Search Results - "Fullmer, Benjamin C"

Influence of the d-Electron Count on CO Binding by Three-Coordinate [(tBu2PCH2SiMe2)2N]Fe, -Co, and -Ni by Ingleson, Michael J, Fullmer, Benjamin C, Buschhorn, Drew T, Fan, Hongjun, Pink, Maren, Huffman, John C, Caulton, Kenneth G

“…Reduction of (PNP)MCl [PNP = (tBu2PCH2SiMe2)2N] with Mg gives three-coordinate, T-shaped (PNP)M for M = Fe(S = 3/2) and Ni. Their reactivity was tested toward…”
Get full text

[Ni{N(SiMe₂CH₂PtBu₂)₂}]⁺: Direct Observation of Transannular Si----C(sp³) Bond Coordination by Fan, Hongjun, Fullmer, Benjamin C, Pink, Maren, Caulton, Kenneth G

“…How low can you go? The title [(PNP)Ni]+ complex is not a T‐shaped d8 cation. Rather, it has an electrophilic NiII center bound to one of the SiC bonds,…”
Get full text

Influence of the Metal Orbital Occupancy and Principal Quantum Number on Organoazide (RN3) Conversion to Transition-Metal Imide Complexes by Walstrom, Amy N, Fullmer, Benjamin C, Fan, Hongjun, Pink, Maren, Buschhorn, Drew T, Caulton, Kenneth G

“…The reaction of phenyl azide with (PNP)Ni, where PNP = (tBu2PCH2SiMe2)2N−, promptly evolves N2 and forms a PN bond in the product (PNPNPh)NiI. A similar…”
Get full text

The Effect of One Valence Electron: Contrasting (PNP)Ni(CO) with (PNP)Ni(NO) to Understand the Half-Bent NiNO Unit by Fullmer, Benjamin C, Pink, Maren, Fan, Hongjun, Yang, Xiaofan, Baik, Mu-Hyun, Caulton, Kenneth G

“…Reaction of a (PNP)Ni radical with NO finishes in the time of mixing to form a 1:1 adduct with a NO stretching frequency of 1654 cm−1. NMR data of this…”
Get full text

Three-Coordinate NiII: Tracing the Origin of an Unusual, Facile Si−C(sp3) Bond Cleavage in [( t Bu2PCH2SiMe2)2N]Ni by Fullmer, Benjamin C, Fan, Hongjun, Pink, Maren, Huffman, John C, Tsvetkov, Nikolay P, Caulton, Kenneth G

“…All attempts to synthesize (PNP)Ni(OTf) form instead ( t Bu2PCH2SiMe2NSiMe2OTf)Ni(CH2P t Bu2). Abstraction of F− from (PNP)NiF by even a catalytic amount of…”
Get full text

O/C Bond Cleavage of CO2 by NiI by Fullmer, Benjamin C, Fan, Hongjun, Pink, Maren, Caulton, Kenneth G

“…Reaction of (PNP)Ni, where PNP is [(tBu2PCH2SiMe2)2N]−1, with CO2 occurs rapidly even at −60 °C to form exclusively the product of transposition of the amide N…”
Get full text

Three-Coordinate Ni II : Tracing the Origin of an Unusual, Facile Si−C(sp 3 ) Bond Cleavage in [( t Bu 2 PCH 2 SiMe 2 ) 2 N]Ni by Fullmer, Benjamin C., Fan, Hongjun, Pink, Maren, Huffman, John C., Tsvetkov, Nikolay P., Caulton, Kenneth G.

Get full text

Evaluating the reducing power of 3-coordinate T-shaped Ni I by Fullmer, Benjamin C., Fan, Hongjun, Pink, Maren, Caulton, Kenneth G.

“…Oxidation of a monovalent nickel pincer complex shows arm displacement, and limitations of reaching Ni(III). [Display omitted] ► Coordination of N 2 initiates…”
Get full text

Evaluating the reducing power of 3-coordinate T-shaped NiI by Fullmer, Benjamin C., Fan, Hongjun, Pink, Maren, Caulton, Kenneth G.

Get full text

Mechanism of Heterolysis of H 2 by an Unsaturated d 8 Nickel Center: via Tetravalent Nickel? by He, Tao, Tsvetkov, Nikolay P., Andino, José G., Gao, Xinfeng, Fullmer, Benjamin C., Caulton, Kenneth G.

Get full text

O/C Bond Cleavage of CO 2 by Ni I by Fullmer, Benjamin C., Fan, Hongjun, Pink, Maren, Caulton, Kenneth G.

Get full text

Reactivity of the Radical NO with a Masked Form of 14 Valence Electron (PNP)Rh: Forming Rh(0, I or II)? by Verat, Alexander Y., Pink, Maren, Fan, Hongjun, Fullmer, Benjamin C., Telser, Joshua, Caulton, Kenneth G.

“…The reaction of NO with [(tBu2PCH2SiMe2)NSiMe2CH2PtBu(CMe2CH2)]RhH, a functional equivalent of “(PNP)Rh,” rapidly forms (PNP)Rh(N2) and (PNP)Rh(NO)(NO2)…”
Get full text

Mechanism of Heterolysis of H2 by an Unsaturated d8 Nickel Center: via Tetravalent Nickel? by He, Tao, Tsvetkov, Nikolay P, Andino, José G, Gao, Xinfeng, Fullmer, Benjamin C, Caulton, Kenneth G

“…Collision of H2 with the unusual nickel complex, (PNP)Ni+, where PNP = ( t Bu2PCH2SiMe2)2N, forms a rare dihydrogen complex of the d8 configuration which then…”
Get full text

[Ni{N(SiMe2CH2PtBu2)2}]+: Direct Observation of Transannular SiC(sp3) Bond Coordination by Fan, Hongjun, Fullmer, Benjamin C., Pink, Maren, Caulton, Kenneth G.

“…Wo sind die Grenzen? Der Titelkomplex [(PNP)Ni]+ ist kein T‐förmiges d8‐Kation, sondern in ihm ist ein elektrophiles NiII‐Zentrum an eine der Si‐C‐Bindungen…”
Get full text

[Ni{N(SiMe 2 CH 2 P t Bu 2 ) 2 }] + : Direct Observation of Transannular SiC(sp 3 ) Bond Coordination by Fan, Hongjun, Fullmer, Benjamin C., Pink, Maren, Caulton, Kenneth G.

Get full text