Search Results - "Fraldi, Natascia"
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1
Improving the Behavior of Bis(phenoxyamine) Group 4 Metal Catalysts for Controlled Alkene Polymerization
Published in Macromolecules (23-06-2009)Get full text
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2
Structure/Properties Relationship for Bis(phenoxyamine)Zr(IV)-Based Olefin Polymerization Catalysts: A Simple DFT Model To Predict Catalytic Activity
Published in Macromolecules (22-05-2012)“…The productivity of a number of bis(phenoxyamine)Zr(IV)-based catalysts (bis(phenoxyamine) = N,N′-bis(3-R1-5-R2-2-O-C6H2CH2)-N,N′-(R3)2-(NCH2CH2N)) in ethene…”
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3
Structure and Dynamics in Solution of Bis(phenoxy-amine)Zirconium Catalysts for Olefin Polymerization
Published in Organometallics (13-06-2011)“…The activity of two bis(phenoxy-amine)ZrR2 precatalysts (bis(phenoxy-amine) = N,N′-(3-tBu-5-OMe-2-C6H2OCH2)2-N,N′-Me2-(NCH2CH2N); R = Me (1), Bn (2, benzyl))…”
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4
Structure−Activity Relationship in Olefin Polymerization Catalysis: Is Entropy the Key?
Published in Journal of the American Chemical Society (06-10-2010)“…Activation parameters for propene polymerization mediated by a bis(phenoxyamine)Zr-dibenzyl catalyst in combination with MAO have been measured experimentally…”
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5
On factors influencing insertion of allylic substrates in Pd–Caryl bonds
Published in Inorganica Chimica Acta (01-04-2009)Get full text
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Coordination modes of 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine ( bedip) to Pt and Pd metal ions: Synthesis and structural characterization of mono- and bi-nuclear complexes
Published in Journal of organometallic chemistry (01-11-2007)“…Versatile coordination features of 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine ( bedip) are disclosed by preparing neutral and cationic Pt(II),…”
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Binuclear Complexes of Bis-Chelating Ligands Based on [1,4]Dioxocino[6,5-b:7,8-b′]dipyridine Moieties
Published in Inorganic chemistry (06-07-2009)“…Ligands based on a [1,4]dioxocino[6,5-b:7,8-b′]dipyridine (doxpy) core were prepared and characterized. They all present two equal chelating moieties each one…”
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On factors influencing insertion of allylic substrates in Pd–C aryl bonds
Published in Inorganica Chimica Acta (20-04-2009)“…Arylation of allylic substrates has been performed in stoichiometric conditions by the use of neutral or cationic aryl/palladium species. The initially formed…”
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C–C coupling of aryl groups and allyl derivatives on Pt(II)-phenanthroline fragments: crystal and molecular structure of the tbp [(η 1,η 2-2-allyl,5-methyl-phenyl)iodo(1,10-phenanthroline)platinum(II)] complex containing the N–N ligand in axial-equatorial coordination mode
Published in Journal of organometallic chemistry (15-04-2005)“…Allyl compounds CH 2 CHCH 2Fn bearing electron-withdrawing functional (Fn) groups mainly react with cationic {Pt(aryl)(1,10-phenanthroline)} + fragments…”
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10
Bis-chelating ligands based on bipyridine or bis-isoquinoline moieties with controlled rotation around the C–C bond
Published in Inorganic chemistry communications (01-11-2005)“…Two unprecedented types of ligands with C 2 symmetry, with comparable essential features, are proposed as supports for metal centres in bimetallic promotion of…”
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