Search Results - "Frogley, Mark"
-
1
Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Published in Nature materials (01-08-2022)“…Natural gas, consisting mainly of methane (CH 4 ), has a relatively low energy density at ambient conditions (~36 kJ l −1 ). Partial oxidation of CH 4 to…”
Get full text
Journal Article -
2
Integration of mesopores and crystal defects in metal-organic frameworks via templated electrosynthesis
Published in Nature communications (02-10-2019)“…Incorporation of mesopores and active sites into metal-organic framework (MOF) materials to uncover new efficient catalysts is a highly desirable but…”
Get full text
Journal Article -
3
Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material
Published in Advanced materials (Weinheim) (01-10-2016)“…Selective adsorption of SO2 is realized in a porous metal–organic framework material, and in‐depth structural and spectroscopic investigations using X‐rays,…”
Get full text
Journal Article -
4
Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework
Published in Angewandte Chemie International Edition (05-11-2018)“…MFM‐300(Al) shows reversible uptake of NH3 (15.7 mmol g−1 at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm−3 at 293 K. In…”
Get full text
Journal Article -
5
Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites
Published in Nature materials (01-12-2019)“…Emissions of SO 2 from flue gas and marine transport have detrimental impacts on the environment and human health, but SO 2 is also an important industrial…”
Get full text
Journal Article -
6
Quantitative Electro-Reduction of CO2 to Liquid Fuel over Electro-Synthesized Metal–Organic Frameworks
Published in Journal of the American Chemical Society (14-10-2020)“…Efficient electro-reduction of CO2 over metal–organic framework (MOF) materials is hindered by the poor contact between thermally synthesized MOF particles and…”
Get full text
Journal Article -
7
Refinement of pore size at sub-angstrom precision in robust metal–organic frameworks for separation of xylenes
Published in Nature communications (27-08-2020)“…The demand for xylenes is projected to increase over the coming decades. The separation of xylene isomers, particularly p- and m -xylenes, is vital for the…”
Get full text
Journal Article -
8
Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal–Organic Frameworks
Published in Journal of the American Chemical Society (15-11-2017)“…During nuclear waste disposal process, radioactive iodine as a fission product can be released. The widespread implementation of sustainable nuclear energy…”
Get full text
Journal Article -
9
Macroscale Superlubricity and Polymorphism of Long-Chain n‑Alcohols
Published in ACS applied materials & interfaces (24-02-2021)“…Simple n-alcohols, such as 1-dodecanol, show anomalous film-forming and friction behaviors under elastohydrodynamic lubrication (EHL) conditions, as found…”
Get full text
Journal Article -
10
Synchrotron Photothermal Infrared Nanospectroscopy of Drug-Induced Phospholipidosis in Macrophages
Published in Analytical chemistry (Washington) (16-06-2020)“…Synchrotron resonance-enhanced infrared atomic force microscopy (RE-AFM-IR) is a near-field photothermal vibrational nanoprobe developed at Diamond Light…”
Get full text
Journal Article -
11
High Ammonia Adsorption in MFM-300 Materials: Dynamics and Charge Transfer in Host–Guest Binding
Published in Journal of the American Chemical Society (03-03-2021)“…Ammonia (NH3) is a promising energy resource owing to its high hydrogen density. However, its widespread application is restricted by the lack of efficient and…”
Get full text
Journal Article -
12
Direct Observation of Ammonia Storage in UiO-66 Incorporating Cu(II) Binding Sites
Published in Journal of the American Chemical Society (18-05-2022)“…The presence of active sites in metal–organic framework (MOF) materials can control and affect their performance significantly in adsorption and catalysis…”
Get full text
Journal Article -
13
A {Ni12}‐Wheel‐Based Metal–Organic Framework for Coordinative Binding of Sulphur Dioxide and Nitrogen Dioxide
Published in Angewandte Chemie International Edition (01-02-2022)“…Air pollution by SO2 and NO2 has caused significant risks on the environment and human health. Understanding the mechanism of active sites within capture…”
Get full text
Journal Article -
14
Highly Efficient Proton Conduction in the Metal–Organic Framework Material MFM-300(Cr)·SO4(H3O)2
Published in Journal of the American Chemical Society (13-07-2022)“…The development of materials showing rapid proton conduction with a low activation energy and stable performance over a wide temperature range is an important…”
Get full text
Journal Article -
15
The effect of optical substrates on micro-FTIR analysis of single mammalian cells
Published in Analytical and bioanalytical chemistry (01-02-2013)“…The study of individual cells with infrared (IR) microspectroscopy often requires living cells to be cultured directly onto a suitable substrate. The surface…”
Get full text
Journal Article -
16
Author Correction: Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site
Published in Nature materials (01-08-2022)Get full text
Journal Article -
17
Elucidating the Drug Release from Metal–Organic Framework Nanocomposites via In Situ Synchrotron Microspectroscopy and Theoretical Modeling
Published in ACS applied materials & interfaces (29-01-2020)“…Nanocomposites comprising metal–organic frameworks (MOFs) embedded in a polymeric matrix are promising carriers for drug delivery applications. While…”
Get full text
Journal Article -
18
Post-synthetic modulation of the charge distribution in a metal-organic framework for optimal binding of carbon dioxide and sulfur dioxide
Published in Chemical science (Cambridge) (2019)“…Modulation of pore environment is an effective strategy to optimize guest binding in porous materials. We report the post-synthetic modification of the charge…”
Get full text
Journal Article -
19
Impact of Host–Guest Interactions on the Dielectric Properties of MFM-300 Materials
Published in Inorganic chemistry (23-10-2023)“…Metal–organic framework (MOF) materials are attracting increasing interest in the field of electronics due to their structural diversity, intrinsic porosity,…”
Get full text
Journal Article -
20
Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework
Published in Nature communications (13-02-2017)“…Hydrogen bonds dominate many chemical and biological processes, and chemical modification enables control and modulation of host–guest systems. Here we report…”
Get full text
Journal Article