Search Results - "Frogley, Mark. D."
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Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Published in Nature materials (01-08-2022)“…Natural gas, consisting mainly of methane (CH 4 ), has a relatively low energy density at ambient conditions (~36 kJ l −1 ). Partial oxidation of CH 4 to…”
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Integration of mesopores and crystal defects in metal-organic frameworks via templated electrosynthesis
Published in Nature communications (02-10-2019)“…Incorporation of mesopores and active sites into metal-organic framework (MOF) materials to uncover new efficient catalysts is a highly desirable but…”
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Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material
Published in Advanced materials (Weinheim) (01-10-2016)“…Selective adsorption of SO2 is realized in a porous metal–organic framework material, and in‐depth structural and spectroscopic investigations using X‐rays,…”
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Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework
Published in Angewandte Chemie International Edition (05-11-2018)“…MFM‐300(Al) shows reversible uptake of NH3 (15.7 mmol g−1 at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm−3 at 293 K. In…”
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Refinement of pore size at sub-angstrom precision in robust metal–organic frameworks for separation of xylenes
Published in Nature communications (27-08-2020)“…The demand for xylenes is projected to increase over the coming decades. The separation of xylene isomers, particularly p- and m -xylenes, is vital for the…”
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Synchrotron Photothermal Infrared Nanospectroscopy of Drug-Induced Phospholipidosis in Macrophages
Published in Analytical chemistry (Washington) (16-06-2020)“…Synchrotron resonance-enhanced infrared atomic force microscopy (RE-AFM-IR) is a near-field photothermal vibrational nanoprobe developed at Diamond Light…”
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Post-synthetic modulation of the charge distribution in a metal-organic framework for optimal binding of carbon dioxide and sulfur dioxide
Published in Chemical science (Cambridge) (2019)“…Modulation of pore environment is an effective strategy to optimize guest binding in porous materials. We report the post-synthetic modification of the charge…”
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Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework
Published in Nature communications (13-02-2017)“…Hydrogen bonds dominate many chemical and biological processes, and chemical modification enables control and modulation of host–guest systems. Here we report…”
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Probing Dielectric Properties of Metal–Organic Frameworks: MIL‑53(Al) as a Model System for Theoretical Predictions and Experimental Measurements via Synchrotron Far- and Mid-Infrared Spectroscopy
Published in The journal of physical chemistry letters (19-10-2017)“…Emerging nanoporous materials, such as metal–organic frameworks (MOFs), are promising low-k dielectrics central to next-generation electronics and high-speed…”
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Synchrotron nano-FTIR spectroscopy for probing anticancer drugs at subcellular scale
Published in Scientific reports (26-07-2024)“…The cellular response to cisplatin was assessed in human osteosarcoma cells, using synchrotron-based (SR) Fourier Transform InfraRed nanospectroscopy…”
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Author Correction: Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Published in Nature materials (01-08-2022)Get full text
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In situ Synchrotron IR Microspectroscopy of CO2 Adsorption on Single Crystals of the Functionalized MOF Sc2(BDC-NH2)3
Published in Angewandte Chemie International Edition (01-12-2014)“…Synchrotron radiation (SR) IR microspectroscopy has enabled determination of the thermodynamics, kinetics, and molecular orientation of CO2 adsorbed in single…”
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Efficient capture and storage of ammonia in robust aluminium-based metal-organic frameworks
Published in Communications chemistry (24-03-2023)“…The development of stable sorbent materials to deliver reversible adsorption of ammonia (NH 3 ) is a challenging task. Here, we report the efficient capture…”
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A Multimodal Study on the Unique Sensing Behavior of a Guest@Metal‐Organic Framework Material for the Detection of Volatile Acetone
Published in Advanced materials interfaces (01-01-2023)“…Owing to their unique functionalities and tailorable properties that are unattainable in conventional materials, metal‐organic frameworks (MOFs) have emerged…”
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Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites
Published in Nature materials (01-12-2019)“…Emissions of SO 2 from flue gas and marine transport have detrimental impacts on the environment and human health, but SO 2 is also an important industrial…”
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Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal–Organic Frameworks
Published in Journal of the American Chemical Society (14-10-2020)“…Efficient electro-reduction of CO2 over metal–organic framework (MOF) materials is hindered by the poor contact between thermally synthesized MOF particles and…”
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Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal–Organic Frameworks
Published in Journal of the American Chemical Society (15-11-2017)“…During nuclear waste disposal process, radioactive iodine as a fission product can be released. The widespread implementation of sustainable nuclear energy…”
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Macroscale Superlubricity and Polymorphism of Long-Chain n‑Alcohols
Published in ACS applied materials & interfaces (24-02-2021)“…Simple n-alcohols, such as 1-dodecanol, show anomalous film-forming and friction behaviors under elastohydrodynamic lubrication (EHL) conditions, as found…”
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High Ammonia Adsorption in MFM-300 Materials: Dynamics and Charge Transfer in Host–Guest Binding
Published in Journal of the American Chemical Society (03-03-2021)“…Ammonia (NH3) is a promising energy resource owing to its high hydrogen density. However, its widespread application is restricted by the lack of efficient and…”
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Direct Observation of Ammonia Storage in UiO-66 Incorporating Cu(II) Binding Sites
Published in Journal of the American Chemical Society (18-05-2022)“…The presence of active sites in metal–organic framework (MOF) materials can control and affect their performance significantly in adsorption and catalysis…”
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