Search Results - "GIDLEY, D. W"
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Effect of Dimethyl Terephthalate and Dimethyl Isophthalate on the Free Volume and Barrier Properties of Poly(ethylene terephthalate) (PET): Amorphous PET
Published in Macromolecules (23-01-2018)“…The effect of blending two low molecular weight diluents (LMWD), dimethyl terephthalate (DMT) and dimethyl isophthalate (DMI), on the microstructure, free…”
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Positronium emission spectra from self-assembled metal-organic frameworks
Published in Physical review. B, Condensed matter and materials physics (18-06-2014)“…Results of positronium (Ps) emission into vacuum from self-assembled metal-organic frameworks (MOFs) are presented and discussed in detail. Four different MOF…”
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Determination of Pore Size in Mesoporous Thin Films from the Annihilation Lifetime of Positronium
Published in The journal of physical chemistry. B (24-05-2001)“…An existing model that relates the annihilation lifetime of positronium trapped in subnanometer pores to the average size of the pores is extended to account…”
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Resolution of the orthopositronium-lifetime puzzle
Published in Physical review letters (23-05-2003)“…The long-standing discrepancy [G. S. Adkins, R. N. Fell, and J. Sapirstein, Ann. Phys. (N.Y.) 295, 136 (2002)]] between the theoretical calculations of the…”
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Interface and Surface Effects on the Glass Transition in Thin Polystyrene Films
Published in Physical review letters (24-02-1997)Get full text
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Determination of pore-size distribution in low-dielectric thin films
Published in Applied physics letters (06-03-2000)“…Positronium annihilation lifetime spectroscopy is used to determine the pore-size distribution in low-dielectric thin films of mesoporous methylsilsesquioxane…”
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Measurement of Hole Volume in Amorphous Polymers Using Positron Spectroscopy
Published in Macromolecules (16-12-1996)“…Positron annihilation lifetime spectroscopy (PALS) measurements, in the temperature range 110−480 K, are given for three linear, amorphous polymers. Based on…”
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Positronium formation as a probe of polymer surfaces and thin films
Published in Physical review letters (12-06-1995)Get full text
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Properties of nanoporous organosilicate hybrid thin films with a bimodal pore size distribution
Published in Polymer international (01-05-2005)“…Low dielectric poly[methylsilsesquioxane‐ran‐trifluoropropylsilsesquioxane‐ran‐(2,4,6,8‐tetramethyl‐2,4,6,8‐tetraethylenecyclotetrasiloxane)silsesquioxane]s…”
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New precision measurement of the decay rate of singlet positronium
Published in Physical review letters (14-03-1994)“…The singlet decay rate has been measured using magnetic singlet-triplet state mixing for positronium formed in a [ital N][sub 2]-isobutane gas mixture. We find…”
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The Direct Patterning of Nanoporous Interlayer Dielectric Insulator Films by Nanoimprint Lithography
Published in Advanced materials (Weinheim) (05-10-2007)“…Nanoscale parallel line‐space patterns are imprinted into a spin‐on organosilicate thin film that contains a second phase pore generating material (porogen)…”
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Precision measurement of the orthopositronium decay rate using the vacuum technique
Published in Physical review letters (10-09-1990)“…A focused beam of 700-eV positrons is used to form orthopositronium ({ital o}-Ps) in evacuated, MgO-lined cavities of different sizes. The {ital o}-Ps decay…”
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Direct search for two-photon decay modes of orthopositronium
Published in Physical review letters (11-03-1991)“…A direct search for {gamma} rays from the forbidden decay {ital o}-Ps{r arrow}2{gamma} has been performed using the same apparatus that recently measured an…”
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New precision measurement of the orthopositronium decay rate: a discrepancy with theory
Published in Physical review letters (30-03-1987)“…The vacuum decay rate gamma(T) of orthopositronium (o-Ps), formed in a gas, has been measured to be 7.0516 + or - 0.0013/microsec. This result, which is four…”
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Influence of cyclic fatigue on the mechanical properties of amorphous polycarbonate
Published in Polymer (Guilford) (1995)“…Changes in the mechanical properties of amorphous polycarbonate during the fatigue failure initiation stage lead to overall embrittlement of the polymer. The…”
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Contributions of the nanovoid structure to the kinetics of moisture transport in epoxy resins
Published in Journal of polymer science. Part B, Polymer physics (01-03-2000)“…Absorbed moisture can degrade the physical properties of an epoxy resin, jeopardizing the performance of an epoxy‐based component. Although specific…”
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Contributions of the nanovoid structure to the moisture absorption properties of epoxy resins
Published in Journal of polymer science. Part B, Polymer physics (01-12-1998)“…Epoxy resins absorb significant quantities of moisture, typically 1 to 7% by weight for various formulations, which can greatly compromise their physical…”
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Morphological Control of Nanoporous Films by the Use of Functionalized Cyclodextrins as Porogens
Published in Advanced functional materials (01-03-2004)“…Porous cyclic silsesquioxane (CSSQ) thin films containing nanopores (∼ 2 nm) with low dielectric constant (k < 2.2), have been prepared by using various…”
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Glancing-angle scattering and neutralization of a positron beam at metal surfaces
Published in Physical review letters (09-02-1987)“…An energetic (10-100 eV) beam of Ps was formed by scattering a well-collimated, small-diameter beam of 30-400-eV positrons off surfaces of Al(110) and clean…”
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