Search Results - "Fujimori, Shiori"

Small Molecule Activation by Two‐Coordinate Acyclic Silylenes by Fujimori, Shiori, Inoue, Shigeyoshi

“…In recent decades, the chemistry of stable silylenes (R2Si:) has evolved significantly. The first major development in this chemistry was the isolation of a…”
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Stannabenzenylpotassium: The First Isolable Tin‐Containing Benzene Derivative by Fujimori, Shiori, Mizuhata, Yoshiyuki, Tokitoh, Norihiro

“…In contrast to the well‐investigated sila‐ and germa‐aromatic compounds, very few aromatic compounds containing tin have been reported. Specifically, no stable…”
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A Mixed‐Anion System Consisting of a Germyl Anion and Anions Delocalized on Conjugated Carbon Ring Skeletons by Fujimori, Shiori, Mizuhata, Yoshiyuki, Tokitoh, Norihiro

“…A trianion consisting of one germyl anion and two anions delocalized on conjugated carbon ring skeletons was synthesized by trimerization of the germanium…”
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Main group carbonyl complexes by Fujimori, Shiori, Inoue, Shigeyoshi

“…The chemistry of carbon monoxide (CO) as a ligand has evolved significantly and transition-metal carbonyl complexes have been widely used as catalysts in many…”
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Recent progress in the chemistry of heavy aromatics by FUJIMORI, Shiori, MIZUHATA, Yoshiyuki, TOKITOH, Norihiro

“…The aromaticity and synthetic application of “heavy benzenes”, i.e., benzenes containing a heavier Group 14 element (Si, Ge, Sn, and Pb) in place of skeletal…”
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Neutral, Cationic and Hydride‐substituted Siloxygermylenes by Roy, Matthew M. D., Fujimori, Shiori, Ferguson, Michael J., McDonald, Robert, Tokitoh, Norihiro, Rivard, Eric

“…The introduction of the labile trimethylsiloxy group to GeII centers in the presence of an N‐heterocyclic carbene donor is reported. The new complex…”
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Heavy Phenyllithium and -sodium: Synthesis and Characterization of Germanium Analogues of Phenyl Anion (‘Germabenzenyl Anions’) by Fujimori, Shiori, Mizuhata, Yoshiyuki, Tokitoh, Norihiro

“…The heavier phenyl anion analogues, 2-tert-butylgermabenzenyllithium Li+·1− and sodium Na+·1−, were synthesized via aryl elimination from the corresponding…”
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Carbon Monoxide in Main-Group Chemistry by Fujimori, Shiori, Inoue, Shigeyoshi

“…The usage of carbon monoxide (CO) as a C1 feedstock for carbonylation has been an important subject of numerous studies for over a century. The chemistry in…”
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An Aluminum Telluride with a Terminal Al=Te Bond and its Conversion to an Aluminum Tellurocarbonate by CO2 Reduction by Xu, Huihui, Kostenko, Arseni, Weetman, Catherine, Fujimori, Shiori, Inoue, Shigeyoshi

“…Facile access to dimeric heavier aluminum chalcogenides [(NHC)Al(Tipp)‐μ‐Ch]2 (NHC=IiPr (1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene, IMe4…”
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Dearomatization of C6 Aromatic Hydrocarbons by Main Group Complexes by Zhu, Huaiyuan, Fujimori, Shiori, Kostenko, Arseni, Inoue, Shigeyoshi

“…The dearomatization reaction is a powerful method for transformation of simple aromatic compounds to unique chemical architectures rapidly in synthetic…”
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Germabenzenylpotassium: A Germanium Analogue of a Phenyl Anion by Mizuhata, Yoshiyuki, Fujimori, Shiori, Sasamori, Takahiro, Tokitoh, Norihiro

“…Reduction of the stable germabenzene, 1‐Tbt‐2‐tert‐butyl‐germabenzene (Tbt=2,4,6‐tris[bis(trimethylsilyl)methyl]phenyl), with KC8 resulted in the formation of…”
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Dearomatization of C 6 Aromatic Hydrocarbons by Main Group Complexes by Zhu, Huaiyuan, Fujimori, Shiori, Kostenko, Arseni, Inoue, Shigeyoshi

“…Abstract The dearomatization reaction is a powerful method for transformation of simple aromatic compounds to unique chemical architectures rapidly in…”
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Tetryliumylidene ions in synthesis and catalysis by Stigler, Sebastian, Fujimori, Shiori, Kostenko, Arseni, Inoue, Shigeyoshi

“…Tetryliumylidene ions ([R-E:] + ), recognised for their intriguing electronic properties, have attracted considerable interest. These positively charged…”
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An Aluminum Telluride with a Terminal Al=Te Bond and its Conversion to an Aluminum Tellurocarbonate by CO 2 Reduction by Xu, Huihui, Kostenko, Arseni, Weetman, Catherine, Fujimori, Shiori, Inoue, Shigeyoshi

“…Facile access to dimeric heavier aluminum chalcogenides [(NHC)Al(Tipp)-μ-Ch] (NHC=IiPr (1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, IMe…”
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Heavy Phenyllithium and -sodium: Synthesis and Characterization of Germanium Analogues of Phenyl Anion (‘Germabenzenyl Anions’) by Fujimori, Shiori, Mizuhata, Yoshiyuki, Tokitoh, Norihiro

“…The heavier phenyl anion analogues, 2-tert-butylgermabenzenyllithium Li+·1− and sodium Na+·1−, were synthesized via aryl elimination from the corresponding…”
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A Mixed‐Anion System Consisting of a Germyl Anion and Anions Delocalized on Conjugated Carbon Ring Skeletons by Fujimori, Shiori, Mizuhata, Yoshiyuki, Tokitoh, Norihiro

“…Invited for the cover of this issue is the group of Norihiro Tokitoh at Kyoto University. The image depicts a mixed‐trianion system based on a…”
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Front Cover: A Mixed‐Anion System Consisting of a Germyl Anion and Anions Delocalized on Conjugated Carbon Ring Skeletons (Chem. Eur. J. 25/2019) by Fujimori, Shiori, Mizuhata, Yoshiyuki, Tokitoh, Norihiro

“…A mixed trianion consisting of one germyl anion and two anions delocalized on conjugated carbon ring skeletons was synthesized by the trimerization of the…”
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Cover Feature: Stannabenzenylpotassium: The First Isolable Tin‐Containing Benzene Derivative (Chem. Eur. J. 64/2018) by Fujimori, Shiori, Mizuhata, Yoshiyuki, Tokitoh, Norihiro

“…Bifacial tin aromatics: The first stable tin‐containing benzene derivative, stannabenzenyl anion, was successfully isolated as a monomer both in solution and…”
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Reaction of germabenzenylpotassium with TBDMSCl: Unusual trimerization of germabenzene skeletons by Mizuhata, Yoshiyuki, Fujimori, Shiori, Tokitoh, Norihiro

“…The reaction of 2-t-Bu-germabenzenylpotassium with Me 2 (t-Bu)SiCl (TBDMSCl) resulted in the coupling among two TBDMS-substituted germabenzenes and the…”
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Small Molecule Activation by 4‐ N , N ‐Dimethylaminopyridine‐Stabilized Bis(silyl)germylenes by Weng, Tobias, Fujimori, Shiori, Stigler, Sebastian, Bock, Balasai M.‐T., Inoue, Shigeyoshi

“…Abstract The synthesis, characterization, and reactivity of DMAP⋅Ge(Si t Bu 3 )Si(TMS) 3 1 a and DMAP⋅Ge[Si(TMS) 3 ] 2 1 b are reported (DMAP = 4‐ N,N…”
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