Search Results - "Freunberger, Stefan A."
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Biredox ionic liquids with solid-like redox density in the liquid state for high-energy supercapacitors
Published in Nature materials (01-04-2017)“…Kinetics of electrochemical reactions are several orders of magnitude slower in solids than in liquids as a result of the much lower ion diffusivity. Yet, the…”
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Mechanism and performance of lithium-oxygen batteries - a perspective
Published in Chemical science (Cambridge) (01-10-2017)“…Rechargeable Li-O 2 batteries have amongst the highest formal energy and could store significantly more energy than other rechargeable batteries in practice if…”
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Charging a Li–O2 battery using a redox mediator
Published in Nature chemistry (01-06-2013)“…The non-aqueous Li–air (O 2 ) battery is receiving intense interest because its theoretical specific energy exceeds that of Li-ion batteries. Recharging the…”
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A stable cathode for the aprotic Li–O2 battery
Published in Nature materials (01-11-2013)“…Rechargeable lithium–air (O 2 ) batteries are receiving intense interest because their high theoretical specific energy exceeds that of lithium-ion batteries…”
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Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors
Published in Angewandte Chemie International Edition (01-10-2012)“…Energy‐storage technologies, including electrical double‐layer capacitors and rechargeable batteries, have attracted significant attention for applications in…”
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An Electrolyte for Reversible Cycling of Sodium Metal and Intercalation Compounds
Published in ChemSusChem (20-01-2017)“…Na battery chemistries show poor passivation behavior of low voltage Na storage compounds and Na metal with organic carbonate‐based electrolytes adopted from…”
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True performance metrics in beyond-intercalation batteries
Published in Nature energy (05-06-2017)“…Beyond-intercalation batteries promise a step-change in energy storage compared to intercalation-based lithium-ion and sodium-ion batteries. However, only…”
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Persistent and reversible solid iodine electrodeposition in nanoporous carbons
Published in Nature communications (24-09-2020)“…Aqueous iodine based electrochemical energy storage is considered a potential candidate to improve sustainability and performance of current battery and…”
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On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering
Published in Nature communications (24-10-2022)“…The inadequate understanding of the mechanisms that reversibly convert molecular sulfur (S) into lithium sulfide (Li 2 S) via soluble polysulfides (PSs)…”
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DABCOnium: An Efficient and High‐Voltage Stable Singlet Oxygen Quencher for Metal–O2 Cells
Published in Angewandte Chemie International Edition (13-05-2019)“…Singlet oxygen (1O2) causes a major fraction of the parasitic chemistry during the cycling of non‐aqueous alkali metal‐O2 batteries and also contributes to…”
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Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium–oxygen batteries
Published in Nature energy (20-03-2017)“…Non-aqueous metal–oxygen batteries depend critically on the reversible formation/decomposition of metal oxides on cycling. Irreversible parasitic reactions…”
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A Moisture- and Oxygen-Impermeable Separator for Aprotic Li-O2 Batteries
Published in Advanced functional materials (2016)“…Despite the unparalleled theoretical gravimetric energy, Li‐O2 batteries are still under a research stage because of their insufficient cycle lives. While the…”
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Deactivation of redox mediators in lithium-oxygen batteries by singlet oxygen
Published in Nature communications (26-03-2019)“…Non-aqueous lithium-oxygen batteries cycle by forming lithium peroxide during discharge and oxidizing it during recharge. The significant problem of oxidizing…”
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Anisotropic, effective diffusivity of porous gas diffusion layer materials for PEFC
Published in Electrochimica acta (30-12-2008)“…A comparative, experimental diffusivity study of gas diffusion layer (GDL) materials for polymer electrolyte fuel cells (PEFC) is presented for the first time…”
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Author Correction: Persistent and reversible solid iodine electrodeposition in nanoporous carbons
Published in Nature communications (06-11-2020)“…An amendment to this paper has been published and can be accessed via a link at the top of the paper…”
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Aprotic Li–O2 Battery: Influence of Complexing Agents on Oxygen Reduction in an Aprotic Solvent
Published in Journal of physical chemistry. C (20-02-2014)“…Several problems arise at the O2 (positive) electrode in the Li-air battery, including solvent/electrode decomposition and electrode passivation by insulating…”
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Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen
Published in Angewandte Chemie (International ed.) (04-05-2018)“…Solid alkali metal carbonates are universal passivation layer components of intercalation battery materials and common side products in metal‐O2 batteries, and…”
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A Reversible and Higher-Rate Li-O2 Battery
Published in Science (03-08-2012)“…The rechargeable nonaqueous lithium-air (Li-O(2)) battery is receiving a great deal of interest because, theoretically, its specific energy far exceeds the…”
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Lithium–Oxygen Batteries and Related Systems: Potential, Status, and Future
Published in Chemical reviews (22-07-2020)“…The goal of limiting global warming to 1.5 °C requires a drastic reduction in CO2 emissions across many sectors of the world economy. Batteries are vital to…”
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To DISP or Not? The Far‐Reaching Reaction Mechanisms Underpinning Lithium‐Air Batteries
Published in Angewandte Chemie International Edition (08-07-2024)“…The short history of research on Li−O2 batteries has seen a remarkable number of mechanistic U‐turns over the years. From the initial use of carbonate…”
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