure by Lee, Vladimir Ya, Ito, Yuki, Gapurenko, Olga A., Sekiguchi, Akira, Minkin, Vladimir I., Minyaev, Ruslan M., Gornitzka, Heinz

“…The first example of the homonuclear pyramidanes, pentagermapyramidane, was synthesized, fully characterized, and computationally studied to reveal its…”
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Pyramidanes by Lee, Vladimir Ya, Ito, Yuki, Sekiguchi, Akira, Gornitzka, Heinz, Gapurenko, Olga A, Minkin, Vladimir I, Minyaev, Ruslan M

“…Pyramidane is an elusive but highly desirable target for synthetic chemists that has attracted a great deal of attention because of its nonclassical structure…”
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Pyramidanes: The Covalent Form of the Ionic Compounds by Lee, Vladimir Ya, Gapurenko, Olga A, Ito, Yuki, Meguro, Takahiko, Sugasawa, Haruka, Sekiguchi, Akira, Minyaev, Ruslan M, Minkin, Vladimir I, Herber, Rolfe H, Gornitzka, Heinz

“…Pyramidane and its derivatives are among the most desirable synthetic chemistry targets, whose appealing square-pyramidal design, fascinating nonclassical…”
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Germanium, carbon-germanium, and silicon-germanium triangulenes by Gapurenko, Olga A., Starikov, Andrey G., Minyaev, Ruslan M., Minkin, Vladimir I.

“…A series of germanium‐containing triangular molecules have been studied by density functional theory (DFT) calculations. The triangulene topology of the…”
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Structure and bonding of new boron and carbon superpolyhedra by Gapurenko, Olga A., Minyaev, Ruslan M., Fedik, Nikita S., Koval, Vitaliy V., Boldyrev, Alexander I., Minkin, Vladimir I.

“…Using the DFT methods, we computationally predict the stability of cage compounds E 4n R n (E = B, C; R = H, F; n  = 4, 8, 12, 24) based on Platonic bodies and…”
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