Crystal structure and magnetic interactions of a new alkoxido and azido bridged 1D copper(II) coordination polymer

A new 1D azido and alkoxido-bridged Cu(II) coordination polymer, [Cu2(H3L)(μ-H2L)(μ-N3)]n (1), was synthesized from the reaction of H4L, Cu(NO3)2·3H2O and NaN3 in methanol, where H4L is (E)-2-((5-bromo-2-hydroxybenzylidene)amino)-2-(hydroxymethyl)propane-1,3-diol. Compound 1 was characterized by ele...

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Bibliographic Details
Published in:	Journal of solid state chemistry Vol. 303; p. 122484
Main Authors:	Bikas, Rahman, Korabik, Maria, Sanchiz, Joaquín, Noshiranzadeh, Nader, Mirzakhani, Prinaz, Gałkowska, Amanda, Szeliga, Daria, Kozakiewicz-Piekarz, Anna
Format:	Journal Article
Language:	English
Published:	Elsevier Inc 01-11-2021
Subjects:	Coordination polymer Copper Crystal structure DFT calculation Magnetic interaction Magnetic interaction DFT calculation Copper Coordination polymer Crystal structure
Online Access:	Get full text
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Summary:	A new 1D azido and alkoxido-bridged Cu(II) coordination polymer, [Cu2(H3L)(μ-H2L)(μ-N3)]n (1), was synthesized from the reaction of H4L, Cu(NO3)2·3H2O and NaN3 in methanol, where H4L is (E)-2-((5-bromo-2-hydroxybenzylidene)amino)-2-(hydroxymethyl)propane-1,3-diol. Compound 1 was characterized by elemental analysis, spectroscopic methods and single-crystal X-ray diffraction. Both spectroscopic and structural studies confirmed the presence of the Schiff base and the azide ligands. Azido and alkoxido bridges connect two Cu(II) ions with different coordination environments. The Schiff base ligand, H4L, shows two coordination modes acting as H3L− and H2L2− to the metal cores. The azido ligands show both end-on and end-to-end bridging modes. The magnetic study performed in the 1.8–300 K range shows an overall ferromagnetic interaction among the copper(II) ions dominated by the coupling through the alkoxido bridge. We have calculated the value of the magnetic coupling constants by means of DFT calculations, and we compared their values with those obtained from the magnetic susceptibility measurements. Synthesis, crystal structure and magnetic interactions of a 1D Cu(II) coordination polymer was experimentally and theoretically investigated. [Display omitted] •Synthesis and crystal structure of a new alkoxido and azido bridged Cu(II) coordination polymer are reported.•Spectroscopic properties of a new 1D coordination polymer are investigated.•Magnetic interactions of a 1D Cu(II) coordination polymer was experimentally and theoretically investigated.
ISSN:	0022-4596 1095-726X
DOI:	10.1016/j.jssc.2021.122484