Search Results - "Freiermuth, Beat"
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Pyrolysis of benzotriazoles. Relationships between 1- and 2-vinylbenzotriazoles, α- and β-azidostyrenes, N-phenylketenimine and indole. Pitfalls in the use of pyrolysis-mass spectrometry in mechanistic studies
Published in Journal of analytical and applied pyrolysis (01-09-2016)“…[Display omitted] •Flash vacuum pyrolysis (FVP) of vinylbenzotriazoles is reinterpreted.•FVP of N-phenylketenimine PhNCCH2 does not produce indole.•FVP of…”
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Pyrolysis of benzotriazoles. 1-Acyl- and 1-alkoxycarbonylbenzotriazoles: Hetero-Wolff rearrangement to N-acyl- and N-alkoxycarbonyl-fulvenimines and free radical routes to cyanocyclopentadienes
Published in Journal of analytical and applied pyrolysis (01-11-2017)“…[Display omitted] •FVP of 1-acyl- and 1-alkoxycarbonylbenzotriazoles yields N-acylfulvenimines.•N-Acyl- and N-alkoxycarbonylfulvenimines yield…”
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Photochemistry and Photophysics of α-Hydroxy Ketones
Published in Macromolecules (13-03-2001)“…Time-resolved laser flash spectroscopy with transient detection by time-resolved UV−vis, IR, and EPR has been employed to investigate the photochemistry and…”
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Direct observation of .alpha.-oxo ketenes formed from 1,3-dioxin-4-ones and the enols of .beta.-keto esters
Published in Journal of organic chemistry (01-03-1991)Get full text
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Tautomerization of Phenols, Part III , The Anthrone−Anthrol Equilibrium in Aqueous Solution
Published in Helvetica chimica acta (19-12-2001)“…The equilibrium between 10H‐anthr‐9‐one and 9‐anthrol favors the ketone, which ionizes as a carbon acid in aqueous base. Rates of equilibration were measured…”
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Molecular and electronic structure of pyracylene
Published in Journal of the American Chemical Society (1990)Get full text
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