Search Results - "GRUSHIN, V. V"

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination by Grushin, Vladimir V

“…Although springing from two established fields, organometallic chemistry and fluorine chemistry, organometallic fluorine chemistry is still in its early…”
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Fluoroform-Derived CuCF3 for Low-Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air by Novák, Petr, Lishchynskyi, Anton, Grushin, Vladimir V.

“…Easy does it: Aryl boronic acids undergo smooth and selective trifluoromethylation with low‐cost fluoroform‐derived CuCF3 in DMF in non‐dried air. The reaction…”
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Cupration of C2F5H: Isolation, Structure, and Synthetic Applications of [K(DMF)2][(t‑BuO)Cu(C2F5)]. Highly Efficient Pentafluoroethylation of Unactivated Aryl Bromides by Lishchynskyi, Anton, Grushin, Vladimir V

“…Pentafluoroethane, C2F5H (HFC-125), is smoothly cuprated with preisolated or in situ-generated [K(DMF)][(t-BuO)2Cu] to give [K(DMF)2][(t-BuO)Cu(C2F5)] (1) in…”
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Mixed Phosphine−Phosphine Oxide Ligands by Grushin, Vladimir V

“…Bis-phosphine monoxides constitute an important class of hemilabile ligands. Grushin provides a detailed overview of mixed phosphine-phosphine oxide compounds,…”
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Facile Ar−CF3 Bond Formation at Pd. Strikingly Different Outcomes of Reductive Elimination from [(Ph3P)2Pd(CF3)Ph] and [(Xantphos)Pd(CF3)Ph] by Grushin, Vladimir V, Marshall, William J

“…Facile and highly selective perfluoroalkyl−aryl reductive elimination from a metal center (Pd) has been demonstrated for the first time. At temperatures as low…”
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Simple, Stable, and Easily Accessible Well-Defined CuCF3 Aromatic Trifluoromethylating Agents by Tomashenko, Olesya A., Escudero-Adán, Eduardo C., Martínez Belmonte, Marta, Grushin, Vladimir V.

“…Give me an F: Exceptionally easy to make in over 90 % yield (see scheme) and air‐stable in the solid state, [(Ph3P)3Cu(CF3)] is a remarkable example of a…”
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Easy Access to the Copper(III) Anion [Cu(CF3)4] by Romine, Andrew M., Nebra, Noel, Konovalov, Andrey I., Martin, Eddy, Benet-Buchholz, Jordi, Grushin, Vladimir V.

“…CuCl or pre‐generated CuCF3 reacts with CF3SiMe3/KF in DMF in air to give [Cu(CF3)4]− quantitatively. [PPN]+, [Me4N]+, [Bu4N]+, [PhCH2NEt3]+, and [Ph4P]+ salts…”
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Application of the Generalized Stationary Phase Method to the Asymptotics of the Tsunami Head Wave in the Hydrodynamic Piston Model by Grushin, V. V.

“…Formulas for the asymptotics of some class of integrals of rapidly oscillating functions that generalize the well-known stationary phase method, which were…”
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Highly efficient electroluminescent materials based on fluorinated organometallic iridium compounds by Wang, Y., Herron, N., Grushin, V. V., LeCloux, D., Petrov, V.

“…We report a class of highly efficient electroluminescent materials based on fluorinated iridium compounds. Using aluminum as the cathode, a device, using…”
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The Challenge of Palladium-Catalyzed Aromatic Azidocarbonylation: From Mechanistic and Catalyst Deactivation Studies to a Highly Efficient Process by Miloserdov, Fedor M, McMullin, Claire L, Belmonte, Marta Martı́nez, Benet-Buchholz, Jordi, Bakhmutov, Vladimir I, Macgregor, Stuart A, Grushin, Vladimir V

“…Azidocarbonylation of iodoarenes with CO and NaN3, a novel Heck-type carbonylation reaction, readily occurs in an organic solvent–H2O biphasic system to…”
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Palladium Fluoride Complexes: One More Step toward Metal-Mediated C−F Bond Formation by Grushin, Vladimir V.

“…The first molecular complexes of palladium containing a Pd−F bond, both fluorides and bifluorides, were synthesized and fully characterized in the solid state…”
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Ruthenium-catalyzed nucleophilic fluorination of halobenzenes by Konovalov, Andrey I, Gorbacheva, Evgeniya O, Miloserdov, Fedor M, Grushin, Vladimir V

“…The first π-coordination-catalyzed nucleophilic fluorination of unactivated aryl halides has been demonstrated. Chlorobenzene reacts with alkali metal…”
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Generalized method of stationary phase for the Fourier transform of a rapidly oscillating function by Grushin, V. V.

“…Asymptotic formulas are obtained for a class of integrals that are Fourier transforms of rapidly oscillating functions. These formulas contain special…”
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Unexpected H2O-Induced Ar−X Activation with Trifluoromethylpalladium(II) Aryls by Grushin, Vladimir V, Marshall, William J

“…A series of new complexes [(L−L)Pd(Ar)(CF3)] (L−L = dppe, dppp, tmeda; Ar = Ph, p-Tol, C6D5) have been synthesized and fully characterized in solution and in…”
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Well-Defined CuC2F5 Complexes and Pentafluoroethylation of Acid Chlorides by Panferova, Liubov I., Miloserdov, Fedor M., Lishchynskyi, Anton, Martínez Belmonte, Marta, Benet-Buchholz, Jordi, Grushin, Vladimir V.

“…Four new well‐defined CuI complexes bearing a C2F5 ligand have been prepared and fully characterized: [(Ph3P)2CuC2F5] (2), [(bpy)CuC2F5] (3),…”
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Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II) by Grushin, Vladimir V, Marshall, William J

“…Attempted preparation of N,N- and S,S-chelate-stabilized arylpalladium fluorides has led to the finding of aryne-mediated fluorination of nonactivated…”
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Asymptotics of the Propagation Problem for Linear Waves on a Two-Dimensional Lattice and Modified Maslov’s Canonical Operator by Grushin, V. V., Sergeev, S. A.

“…In the paper, the problem of propagation of waves generated by localized source on a two-dimensional lattice is studied. The discrete problem is reduced to a…”
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Continuous Process for Production of CuCF3 via Direct Cupration of Fluoroform by Mazloomi, Zahra, Bansode, Atul, Benavente, Pedro, Lishchynskyi, Anton, Urakawa, Atsushi, Grushin, Vladimir V

“…The first continuous flow process has been developed for the synthesis of a superior trifluoromethylating reagent, “ligandless” CuCF3, from fluoroform, by far…”
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The Trifluoromethyl Anion by Lishchynskyi, Anton, Miloserdov, Fedor M., Martin, Eddy, Benet-Buchholz, Jordi, Escudero-Adán, Eduardo C., Konovalov, Andrey I., Grushin, Vladimir V.

“…First evidence for the existence of free trifluoromethyl anion CF3− has been obtained. The 3D‐caged potassium cation in [K(crypt‐222)]+ is inaccessible to…”
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Synthesis of 2,5-Diformylfuran and Furan-2,5-Dicarboxylic Acid by Catalytic Air-Oxidation of 5-Hydroxymethylfurfural. Unexpectedly Selective Aerobic Oxidation of Benzyl Alcohol to Benzaldehyde with Metal=Bromide Catalysts by Partenheimer, Walt, Grushin, Vladimir V.

“…The alcohol group of hydroxymethylfurfural (compound 1, HMF) is preferentially oxidized by dioxygen and metal/bromide catalysts [Co/Mn/Br, Co/Mn/Zr/Br;…”
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