Search Results - "GAVNEY, J. A"

Synthesis, chromatographic separation, and stereophysical analysis of the homologous [Ni12-x(PMe)x(CO)24-3x]2- series (x = 2, 3, 4) containing noncentered Ni12-xPx icosahedral cages and the [Ni10(.mu.5-PMe)2(.mu.4-PMe)5(CO)10]2- dianion containing a structurally unprecedented heptacapped pentagonal prismatic metal cage: structural, spectroscopic, and electrochemical consequences due to replacement of Ni(CO)3 fragments with electronically equivalent (isolobal) PMe fragments by Rieck, David F., Gavney, James A., Norman, Richard L., Hayashi, Randy K., Dahl, Lawrence F.

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Mechanism of rearrangement of an allylvinylrhenium complex to an (allyl vinyl ketone)rhenium complex: role of concerted organometallic reactions in avoiding high-energy coordinatively unsaturated intermediates by Casey, Charles P, Vosejpka, Paul C, Underiner, Todd L, Slough, Greg A, Gavney, James A

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Rearrangement of a propargyl vinyl rhenium complex to a rhenium allenyl vinyl ketone complex by Casey, Charles P, Underiner, Todd L, Vosejpka, Paul C, Gavney, James A, Kiprof, Paul

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Diphosphines with natural bite angles near 120° increase selectivity for n-aldehyde formation in rhodium-catalyzed hydroformylation by CASEY, C. P, WHITEKER, G. T, MELVILLE, M. G, PETROVICH, L. M, GAVNEY, J. A, POWELL, D. R

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Rearrangement of an allyl vinyl rhenium complex to a rhenium allyl vinyl ketoine complex via two consecutive concerted organometallic rearrangements by CASEY, C. P, VOSEJPKA, P. C, GAVNEY, J. A

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Rearrangement of Rhenium Allyl Vinyl Ketone Complexes by Casey, Charles P, Underiner, Todd L, Vosejpka, Paul C, Slough, Greg A, Gavney, James A, Hayashi, Randy K

“…The isomerization of parallel−perpendicular allyl vinyl ketone complex C5H5(CO)Re(η2,η2-H2CCHCH2COCHCHCH2CMe3) (2) to the diastereomeric…”
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