Search Results - "Fowler, Frank W."
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Single-Crystal-to-Single-Crystal Topochemical Polymerizations by Design
Published in Accounts of chemical research (01-09-2008)“…The polymerization of simple conjugated dienes has long been of interest: polydienes occur throughout Nature, and polyisoprene and its analogues form the basis…”
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Preparation and Structure of a Tubular Addition Polymer: A True Synthetic Nanotube
Published in Journal of the American Chemical Society (11-01-2012)“…The structure of a synthetic nanotube prepared by the solid-state polymerization of a stacked column of diacetylene-based macrocycles has been determined. A…”
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Weak Interactions Dominating the Supramolecular Self-Assembly in a Salt: A Designed Single-Crystal-to-Single-Crystal Topochemical Polymerization of a Terminal Aryldiacetylene
Published in Journal of the American Chemical Society (21-01-2009)“…Single-crystal-to-single-crystal (SCSC) topochemical polymerizations of diacetylenes can yield nearly defect-free conjugated polymer crystals unattainable by…”
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Pressure-Induced Polymerization of Diiodobutadiyne in Assembled Cocrystals
Published in Journal of the American Chemical Society (02-04-2008)“…Diiodobutadiyne forms cocrystals with bis(pyridyl)oxalamides in which the diyne alignment is near the ideal parameters for topochemical polymerization to the…”
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Single-Crystal-to-Single-Crystal Topochemical Polymerizations of a Terminal Diacetylene: Two Remarkable Transformations Give the Same Conjugated Polymer
Published in Journal of the American Chemical Society (15-10-2003)“…Host−guest chemistry was used to prepare a cocrystal of a dipyridyl substituted oxalamide host and a resorcinol derivative of a terminal diacetylene. X-ray…”
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The Topochemical 1,6-Polymerization of a Triene
Published in Journal of the American Chemical Society (11-09-2002)“…The first topochemical 1,6-polymerization of a triene has been observed. The required supramolecular structure for this polymerization was achieved by the π−π…”
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A Rational Approach to the Preparation of Polydipyridyldiacetylenes: An Exercise in Crystal Design
Published in Crystal growth & design (01-11-2005)“…Crystals have been designed for the purpose of carrying out the topochemical polymerization of two isomeric dipyridyldiacetylenes,…”
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Molecular Symmetry and the Design of Molecular Solids: The Oxalamide Functionality as a Persistent Hydrogen Bonding Unit
Published in Journal of the American Chemical Society (08-01-1997)“…A symmetry analysis based upon the structure of simple molecules and their anticipated intermolecular interactions can lead to successful predictions of…”
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Controlled Spacing of Metal Atoms via Ligand Hydrogen Bonds
Published in Journal of the American Chemical Society (22-10-1997)Get full text
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Preparation of layered diacetylenes as a demonstration of strategies for supramolecular synthesis
Published in Journal of the American Chemical Society (01-12-1995)Get full text
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Designed Cocrystals Based on the Pyridine−Iodoalkyne Halogen Bond
Published in Organic letters (12-05-2005)“…Diiodobutadiyne (1) and diiodohexatriyne (2) form cocrystals with bispyridyl oxalamides and ureas, based on the halogen bond between the alkynyl iodine and…”
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A Supramolecular Solution to a Long-Standing Problem: The 1,6-Polymerization of a Triacetylene
Published in Angewandte Chemie International Edition (16-06-2000)“…A topochemical polymerization of a triacetylene has been achieved by the synthesis of a host molecule specifically designed to preorganize a triacetylene…”
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Commensurate and Incommensurate Hydrogen Bonds. An Exercise in Crystal Engineering
Published in Journal of the American Chemical Society (07-11-2001)“…Ureas characteristically form one-dimensional hydrogen-bonded α-networks with a repeat distance of about 4.60 Å. Oxamides form similar α-networks with a longer…”
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Synthesis and reactions of N-protected 2-lithiated pyrroles and indoles. The tert-butoxycarbonyl substituent as a protecting group
Published in Journal of organic chemistry (01-01-1981)Get full text
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What have We Learned about Topochemical Diacetylene Polymerizations?
Published in Supramolecular chemistry (01-01-2005)“…A series of five polydiacetylenes have been synthesized via topochemical polymerizations of the corresponding monomers. The requisite structural parameters for…”
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Intramolecular Diels−Alder Reaction of 2-Cyano-1-aza-1,3-butadienes
Published in Journal of organic chemistry (04-04-1997)“…It has been demonstrated that a 2-cyano substituent is sufficient to activate 1-aza-1,3-butadienes with respect to the intramolecular Diels−Alder reaction…”
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Diels-Alder reaction of 2-cyano-1-azadienes. The effect of nitrogen substituents
Published in Journal of organic chemistry (01-04-1993)Get full text
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An approach to the design of molecular solids. The ureylene dicarboxylic acids
Published in Journal of the American Chemical Society (01-08-1990)Get full text
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Intramolecular Diels−Alder Reaction of N-Alkyl-2-cyano-1-azadienes: A Study of the Eschenmoser Cycloreversion of Dihydrooxazines as a Route to N-Alkyl-2-cyano-1-azadienes
Published in Journal of organic chemistry (04-04-1997)“…In connection with the development of the intramolecular Diels−Alder reaction (IMDA) of 1-azadienes, the 5,6-dihydro-4H-1,2-oxazine 12 has been evaluated as a…”
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