Controlling the Orientation of Metal–Organic Framework Crystals by an Interfacial Growth Approach Using a Metal Ion-Doped Polymer Substrate

Controlling the Orientation of Metal–Organic Framework Crystals by an Interfacial Growth Approach Using a Metal Ion-Doped Polymer Substrate

Highly oriented three-dimensional metal–organic framework (MOF) crystals with a pillared-layer structure were prepared on a metal ion-doped polymer substrate. This approach allowed the formation of MOF crystals with controlled crystalline orientation in a one-pot reaction facilitated by the control...

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Bibliographic Details
Published in:Crystal growth & design Vol. 18; no. 1; pp. 402 - 408
Main Authors: Ohhashi, Takashi, Tsuruoka, Takaaki, Fujimoto, Seiya, Takashima, Yohei, Akamatsu, Kensuke
Format: Journal Article
Language:English
Published: American Chemical Society 03-01-2018
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Summary:Highly oriented three-dimensional metal–organic framework (MOF) crystals with a pillared-layer structure were prepared on a metal ion-doped polymer substrate. This approach allowed the formation of MOF crystals with controlled crystalline orientation in a one-pot reaction facilitated by the control of the chemical interaction between the framework components and polymer substrate. Further, this approach provides a new concept for the one-pot synthesis of oriented MOF crystals and furthers the fundamental understanding of the crystal growth mechanism based on self-assembly processes on two-dimensional support substrates.
ISSN:1528-7483
1528-7505
DOI:10.1021/acs.cgd.7b01402