Search Results - "GUERRET, O"
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Amphiphilic gradient poly(styrene- co-acrylic acid) copolymer prepared via nitroxide-mediated solution polymerization. Synthesis, characterization in aqueous solution and evaluation as emulsion polymerization stabilizer
Published in Polymer (Guilford) (08-03-2006)“…A well-defined, amphiphilic poly(styrene- co-acrylic acid) copolymer was synthesized in a single step by nitroxide-mediated controlled free-radical…”
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Acrylamide-Based Amphiphilic Block Copolymers via Nitroxide-Mediated Radical Polymerization
Published in Macromolecules (12-08-2003)“…Nitroxide-mediated polymerization is shown to produce well-defined poly(N,N-dimethylacrylamide) samples. In the presence of SG1, a β-phosphonylated nitroxide,…”
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Effect of sodium polyacrylate molecular weight on the crystallogenesis of calcium carbonate
Published in Journal of crystal growth (15-08-2007)“…Aqueous solutions of sodium polyacrylates (NaPA) series having molecular weights ( M w) ranging from 2540 to 9890 g mol −1 are used as precipitation media to…”
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1,2,4-Triazole-3,5-diylidene: A Building Block for Organometallic Polymer Synthesis
Published in Journal of the American Chemical Society (16-07-1997)Get full text
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Use of a nanoindentation fatigue test to characterize the ductile–brittle transition
Published in Journal of the European Ceramic Society (01-04-2009)“…When considering grinding of minerals, scaling effect induces competition between plastic deformation and fracture in brittle solids. The competition can be…”
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Apparent 1,2-Silyl Migrations in Aromatic Carbenes Occur by Intermolecular Silyl Exchanges
Published in Journal of the American Chemical Society (09-09-1998)Get full text
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Amphiphilic diblock copolymers with adhesive properties: I. Structure and swelling with water
Published in The European physical journal. E, Soft matter and biological physics (01-07-2006)“…We study asymmetric block copolymers with the simple diblock AB architecture, in the case where the longer block A is both hydrophobic and "soft", whereas the…”
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Theoretical Expression of the Average Activation−Deactivation Equilibrium Constant in Controlled/Living Free-Radical Copolymerization Operating via Reversible Termination. Application to a Strongly Improved Control in Nitroxide-Mediated Polymerization of Methyl Methacrylate
Published in Macromolecules (28-06-2005)“…The average activation−deactivation equilibrium constant, 〈K〉, was determined on a theoretical basis for controlled free-radical copolymerizations operating…”
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Free and Supported Phosphorus Ylides as Strong Neutral Brønsted Bases
Published in Journal of organic chemistry (14-05-1999)Get full text
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Nitroxide-Mediated Controlled Free-Radical Emulsion Polymerization of Styrene and n-Butyl Acrylate with a Water-Soluble Alkoxyamine as Initiator
Published in Angewandte Chemie International Edition (19-11-2004)“…Latex: Nitroxide‐mediated emulsion polymerizations of n‐butyl acrylate and styrene were successfully carried out in a multistep process, with a novel…”
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First Nitroxide-Mediated Controlled Free-Radical Polymerization of Acrylic Acid
Published in Macromolecules (04-11-2003)“…Controlled poly(acrylic acid) homopolymers were synthesized for the first time by direct nitroxide-mediated polymerization of acrylic acid. The polymerizations…”
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Nitroxide-Mediated Controlled Free-Radical Emulsion Polymerization Using a Difunctional Water-Soluble Alkoxyamine Initiator. Toward the Control of Particle Size, Particle Size Distribution, and the Synthesis of Triblock Copolymers
Published in Macromolecules (29-11-2005)“…A novel dialkoxyamine bearing two carboxylic acid groups was synthesized by the addition of a high dissociation rate constant alkoxyamine onto tri(ethylene…”
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Direct Synthesis of Controlled Poly(styrene-co-acrylic acid)s of Various Compositions by Nitroxide-Mediated Random Copolymerization
Published in Macromolecular chemistry and physics (01-11-2003)“…Styrene and acrylic acid were copolymerized under controlled conditions, in 1,4‐dioxane solution at 120 °C and 2 bar, using an alkoxyamine initiator based on…”
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Novel SG1-Based Water-Soluble Alkoxyamine for Nitroxide-Mediated Controlled Free-Radical Polymerization of Styrene and n-Butyl Acrylate in Miniemulsion
Published in Macromolecules (15-06-2004)“…Nitroxide-mediated controlled free-radical polymerizations of n-butyl acrylate and styrene were performed in miniemulsion using, for the first time, a…”
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Online Monitoring of Controlled Radical Polymerization: Nitroxide-Mediated Gradient Copolymerization
Published in Macromolecules (10-02-2004)“…A comprehensive characterization of the controlled radical copolymerization of styrene and n-butyl acrylate comonomers is obtained by using a recently…”
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End-Group Characterization of Poly(acrylic acid) Prepared by Nitroxide-Mediated Controlled Free-Radical Polymerization
Published in Macromolecular rapid communications. (01-07-2004)“…A low‐molar‐mass poly(acrylic acid) with a narrow molar‐mass distribution, prepared by SG1 nitroxide‐mediated controlled free‐radical polymerization, was…”
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Alkoxyamine-Mediated Radical Synthesis of Indolinones and Indolines
Published in Organic letters (25-12-2003)“…Thermolysis of α-alkoxyamino propionanilides produces indolinones, whereas thermal reaction of N-allylaniline derivatives with various Tordo-type alkoxyamines…”
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Synthesis and structure of 1,2,4-triazol-2-ium-5-ylidene complexes of Hg(II), Pd(II), Ni(II), Ni(0), Rh(I) and Ir(I)
Published in Journal of organometallic chemistry (16-12-2002)“…The reaction of M(OAc) 2 [M=Hg(II), Pd(II), Ni(II)] or M(acac)(CO) 2 [M=Rh(I), Ir(I)] with dicationic 1,2,4-triazolium salts 2 affords a series of…”
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Synthesis and Characterization of Poly(styrene-b-n-butyl acrylate-b-styrene) Triblock Copolymers Using a Dialkoxyamine as Initiator
Published in Macromolecules (07-05-2002)“…This study investigates the ability of a novel difunctional alkoxyamine based on N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (SG1) to serve as…”
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