Search Results - "Gan , Liangbing"
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[60]Fullerene‐Based Macrocycle Ligands
Published in Chemistry : a European journal (04-08-2017)“…Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various…”
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Preparation of Open-Cage Fullerenes and Incorporation of Small Molecules Through Their Orifices
Published in Advanced materials (Weinheim) (06-04-2010)“…Open‐cage fullerenes can act as hosts for small molecules such as water, nitrogen, or hydrogen, forming endohedral fullerenes. Following a brief summary of…”
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Open-cage fullerenes as tailor-made container for a single water molecule
Published in Journal of physical organic chemistry (01-10-2013)“…Water is the most important liquid on earth. Clusters of water have been investigated extensively in an effort to understand the bulk property of water. But…”
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Oxygen‐Delivery Materials: Synthesis of an Open‐Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O2
Published in Angewandte Chemie International Edition (22-10-2018)“…An open‐cage [60]fullerene was prepared through a multiple‐step sequence based on peroxide‐mediated cage‐opening reactions. Key steps include repeated…”
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Synthesis of C70‐Based Fluorophores through Sequential Functionalization to Form Isomerically Pure Multiadducts
Published in Angewandte Chemie International Edition (20-02-2017)“…Selective addition to the C70 cage divides its π‐conjugated system into various smaller π‐conjugated systems with enhanced fluorescent properties. Key…”
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Concise Synthesis of Open‐Cage Fullerenes for Oxygen Delivery
Published in Angewandte Chemie International Edition (02-12-2019)“…Open‐cage fullerenes with a 19‐membered orifice were prepared in three steps from C60. The key step for cage‐opening is aniline mediated ring expansion of a…”
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Facile Synthesis of Isomerically Pure Fullerenols and Formation of Spherical Aggregates from C60(OH)8
Published in Angewandte Chemie International Edition (19-07-2010)“…Octahydroxy fullerene C60(OH)8 (see picture) is among the isomerically pure fullerenols with two to eight OH groups that were prepared by selective…”
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Selective Addition of Palladium on the Rim of Open-Cage Fullerenes To Form Mononuclear and Dinuclear Complexes
Published in Organometallics (26-08-2019)“…Open-cage fullerenes having an 11-membered orifice and keto lactone groups on the rim of the orifice reacted with both Pd(PPh3)4 and Pd(OAc)2/PPh3 to form a…”
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Switchable Open-Cage Fullerene for Water Encapsulation
Published in Angewandte Chemie International Edition (17-12-2010)“…A molecular container for a single water molecule was obtained by chemical transformation of a [60]fullerene cage. A phosphate moiety acts as an effective…”
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Fabrication of Low-Dimension Nanostructures Based on Organic Conjugated Molecules
Published in Advanced materials (Weinheim) (04-08-2008)“…The aim of this review is to explore the fundamental and technological incentive for the molecular design, synthesis, and aggregation behavior of conjugated…”
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Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3 and C60O4
Published in Angewandte Chemie International Edition (18-06-2012)“…Breaking the surface: Replacement of a fullerene cage carbon with a nitrogen or oxygen atom is achieved by reactions mediated with fullerene peroxide. Similar…”
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Cap Formation Engineering: From Opened C60 to Single-Walled Carbon Nanotubes
Published in Nano letters (08-09-2010)“…Structural control, and especially chirality control, remains a significant challenge in the synthesis of single-walled carbon nanotubes (SWNTs). We report…”
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Selective Addition of Secondary Amines to C60: Formation of Penta- and Hexaamino[60]fullerenes
Published in Journal of organic chemistry (19-09-2014)“…Secondary amines are well-known to add to [60]fullerene to form the tetraamino epoxy adduct C60(O)(NR1R2)4 under both photolysis and thermal conditions in the…”
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Controlled Synthesis of Nitrogen-Doped Graphene on Ruthenium from Azafullerene
Published in Nano letters (10-05-2017)“…The controlled synthesis of high-quality nitrogen (N) doped single layer graphene on the Ru(0001) surface has been achieved using the N-containing sole…”
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Synthesis of Decahydropyrrolo[2,1,5-cd]indolizine through Consecutive [2 + 3] Cycloadditions and 6-Exo-Trig Cyclization
Published in Journal of organic chemistry (20-05-2011)“…Azomethine ylide formed from glycine methyl ester and cinnamaldehyde adds to N-phenylmaleimide to form pyrrolidine derivative, further treatment of which with…”
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Release of the Water Molecule Encapsulated Inside an Open-Cage Fullerene through Hydrogen Bonding Mediated by Hydrogen Fluoride
Published in Chemistry : a European journal (21-09-2015)“…A reversible wetting/dewetting procedure is reported for an open‐cage fullerene with an 18‐membered orifice. In a homogeneous mixture of H2O/EtOH/CHCl3, water…”
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Hydrolysis‐Initiated Domino Process on the Rim of Open‐Cage C60 Derivatives Including Decarbonylation and Double Dehydration
Published in ChemPlusChem (Weinheim, Germany) (01-07-2017)“…Hydrolysis of an open‐cage C60 derivative in a mixture of HCl/AcOH/H2O resulted in removal of two hydroxyl groups, one carbonyl group and one aniline group in…”
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Molecular Containers Derived from [60]Fullerene through Peroxide Chemistry
Published in Accounts of chemical research (16-07-2019)“…Conspectus Molecular containers can keep guest molecules in a confined space that is completely separated from the solution. They have wide potential…”
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Synthesis of an Azahomoazafullerene C59N(NH)R and Gas-Phase Formation of the Diazafullerene C58N2
Published in Angewandte Chemie International Edition (03-05-2013)“…Open the cage if you dare: The azahomoazafullerene 1 was prepared from a tert‐butylperoxy‐substituted azafullerene derivative C59NBr(OOtBu)4. Singlet oxygen…”
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Synthesis of Open-Cage Fullerenes with a Long Tail
Published in Organic Materials (01-10-2020)“…To explore potential applications for open-cage fullerenes, we employed 4-((6-bromohexyl)oxy)aniline to react with an open-cage fullerene precursor which has…”
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